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14064-41-6

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14064-41-6 Usage

General Description

1-Methoxy-3-[(E)-2-phenylethenyl]benzene, also known as Anethole, is an organic compound that belongs to the class of phenylpropanoids. It is a colorless to pale yellow liquid that is found in the essential oils of anise, fennel, and star anise. Anethole is commonly used as a flavoring agent in the food and beverage industry, particularly in licorice and anise-flavored products. It also has antibacterial and antifungal properties, and is used in the pharmaceutical and cosmetic industries. Additionally, anethole has been studied for its potential medicinal properties, including anti-inflammatory, antioxidant, and cancer-fighting effects. However, it is important to note that anethole may have potential toxic effects if consumed in large quantities.

Check Digit Verification of cas no

The CAS Registry Mumber 14064-41-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,6 and 4 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 14064-41:
(7*1)+(6*4)+(5*0)+(4*6)+(3*4)+(2*4)+(1*1)=76
76 % 10 = 6
So 14064-41-6 is a valid CAS Registry Number.

14064-41-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methoxy-3-(2-phenylethenyl)benzene

1.2 Other means of identification

Product number -
Other names (E)-1-methoxy-3-stytylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14064-41-6 SDS

14064-41-6Relevant articles and documents

Rh-catalyzed reagent-free ring expansion of cyclobutenones and benzocyclobutenones

Chen, Peng-Hao,Sieber, Joshua,Senanayake, Chris H.,Dong, Guangbin

, p. 5440 - 5445 (2015)

Here we report a reagent-free rhodium-catalyzed ring-expansion reaction via C-C cleavage of cyclobutenones. A variety of poly-substituted cyclopentenones and 1-indanones can be synthesized from simple cyclobutenones and benzocyclobutenones. The reaction condition is near pH neutral without additional oxidants or reductants. The potential for developing a dynamic kinetic asymmetric transformation of this reaction has also been demonstrated. Further study supports the proposed pathway involving Rh-insertion into the cyclobutenone C-C bond, followed by β-hydrogen elimination, olefin insertion and reductive elimination.

Geometry constrained N-(5,6,7-trihydroquinolin-8-ylidene)arylaminopalladium dichloride complexes: Catalytic behavior toward methyl acrylate (MA), methyl acrylate-co-norbornene (MA-co-NB) polymerization and heck coupling

Zeng, Yanning,Mahmood, Qaiser,Liang, Tongling,Sun, Wen-Hua

, (2016)

A new pair of plladium complexes (Pd4 and Pd5) ligated with constrained N-(5,6,7-trihydroquinolin-8-ylidene)arylamine ligands have been prepared and well characterized by 1H-, 13C-NMR and FTIR spectroscopies as well as elemental analysis. The molecular structure of Pd4 and Pd5 in solid state have also been determined by X-ray diffraction, showing slightly distorted square planar geometry around the palladium metal center. All complexes Pd1-Pd5 are revealed highly efficient catalyst in methyl acrylate (MA) polymerization as well as methyl acrylate/norbornene (MA/NB) copolymerization. In the case of MA polymerization, as high as 98.4% conversion with high molecular weight up to 6282 kg·mol-1 was achieved. Likewise, Pd3 complex has good capability to incorporate about 18% NB content into MA polymer chains. Furthermore, low catalyst loadings (0.002 mol %) of Pd4 or Pd5 are able to efficiently mediate the coupling of haloarenes with styrene affording up to 98% conversion.

Catalytic application of zwitterionic palladium complexes in Mizoroki-Heck reactions using ionic liquid as solvent

Wang, Yi-Ping,Lee, Hon Man

, p. 90 - 98 (2015)

New ligand precursors with different pendent alky chain length were obtained in a single step by reacting appropriate 1-alkyl-2-methyl-1H-imidazoles with chloroacetone in THF at 80°C overnight. Zwitterionic palladium complexes were prepared by reacting Pd

Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

Babu, Reshma,Balaraman, Ekambaram,Midya, Siba P.,Subaramanian, Murugan,Yadav, Vinita

, p. 7552 - 7562 (2021/06/28)

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.

Custom-Made Pyrene Photocatalyst-Promoted Desulfonylation of Arylethenyl Sulfones Using Green-Light-Emitting Diodes

Watanabe, Hikaru,Nakajima, Kazuki,Ekuni, Kento,Edagawa, Ryota,Akagi, Yuta,Okuda, Yasuhiro,Wakamatsu, Kan,Orita, Akihiro

, p. 2984 - 2994 (2021/03/04)

The Sonogashira coupling of 1,3,6,8-tetrabromopyrene with 4-[(-)-β-citronellyloxy]phenylethyne was employed to synthesize 1,3,6,8-tetra[4-(citronellyloxy)phenylethynyl]pyrene. The pyrene derivative catalyzed the reductive desulfonylation of ethenyl sulfones via visible-light irradiation (514 nm green light-emitting diodes) in the presence of i -Pr 2NEt. The β-citronellyloxy groups provided the sufficient solubility to the highly π-expanded pyrene catalyst, and their polar oxygen functionalities enabled the easy separation of the catalyst from the products via column chromatography.

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