14032-06-5

Upstream product

• 64-19-7 acetic acid 
• 931-59-9 benzenesulfenyl chloride 
• 110-83-8 cyclohexene 
• 127-09-3 sodium acetate 
• 105850-52-0 trans-2-phenylthiocyclohexyl N,N-diethylsulfamate 
• 14032-04-3 trans-2-phenylthiocyclohexanol 
• 108-24-7 acetic anhydride 
• 108-98-5 thiophenol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 75-36-5 acetyl chloride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 882-33-7 diphenyldisulfane 
• 105850-51-9 C₁₀H₁₅NO₃S₂ 
• 1600-27-7 mercury(II) diacetate 

Relevant academic research and scientific papers

Highly enantioselective kinetic resolution of trans-2-(phenylthio) cyclohexanol derivatives by immobilized Candida antartica B lipase

Candida antartica B (immobilized CAL-B) mediated resolutions of trans-2-(phenylthio)cyclohexanol derivatives using vinyl acetate as acylating agent and MTBE as solvent provide excellent enantioselectivity (up to >99%) and high yield of both the enantiomer

PhI(OAc)2/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides

A convenient method for 1,2-acetoxysulfenylation of alkenes using disulfide promoted by (diacetoxyiodo)benzene (PhI(OAc)2, DIB)/KI was developed. The reaction is highly regioselective for styrene derivatives while aliphatic alkenes lead to a mixture of two regioisomers.

Diastereoselective synthesis of β-hydroxy sulfoxides: Enzymatic and biomimetic approaches

Stereoselectivities of up to 98 % have been found in the enzymatic synthesis of β-hydroxy sulfoxides catalyzed by cyclohexanone monooxygenase (CHMO). The diastereoselectivity of the "one-pot" preparation of the title compounds in the presence of bovine se

ELECTROPHILIC SULFAMATOSULFENYLATION OF OLEFINS

The reaction of N,N-dialkylarenesufenamides with sulfur trioxides gave arenesulfenyl sulfamates, which have clearly defined electrophilic characteristics.These reagents are capable of adding at the C=C bond of olefins with the formation of the sulfamates of arylthio-substituted alcohols.The reaction with cyclohexene is stereospecific and leads to the trans-1,2-adducts, while the reaction with norbornene and norbornadiene is accompanied by rearrangement of the carbon framework.For the case of the cyclohexane derivatives it was shown that the vicinal arylthiosulfamates are highly sensitive to nucleophilic reagents.

REACTION OF SULFENYL HALIDES WITH ALKENES IN THE PRESENCE OF PERCHLORIC ACID

In the reaction of 2,4-dinitrobenzenesulfenyl chloride and benzenesulfenyl chloride with cyclohexane, propene, and styrene in acetic acid in the presence of perchloric acid the corresponding solvent adducts are formed with yields of 47-75percent.The effect of the perchloric acid on the rate of the reaction of 2,4-dinitrobenzenesulfenyl chloride with cyclohexene is described by an equation for homogeneous catalysis.On the basis of the kinetic data two possible schemes are proposed for the effect of perchloric acid on the formation of the solvent adducts, i.e., a mechanism of homogeneous catalysis and by an ion-exchange mechanism in the noncontrolling stages of the reaction.