15879-93-3 Usage
Description
Chloralose, (R)-1,2-O-(2,2,2-trichloroethylidene)-
α-D-glucofuranose, is a crystalline powder which is soluble in water,
fairly soluble in alcohol, diethyl ether, glacial acetic acid,
sparingly soluble in chloroform, practically insoluble in
petroleum ether.Chloralose is produced by reaction of glucose with waterfree
chloral under heating (21).
Chemical Properties
needle-like crystals or powder
Uses
Different sources of media describe the Uses of 15879-93-3 differently. You can refer to the following data:
1. Coating seeds to protect them from birds.
2. It has been employed widely as an animal anesthetic in the laboratory setting. alpha-chloralose is a true anesthetic or an immobilizing agent with sedative-hypnotic properties has important implications. Canada geese (Branta canadensis) and blue geese (Chen caerulescens) were caught with alpha-chloralose, an oral hypnotic administered on bait. Wild turkeys (Meleagris gallopavo) were captured with alpha-chloralose, an oral anesthetic.
3. Chloralose is used for the control of rodents, particularly mice, and
as a bird repellent and a bird narcotic.
Hazard
May cause addiction, highly toxic.
Safety Profile
Poison by ingestion,
subcutaneous, and intraperitoneal routes.
Questionable carcinogen with experimental
tumorigenic data. When heated to
decomposition it emits toxic fumes of Cl-.
Metabolic pathway
Chloralose is effectively a chloral generator which, in turn, affords trichloroethanol
by metabolism. This is the narcotic agent. Sleep is induced in
mice before death and therefore the compound is regarded as a humane
mouse killer. It is particularly effective when a quick clearout is required
but there is evidence that mice can become tolerant.
Degradation
Chloralose is hydrolysed by acid and base to glucose and chloral (2, trichloroacetaldehyde).
Check Digit Verification of cas no
The CAS Registry Mumber 15879-93-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,8,7 and 9 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 15879-93:
(7*1)+(6*5)+(5*8)+(4*7)+(3*9)+(2*9)+(1*3)=153
153 % 10 = 3
So 15879-93-3 is a valid CAS Registry Number.
InChI:InChI=1/C8H11Cl3O6/c9-8(10,11)7-16-5-3(14)4(2(13)1-12)15-6(5)17-7/h2-7,12-14H,1H2/t2-,3+,4-,5-,6-,7-/m1/s1
15879-93-3Relevant articles and documents
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White,Hixon
, p. 2438,2443 (1933)
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Pictet,Reichel
, p. 621,623, 626 (1923)
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Glucofuranose derivatives as a library for designing and investigating low molecular mass organogelators
Luboradzki, Roman,Pakulski, Zbigniew,Sartowska, Bozena
, p. 10122 - 10128 (2005)
We designed and synthesized a class of saccharide-based gelators having three free OH groups in the glucofuranose fragment. The gelating abilities of fourteen compounds were examined to systematically study the influence of the hydrophobic fragment connected to the C2′ carbon. Also the correlation between the saccharide crystal structure and its gelating properties was examined, showing limited usefulness in this particular case. SEM observations were carried out in order to investigate the hierarchical structure of xerogels and changes depending on different gel concentration.
Herbicidal composition containing dioxolane, dioxane, or dioxepane derivatives as antidote
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, (2008/06/13)
The invention relates to a herbicidal composition which contains, besides binding, wetting, dispersing, emulsifying agents, solvents and/or surface-active substances, herbicides as active agent of thiocarbamate, carbamate, acid amide or urea type alone or in a combination, furthermore as antidote a compound of the general formula I STR1 wherein R1 and R2, independently of each other, are hydrogen, C1-6 alkyl, C2-6 alkenyl, C1-4 cyanoalkyl, C1-6 haloalkyl, phenyl-C1-4 -haloalkyl, phenyl, halogenphenyl, C1-4 -alkyl-phenyl, C1-4 -alkoxyphenyl, furfuryl; R3 and R4, independently of each other, are hydrogen, C1-18 -alkyl, C2-4 -haloalkyl, C2-4 -cyanoalkyl, C1-4 -alkoxy-C2-4 -alkyl, C5-6 -cycloalkyl, phenyl-C1-4 -alkyl, C3-4 -alkenyl, phenyl-C3-4 -alkenyl, di-C1-4 -alkylamino-C2-4 -alkyl, hydroxy-C2-6 -alkyl, furfuryl, tetrahydrofurfuryl, C1-4 -alkoxy-C2-4 -alkoxy-C2-4 -alkyl; R3 and R4, together, are C2-4 -alkylene, C4 -alkenylene, glucofuranosylene, acetoxy-C3 -alkylene, C1-4 -alkoxy-C3 -alkylene, hydroxy-C3 -alkylene, halogen-C3 -alkylene; wherein the quantity of the antidote lies between 0.01 and 15 parts by weight referred to 1 part by weight of herbicidal agent, furthermore the composition contains altogether 0.1 to 95 percent by weight of the herbicidal agents and the antidote.
