14032-04-3

Basic information

• Product Name: Cyclohexanol, 2-(phenylthio)-
• CAS NO: 14032-04-3
• Molecular Formula: C12H16OS
• Molecular Weight: 208.324
• Mol File: 14032-04-3.mol
• Article Data: 61

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-(phenylthio)-(14032-04-3)
• EPA Substance Registry System: Cyclohexanol, 2-(phenylthio)-(14032-04-3)

Safety Data

• Hazardous Substances Data: 14032-04-3(Hazardous Substances Data)

Upstream product

• 286-20-4 cyclohexane-1,2-epoxide 
• 108-98-5 thiophenol 
• 64168-52-1 4'-nitrobenzenesulfenanilide 
• 75-05-8 acetonitrile 
• 110-83-8 cyclohexene 
• 24796-87-0 2-bromo-cyclohexanol 
• 4832-52-4 tris(phenylthio)methane 
• 882-33-7 diphenyldisulfane 
• 4551-15-9 phenylthiotrimethylsilane 
• 13865-50-4 methoxymethyl phenyl sulfide 
• 930-69-8 sodium thiophenolate 
• 102438-47-1 6,6-bis(phenylthio)hexan-1-ol 
• 98289-55-5 trans-1-phenylthio-2-trifluoroacetoxycyclohexane 
• 286-20-4 cyclohexene oxide 

Downstream Products

• 133576-46-2 trans-2-(phenylsulfanyl)cyclohexanol 
• 127871-84-5 6-Phenylsulfanyl-hexanal 
• 73843-10-4 2-(phenylsulphonyl)cyclohexanone 
• 100388-22-5 1-bromo-2-phenylsulfanylcyclohexane 
• 24337-53-9 2-(1-Hydroxy-1-methylethyl)cyclohexanol 
• 14032-03-2 ((1R,2R)-2-chlorocyclohexyl)(phenyl)sulfane 
• 190436-63-6 (2-nitrocyclohexyl) phenyl sulfide 
• 190436-75-0 (2-Nitro-cyclohex-1-enylsulfanyl)-benzene 
• 1229238-64-5 (+)-trans-1-benzoyloxy-2-phenylsulfanylcyclohexane 
• 102917-46-4 (-)-trans-(1R,2R)-2-(phenylthio)-1-cyclohexanol 
• 92633-43-7 2-(phenylsulfonyl)cyclohexanol 
• 65117-26-2 2-Phenylsulfinyl-cyclohexanol 
• 98289-55-5 trans-1-phenylthio-2-trifluoroacetoxycyclohexane 
• 133775-38-9 (1R, 2R)-2-(phenylthio)cyclohexyl acetate 

Relevant articles and documents

Synthesis and application of Cu(II) immobilized MCM-41 based solid Lewis acid catalyst for aminolysis reaction under solvent-free condition

In this paper, a Cu(II) immobilized periodic mesoporous organosilica (PMOs) was synthesized and used as a reusable solid Lewis acid catalyst for the aminolysis of epoxides under solvent-free conditions. An amide-based ligand, L-propylsilyl (1) having a specific binding pocket was prepared and fabricated on mesoporous MCM-41 to produce mesoporous organosilica L-propylsilyl@MCM-41 (2). Further, it has been utilized for anchoring Cu(II) ions under controlled reaction conditions to yield solid Lewis acid catalyst Cu(II)-L-propylsilyl@MCM-41 (3). The synthesized catalyst 3 exhibits significantly higher catalytic activity for aminolysis compared to hitherto known solid Lewis acid catalysts. An extensive range of β-amino alcohols with high regio and stereoselectivity were prepared by using catalyst 3. The catalyst was recovered easily and reused eight times without any loss in its catalytic activity. Furthermore, the synthesis of clinically significant propranolol (β-blocker) from α- naphthyl glycidyl ether was attained successfully using catalyst 3 in a very decent yield.

Rapid, benign, and additive-free thiolysis of epoxides under ultrasonic/aqueous conditions

An environmentally friendly and efficient procedure is developed for ring opening of various epoxides with thiols under non-thermal conditions. Reactions take place by ultrasonic irradiation of the two reactants suspended in an additive-free aqueous mediu

Highly enantioselective kinetic resolution of trans-2-(phenylthio) cyclohexanol derivatives by immobilized Candida antartica B lipase

Candida antartica B (immobilized CAL-B) mediated resolutions of trans-2-(phenylthio)cyclohexanol derivatives using vinyl acetate as acylating agent and MTBE as solvent provide excellent enantioselectivity (up to >99%) and high yield of both the enantiomer