13510-35-5Relevant articles and documents
Phase composition and microstructure of In3S4 and CuInS2 films grown on silicon by spray pyrolysis
Sergeeva,Naumov,Semenov,Sokolov
, p. 1046 - 1049 (2007)
We describe the microstructure and phase composition of In 3S4 and CuInS2 films grown on silicon by spray pyrolysis using aerosols of thiourea complexes and examine the effects of the deposition temperature and the nature
Indium(III) compounds containing the neopentyl substituent, In(CH2CMe3)3, In(CH2CMe3)2Cl, In(CH2CMe3)Cl2, and In(CH2CMe3)2CH3. Crystal and molecular structure of dichloroneopentylindium(III), an inorganic polymer
Beachley Jr.,Spiegel, Ella F.,Kopasz, John P.,Rogers, Robin D.
, p. 1915 - 1921 (1989)
The neopentylindium(III) derivatives In(CH2CMe3)3, In(CH2CMe3)2Cl, In(CH2CMe3)Cl2, and In(CH2CMe3)2Me have been prepared and characterized by elemental analyses, cryoscopic molecular weight studies in benzene, IR and 1H NMR spectroscopic data, and Lewis acidity studies. Molecular weight studies suggest that In(CH2CMe3)3 and In(CH2CMe3)2Me are monomeric molecules whereas In(CH2CMe3)2Cl is dimeric in benzene solution. The dichloro derivative In(CH2CMe3)Cl2, which has insufficient solubility in benzene for molecular weight studies, crystallizes in the acentric space group P212121 with a = 6.717 (4) ?, b = 12.217 (4) ?, c = 22.658 (7) ?, V = 1859 ?3, and Z = 8 (formula units). Diffraction data (Mo Kα, 2θ = 2-50°) were collected with a Enraf-Nonius CAD-4/θ-2θ diffractometer. Full-matrix least-squares refinement led to a final R value of 9.062 for 1584 observed [Fo ≥ 5σ(Fo)] reflections. Dichloroneopentylindium(III) is a one-dimensional polymer with no short contacts between strands. Each indium has distorted trigonal-bipyramidal geometry.
Indium nitride from indium iodide at low temperatures: Synthesis and their optical properties
Wu, Changzheng,Li, Tanwei,Lei, Lanyu,Hu, Shuangquan,Liu, Yi,Xie, Yi
, p. 1610 - 1615 (2007/10/03)
In this paper, we present an effective synthetic protocol to produce high quality InN nanocrystals using indium iodide (InI3), one member of the family of indium halides, as the indium source at a low temperature of 3), with a stronger covalent ability, can also prevent the In3+ from being reduced to elemental indium, and then InN is formed. This synthetic protocol not only provides an alternative method to successfully synthesize high-quality InN, but is also useful to fabricate other functional materials by using stronger covalent reactants to prevent reduction/oxidation in the oxidation/reduction reaction process, respectively. Furthermore, we also report the first example of an orientation-attachment process occurring between the metal nitride particles. The high purity of the InN nanoparticles can be seen from the XPS and HRTEM results, showing the as-obtained products possess no obvious iodine or amorphous layers on the surface of particles, respectively. By controlling the parameters of reaction temperature and time, nanoparticles with different sizes were obtained as the final products. Raman and IR results indicate that our experimental data were consistent with the theoretical prediction and this gives further evidence that high quality InN nanocrystals were obtained. Moreover, it has been shown that the near-infrared band around 0.7 eV is characteristic of these samples and there were no obvious peaks around 1.9 eV, indicating that these InN nanocrystals exhibit a band gap of 0.7 eV, rather than the previously accepted 1.9 eV. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2005.
Highly selective acylation of alcohols and amines by an indium triiodide-catalysed transesterification process
Ranu, Brindaban C.,Dutta, Pinak,Sarkar, Arunkanti
, p. 2223 - 2225 (2007/10/03)
A very simple method has been developed for the acylation of alcohols and amines by ethyl acetate through an indium triiodide-catalysed transesterification process. Using this method acylation of a primary OH group in the presence of secondary and phenolic OH groups, and of a primary NH2 in the presence of secondary NH and primary OH have been achieved with high selectivity. The Royal Society of Chemistry 2000.
