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Trihydroxyboroxine, also known as B3O3H3, is a boron compound characterized by the presence of three hydroxyl groups. It exists as a colorless crystalline solid that is soluble in water and has a melting point of 78 degrees Celsius. Trihydroxyboroxine is recognized for its unique chemical properties and structural features, making it a versatile reagent in various scientific and industrial applications.

13460-51-0

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13460-51-0 Usage

Uses

Used in Organic Synthesis:
Trihydroxyboroxine is used as a reagent in organic synthesis for its ability to facilitate a range of chemical reactions, contributing to the formation of complex organic molecules.
Used as a Boron Source:
In the production of icosahedral boranes, Trihydroxyboroxine serves as an essential boron source, playing a critical role in the synthesis of these important compounds with unique structural and chemical properties.
Used in the Synthesis of Boron-Containing Polymers and Materials:
Trihydroxyboroxine is utilized as a key building block in the creation of boron-containing polymers and materials, which have potential applications in various fields due to their distinct properties.
Used in Medicine:
Trihydroxyboroxine has potential applications in the medical field, where its unique chemical properties could be harnessed for the development of new pharmaceuticals or therapeutic agents.
Used in Agriculture:
Trihydroxyboroxine may also find use in agricultural applications, potentially contributing to the development of new agrochemicals or enhancing crop protection and yield.
Used in Materials Science:
In the realm of materials science, Trihydroxyboroxine's unique structural features could be employed in the design and synthesis of advanced materials with specific properties for various applications.

Check Digit Verification of cas no

The CAS Registry Mumber 13460-51-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,4,6 and 0 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 13460-51:
(7*1)+(6*3)+(5*4)+(4*6)+(3*0)+(2*5)+(1*1)=80
80 % 10 = 0
So 13460-51-0 is a valid CAS Registry Number.
InChI:InChI=1/B3H3O6/c4-1-7-2(5)9-3(6)8-1/h4-6H

13460-51-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,4,6-trihydroxy-1,3,5,2,4,6-trioxatriborinane

1.2 Other means of identification

Product number -
Other names (HBO2)3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13460-51-0 SDS

13460-51-0Synthetic route

boron trioxide

boron trioxide

water
7732-18-5

water

metaboric acid
13460-51-0

metaboric acid

Conditions
ConditionsYield
In neat (no solvent) reaction in steam at 1061 K;;
In neat (no solvent) Kinetics;
In neat (no solvent) Kinetics;
In neat (no solvent) reaction in steam at 1061 K;;
methanol
67-56-1

methanol

Trimethyl borate
121-43-7

Trimethyl borate

boric acid
11113-50-1

boric acid

A

metaboric acid
13460-51-0

metaboric acid

B

cyclotriboric acid trimethyl ester
102-24-9

cyclotriboric acid trimethyl ester

Conditions
ConditionsYield
In methanol byproducts: H2O; at 100°C, filtration of metaboric acid;;
boric acid
11113-50-1

boric acid

metaboric acid
13460-51-0

metaboric acid

Conditions
ConditionsYield
In toluene azeotropic dehydration with toluene;;
In toluene byproducts: H2O; dehydration in boiling toluene by azeotropic distn.;;
In neat (no solvent) 95-100°C, 24h;;
boric acid
11113-50-1

boric acid

A

metaboric acid
13460-51-0

metaboric acid

B

water
7732-18-5

water

Conditions
ConditionsYield
In neat (no solvent) heating to temperatures higher than 100°C;;
In neat (no solvent) heating to temperatures higher than 100°C;;
tri-n-butoxyboroxin
101-36-0

tri-n-butoxyboroxin

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

metaboric acid
13460-51-0

metaboric acid

Conditions
ConditionsYield
In neat (no solvent) byproducts: C4H9Br; at 20°C;;
In neat (no solvent) byproducts: C4H9Br; at 20°C;;0%
In neat (no solvent) byproducts: C4H9Br; at 20°C;;0%
In neat (no solvent) byproducts: C4H9Br; at 20°C;;
acetic acid
64-19-7

acetic acid

A

metaboric acid
13460-51-0

metaboric acid

B

triethoxyboroxine
7325-11-3

triethoxyboroxine

C

ethyl acetate
141-78-6

ethyl acetate

boron trioxide

boron trioxide

water
7732-18-5

water

A

metaboric acid
13460-51-0

metaboric acid

B

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
In water heating mixt. of boron oxide and water overnight to melt; different molar ratios of compds. were used; detected by Raman spectroscopy;
boron

boron

metaboric acid
13460-51-0

metaboric acid

hexaboron monoxide

hexaboron monoxide

Conditions
ConditionsYield
In neat (no solvent) heating to 1900 to 2000°C in vacuum at 0.41 kbar;;
metaboric acid
13460-51-0

metaboric acid

metaboric acid
13460-50-9

metaboric acid

Conditions
ConditionsYield
In gaseous matrix Irradiation (UV/VIS); pulsed laser evapn. into an Ar stream condensed at 12 K; detd. by IR;
propylamine
107-10-8

propylamine

metaboric acid
13460-51-0

metaboric acid

(B(OH)O)2OBOHNH2(n-C3H7)
92274-41-4

(B(OH)O)2OBOHNH2(n-C3H7)

metaboric acid
13460-51-0

metaboric acid

acetyl chloride
75-36-5

acetyl chloride

triacetyl boroxine
126755-89-3

triacetyl boroxine

metaboric acid
13460-51-0

metaboric acid

n-Octylamine
111-86-4

n-Octylamine

(B(OH)O)2OBOHNH2(n-C8H17)

(B(OH)O)2OBOHNH2(n-C8H17)

metaboric acid
13460-51-0

metaboric acid

BHO2, cubic
13460-50-9

BHO2, cubic

Conditions
ConditionsYield
In neat (no solvent) heatong to 140°C for a longer period of time;;
metaboric acid
13460-51-0

metaboric acid

BHO2, monoclinic
13460-50-9

BHO2, monoclinic

Conditions
ConditionsYield
In neat (no solvent) at 130-160°C;;
In neat (no solvent) at 130-160°C;;
metaboric acid
13460-51-0

metaboric acid

2,6-di-tert-butylphenol
128-39-2

2,6-di-tert-butylphenol

tris(2.6-di-t-butyl phenyloxy)boroxin
13086-83-4

tris(2.6-di-t-butyl phenyloxy)boroxin

Conditions
ConditionsYield
excess borane;;
excess borane;;
metaboric acid
13460-51-0

metaboric acid

2,6-di-tert-butyl-4-methyl-phenol
128-37-0

2,6-di-tert-butyl-4-methyl-phenol

tris(2.6-t-butyl-4-methyl phenyloxy)boroxine
53246-53-0

tris(2.6-t-butyl-4-methyl phenyloxy)boroxine

metaboric acid
13460-51-0

metaboric acid

tris(2-tridecyloxy)boroxine
36375-52-7

tris(2-tridecyloxy)boroxine

metaboric acid
13460-51-0

metaboric acid

sodium carbonate
497-19-8

sodium carbonate

barium carbonate

barium carbonate

sodium barium orthoborate

sodium barium orthoborate

Conditions
ConditionsYield
In neat (no solvent, solid phase) at 750℃;
metaboric acid
13460-51-0

metaboric acid

barium carbonate

barium carbonate

A

3BaO*B2O3

3BaO*B2O3

B

2.5BaO*B2O3

2.5BaO*B2O3

Conditions
ConditionsYield
With sodium fluoride In neat (no solvent, solid phase) at 800℃; Time;

13460-51-0Relevant academic research and scientific papers

A study of the reaction of boric acid with amines: Hydroxyboroxin-amine salts

Vineyard,Godt Jr.

, p. 1144 - 1147 (1964)

The reaction of boric acid with amines has been found to yield either N-substituted ammonium triborates or N-substituted ammonium pentaborates. The major factors governing which product is formed are the steric requirements of the amine and the mole ratio of the reactants. Evidence is presented for the proposed structure of these products.

X-ray diffraction and micro-raman study of structural transformations in (B2O3)1-x(H2O)x glasses and liquids

Bruening, Ralf,Galbraith, Justine B.,Braedley, Katherine E.,Johnstone, Jonathan,Robichaud, Jacques,Balaji, Subramanian,Djaoued, Yahia

, p. 3745 - 3751 (2011/02/16)

Liquid water and vitreous B2O3 are the endpoints of a continuous range of random networks in which hydrogen bonds gradually replace covalent bonds. Previous work has shown that glasses can be obtained by quenching in the range x≤0.50. We report the wide-angle X-ray scattering by the liquid phase in the composition range from x=0.38 to 1.00 (pure water) at temperatures just above the liquidus. The first sharp diffraction peak (FSDP) remains at an approximately constant position in the range 0≤x≤0.8. Beyond this range, the position of the FSDP shifts linearly to higher angles. The relative concentration of the molecular species in the glasses and melts were measured with micro-Raman spectroscopy. Small molecular species are found for glasses and liquids with x;gt&0.36, determining the critical point at which the sample ceases to be a single macromolecule. Molecular water is present in liquids with x;>0.62.

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