13220-01-4

Basic information

• Product Name: Methanone, (2,5-diphenyl-1H-pyrrol-3-yl)phenyl-
• CAS NO: 13220-01-4
• Molecular Formula: C23H17NO
• Molecular Weight: 323.394
• Mol File: 13220-01-4.mol

Chemical Properties

• CAS DataBase Reference: Methanone, (2,5-diphenyl-1H-pyrrol-3-yl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (2,5-diphenyl-1H-pyrrol-3-yl)phenyl-(13220-01-4)
• EPA Substance Registry System: Methanone, (2,5-diphenyl-1H-pyrrol-3-yl)phenyl-(13220-01-4)

Safety Data

• Hazardous Substances Data: 13220-01-4(Hazardous Substances Data)

Upstream product

• 838-40-4 2,5-diphenyl-1H-pyrrole 
• 93-97-0 benzoic acid anhydride 
• 1854-56-4 2-benzoyl-1,4-diphenylbutane-1,4-dione 
• 631-61-8 ammonium acetate 
• 13636-88-9 3,3-bis(methylthio)-1-phenylprop-2-en-1-one 
• 780-25-6 N-benzylidene benzylamine 
• 94104-20-8 3a,5,6a-triphenyl-3a,6a-dihydro-2H-furo<3,2-b>pyrrole-2,6(3H)-dione 
• 100-42-5 styrene 
• 80012-16-4 3-amino-1,3-diphenyl-2-propene-1-onate 
• 2039-49-8 3,5-diphehylisoxazole 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 98815-39-5 (Z)-3-amino-1,3-diphenylprop-2-en-1-one 
• 98-86-2 acetophenone 
• 536-74-3 phenylacetylene 

Downstream Products

• 70487-23-9 3-benzyl-2,5-diphenyl-1H-pyrrole 

Relevant articles and documents

Ruthenium-catalyzed acceptorless dehydrogenative coupling of amino alcohols and ynones to access 3-acylpyrroles

Herein, a new strategy for the direct synthesis of functionalized pyrroles from β-amino alcohols and ynones via ruthenium-catalyzed acceptorless dehydrogenative coupling has been demonstrated. This developed methodology proceeds in an atom- and step-economic fashion together with the merits of broad substrate scope, operational simplicity, and water and hydrogen gas as the sole by-products, which provides an alternative and sustainable way to access functionalized pyrroles. Further, this method was applied to the rapid synthesis of the COX-1/COX-2 inhibitor and boron dipyrromethene derivative successfully.

Ru(ii)-Catalyzed, Cu(ii)-mediated carbene migratory insertion in the synthesis of trisubstituted pyrroles from isoxazoles

A convenient, “one-pot” synthesis of trisubstituted pyrrolesviaa Ru(ii)-catalyzed, Cu(ii)-mediated reaction of substituted isoxazoles with sulfonylhydrazones has been developed. A series of highly functionalized pyrroles are obtainedviaa synergistic forma

Palladium(ii)-catalysed regioselective synthesis of 3,4-disubstituted quinolines and 2,3,5-trisubstituted pyrroles from alkenes via anti-Markovnikov selectivity

A novel strategy has been identified for the regioselective synthesis of 3,4-disubstituted quinolines and 2,3,5-trisubstituted pyrroles from simple alkenes via anti-Markovnikov selectivity under palladium catalysis. The salient features are synthesis of two different heterocycles, readily available starting materials, broad substrate scope, moderate to good yields and use of molecular oxygen as a terminal oxidant.

Studies on cycloaddition reactions of 1,3-diphenyl-2-azaallyl lithium and ethyl (benzylideneamino) acetate anion with α-oxoketene dithioacetals

The α-oxoketene dithioacetals undergo anionic [1,3] cycloaddition with 1,3-diphenyl-2-azaallyllithium to give either pyrroles or spiropyrrolines with two exceptions. Lithium bromide/triethylamine induced cycloaddition of ethyl (benzylideneamino)acetate (7