13509-27-8

Basic information

• Product Name: METHYL PHENYL CARBONATE
• Synonyms: PHENYLMETHYL CARBONATE;METHYL PHENYL CARBONATE;Carbonic acid methyl phenyl;Carbonic acid O-phenyl O-methyl ester;Carbonic acid=methyl=phenyl ester
• CAS NO: 13509-27-8
• Molecular Formula: C₈H₈O₃
• Molecular Weight: 152.15
• Mol File: 13509-27-8.mol
• Article Data: 83

Chemical Properties

• Melting Point: 147-151 °C
• Boiling Point: 210-213℃
• Flash Point: 97.1 °C
• Appearance: colourless liquid
• Density: 1.14 g/cm³
• Vapor Pressure: 0.124mmHg at 25°C
• Refractive Index: 1.4985
• Storage Temp.: Inert atmosphere,Room Temperature
• Stability: Stable. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: METHYL PHENYL CARBONATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL PHENYL CARBONATE(13509-27-8)
• EPA Substance Registry System: METHYL PHENYL CARBONATE(13509-27-8)

Safety Data

• Safety Statements: 22-24/25
• Hazardous Substances Data: 13509-27-8(Hazardous Substances Data)

Usage

Chemical Properties

colourless liquid

InChI:InChI=1/C8H8O3/c1-10-8(9)11-7-5-3-2-4-6-7/h2-6H,1H3

Upstream product

• 102-09-0 bis(phenyl) carbonate 
• 67-56-1 methanol 
• 101970-86-9 methyl 1,1,1-trichloromethyl carbonate 
• 139-02-6 sodium phenoxide 
• 1885-14-9 phenyl chloroformate 
• 79-22-1 methyl chloroformate 
• 108-95-2 phenol 
• 54714-11-3 4,6-diphenylthieno-[3,4-d]-1,3-dioxol-2-one-5,5-dioxide 
• 86801-34-5 4-Butyl-4H-pyridine-1-carboxylic acid phenyl ester 
• 616-38-6 carbonic acid dimethyl ester 
• 1202680-24-7 phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate 
• 122-79-2 Phenyl acetate 
• 124-38-9 carbon dioxide 
• 107-31-3 Methyl formate 

Downstream Products

• 102-09-0 bis(phenyl) carbonate 
• 1245824-37-6 C₁₄H₁₉BO₅ 
• 103-82-2 phenylacetic acid 
• 67-56-1 methanol 
• 108-95-2 phenol 
• 4277-63-8 methyl 1H-pyrrole-1-carboxylate 
• 56880-01-4 1-phenoxycarbonyl pyrrole 
• 2486-07-9 2,4-dinitrophenyl phenyl ether 
• 2555-49-9 phenoxyacetic acid ethyl ester 
• 93-99-2 benzoic acid phenyl ester 
• 616-38-6 carbonic acid dimethyl ester 
• 5817-70-9 methyl N-benzylcarbamate 
• 2603-10-3 N-phenyl methyl carbamate 
• 591-40-2 Anilinium-triflourmethansulfonat 

Related news

Isobaric vapor–liquid equilibrium at 101.3 kPa and excess properties at 298.15 K for binary mixtures of METHYL PHENYL CARBONATE (cas 13509-27-8) with methanol or dimethyl carbonate08/13/2019

The vapor pressure of the pure component of methyl phenyl carbonate (MPC) was measured at temperatures ranging from 378 K to 488 K. The experimental vapor pressures could be fit well with a three-parameter Antoine equation. Isobaric vapor–liquid equilibria for binary systems (MPC + methanol and...detailed

Preparation and catalytic property of MoO3/SiO2 for disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to diphenyl carbonate08/12/2019

MoO3/SiO2 were prepared by different methods and used as heterogeneous catalysts for the liquid-phase disproportionation of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC). The characterization of XRD, FT-IR and BET showed that the preparation methods remarkably affected the structural...detailed

Efficient synthesis of 1,6-hexamethylene diurethane through coupling transesterification and methoxycarbonylation with METHYL PHENYL CARBONATE (cas 13509-27-8) as intermediate08/11/2019

A reaction coupling system of transesterification and methoxycarbonylation with methyl phenyl carbonate (MPC) as intermediate was established to efficiently prepare 1,6-hexamethylene diurethane (HDU) from 1,6-hexamethylene diamine (HDA). The feasibility of the system was explored using the therm...detailed

Highly efficient and stable PbO–ZrO2 catalyst for the disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to synthesize diphenyl carbonate08/10/2019

Heterogeneous PbO–ZrO2 catalysts (PbZr) were first prepared by coprecipitation method, and used to catalyze the liquid-phase disproportionation reaction of methyl phenyl carbonate (MPC) to synthesize diphenyl carbonate (DPC). PbZr with PbO loading of 15.2 wt% (15.2PbZr) exhibited the best catal...detailed

Influence of coordination groups on the catalytic performances of organo-titanium compounds for disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to synthesize diphenyl carbonate08/09/2019

The disproportionation of methyl phenyl carbonate (MPC) to synthesize diphenyl carbonate (DPC) catalyzed by organo-titanium compounds with different coordination groups was systematically investigated. The results of the molecular structure analysis, the catalytic performance evaluation and the ...detailed

A study of METHYL PHENYL CARBONATE (cas 13509-27-8) and diphenyl carbonate as electrolyte additives for high voltage LiNi0.8Mn0.1Co0.1O2/graphite pouch cells08/08/2019

The effectiveness of methyl phenyl carbonate and diphenyl carbonate as electrolyte additives either singly or in combination with methylene methyl disulfonate and tris(-trimethyl-silyl)-phosphite has been systematically investigated in LiNi0.8Mn0.1Co0.1O2/graphite pouch cells. Experiments conduc...detailed

Relevant articles and documents

Improved Synthesis of Unsymmetrical Carbonate Derivatives Using Calcium Salts

An effective synthetic method for unsymmetrical carbonate species has been developed. Calcium oxide and calcium hydroxide were found to be highly effective for this reaction, affording unsymmetrical carbonates in high yield and purity. Calcium chloride, which is a coproduct, serves as a water scavenger that can be easily removed. Additional drying processes and complicated purification steps are not necessary in this reaction. This improved process is important in terms of green sustainable chemistry principles.

Methylchloroformate synthesis via direct interaction of palladium di(methoxycarbonyl) complexes with CuCl2: utilization in the synthesis of carbonates and carbamates

ClCOOCH3 has been obtained in very good yield by reaction of (L2 = 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen)> with CuCl2.The in situ reaction of ClCOOCH3 with alcohols or amines produces carbonates or carbamates.

Proton Inventories of the Basic Methanolysis of Phenyl Methyl Carbonate and Diphenyl Carbonate

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Selective O-Methylation of Phenol with Dimethyl Carbonate over Catalysts Supported on CaO

Abstract: In this work CaO-based catalysts were found to be efficient heterogeneous catalysts for the methylation of phenol with dimethyl carbonate (DMC) in a closed high pressure reactor. The optimization experiments have been carried out to obtain best phenol conversion and the results showed that CaO catalyst modified with KCl had the best catalytic performance. When the reaction was carried out at 200°C, with phenol to dimethyl carbonate molar ratio of 1 : 2, 15% KCl/CaO catalyst dosage of 3%, reaction time 9 h, 100% conversion of phenol and 95% selectivity towards anisole have been achieved. The structure and properties of the materials were thoroughly characterized by Fourier transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET). The close correlation was found between surface basicity of the catalysts and their catalytic performance for phenol conversion and anisole selectivity.

Diphenyl carbonate compound preparation method

The invention relates to the field of diphenyl carbonate synthesis, and discloses a diphenyl carbonate compound preparation method, which comprises: in the presence of a catalyst represented by a formula (1-1) or a formula (1-2), carrying out a transesterification reaction on a phenol compound represented by a formula (II) and a diester carbonate compound represented by a formula (III), wherein R1, R2 and R3 are selected from a C1-C14 aliphatic hydrocarbon group, a C3-C14 cycloalkyl group, a C6-C14 aryl group, a C7-C14 alkylaryl group, a C7-C14 aralkyl group and a C10-C14 condensed ring aryl group, and X is halogen. The method is high in catalytic activity, high in selectivity and good in stability. Formula (1-1) is (H-[O-Si-(R1)2]n-O)x1-Ti-(OR3)y1X(4-x1-y1), and formula (1-2) is [Si(R2)xO]x2-Ti-(OR3)y2X(4-x2-y2).