13059-86-4

Basic information

• Product Name: Butyl(2,4-dinitrophenyl)amine
• Synonyms: Butyl(2,4-dinitrophenyl)amine;N-Butyl-2,4-dinitroaniline;N-Butyl-2,4-dinitrobenzenamine
• CAS NO: 13059-86-4
• Molecular Formula: C₁₀H₁₃N₃O₄
• Molecular Weight: 239.22792
• Mol File: 13059-86-4.mol
• Article Data: 45

Chemical Properties

• Boiling Point: 384.2°C at 760 mmHg
• Flash Point: 186.1°C
• Appearance: /
• Density: 1.313g/cm³
• Vapor Pressure: 4.17E-06mmHg at 25°C
• Refractive Index: 1.606
• CAS DataBase Reference: Butyl(2,4-dinitrophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: Butyl(2,4-dinitrophenyl)amine(13059-86-4)
• EPA Substance Registry System: Butyl(2,4-dinitrophenyl)amine(13059-86-4)

Safety Data

• Hazardous Substances Data: 13059-86-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13N3O4/c1-2-3-6-11-9-5-4-8(12(14)15)7-10(9)13(16)17/h4-5,7,11H,2-3,6H2,1H3

Upstream product

• 70-34-8 2,4-Dinitrofluorobenzene 
• 109-73-9 N-butylamine 
• 709-49-9 1-iodo-2,4-dinitrobenzene 
• 64-17-5 ethanol 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 17508-17-7 O-(2,4-dinitrophenyl)hydroxylamine 
• 99-65-0 meta-dinitrobenzene 
• 109-65-9 1-bromo-butane 
• 97-02-9 2,4-Dinitroanilin 
• 1126-78-9 N-(n-butyl)aniline 
• 619-16-9 1-chloro-2,5-dinitrobenzene 
• 584-48-5 2,4-dinitrobromobenzene 
• 54247-05-1 1,3-dinitrobenzene-d₄ 
• 22113-86-6 ethylammonium nitrate 

Downstream Products

• 56136-72-2 N¹-butyl-4-nitrobenzene-1,2-diamine 
• 51-28-5 2,4-Dinitrophenol 
• 64899-09-8 N-(n-butyl)-2,4-dinitrotrifluoroacetanilide 
• 86824-87-5 Butyl-(2,4,6-trinitro-phenyl)-nitramin 
• 97-02-9 2,4-Dinitroanilin 

Relevant articles and documents

Molecular recognition-based catalysis in nucleophilic aromatic substitution: A mechanistic study

Nucleophilic aromatic substitution for nitro-activated substrates in the presence of glymes and crown ethers is reported. The kinetic study reveals the many-sided nature of the polyether-catalyzed SNAr mechanism as well as the main features aff

Characterization of solvent mixtures. Part 8 - Preferential solvation of chemical probes in binary solvent systems of a polar aprotic hydrogen-bond acceptor solvent with acetonitrile or nitromethane. Solvent effects on aromatic nucleophilic substitution r

The use of chemical probes for the characterization of chemical properties was explored for completely non-aqueous aprotic binary solvent mixtures. The Dimroth-Reichardt ET(30) betaine dye, 4-nitrophenol, 4-nitroanisole, 4-nitroaniline and N,N-

Catalysis in Micellar Media. Kinetics and Mechanism for the Reaction of 1-Fluoro-2,4-dinitrobenzene with n-Butylamine and Piperidine in n-Hexane and AOT/n-Hexane/Water Reverse Micelles

The nucleophilic aromatic substitution SNAr reaction of 1-fluoro-2,4-dinitrobenzene with n-butylamine and piperidine was studied in n-hexane and AOT/n-hexane/water reverse micelle media. The kinetic profile of the reactions was investigated as

Direct formation of aromatic C-N bonds. Regioselective amination of m- dinitrobenzene via fluoride promoted nucleophilic aromatic photosubstitution for hydrogen

Useful yields are achieved in the regioselective direct formation of anilines and aromatic amides through hydrogen nucleophilic aromatic photosubstitution of m-dinitrobenzene with primary amines and amides, promoted by fluoride anion.

Solvent effects on chemical processes: New solvents designed on the basis of the molecular-microscopic properties of (molecular solvent + 1,3-dialkylimidazolium) binary mixtures

The purpose of this work was to analyze the microscopic feature of binary solvent systems formed by a molecular solvent (acetonitrile or dimethylformamide or methanol) and an ionic liquid (IL) cosolvent [1-(1-butyl)-3- methylimidazolium tetrafluoroborate

Photoacoustic Spectroscopy of Chemically Bonded Chromatographic Stationary Phases

A qualitative study of chemically-bonded, chromatographic stationary phases was undertaken to assess the applicability of photoacoustic spectroscopy (PAS) to the characterization of chemically-modified surfaces.The ability of this technique to identify co

Mechanism of base catalysis in the reactions of phenyl aryl ethers with aliphatic amines in dimethyl sulfoxide

The reactions of n-butylamine, pyrrolidine and piperidine with phenyl 2,4,6-trinitrophenyl ether, 3, in DMSO result in the rapid reversible formation of adducts by reaction at the 3-position followed by attack at the 1-position leading to substitution of

Aryl-Diadamantyl Phosphine Ligands in Palladium-Catalyzed Cross-Coupling Reactions: Synthesis, Structural Analysis, and Application

Synthesis, temperature-dependent NMR structure investigation and utilization of a new, stable and easily accessible aryl-diadamantylphosphine ligand family is reported. The bulky and electron-rich phosphorus center of the ligand enhances the catalytic activity of palladium in cross-coupling reactions of sterically demanding ortho-substituted aryl halides. In our study, we demonstrated the synthetic applicability of the new phosphine ligands in Buchwald-Hartwig and tosyl hydrazone coupling reactions.

Pd(OAc)2-catalyzed dinitration reaction of aromatic amines

Taking advantage of Pd(OAc)2-catalyzed dinitration reactions with Bi(NO3)3·5H2O in trifluoroethanol (TFE) and trifluoroacetic acid (TFA), we have developed an efficient and practical method for the synthesis of secondary dinitro-aromatic amines. The products could be applied to the preparation of 5-amine-N-methyl-benzimidazolone, the azo-dyes, economic advantages. The method has also been expanded to the dinitration reaction of some tertiary aromatic amines.