15967-72-3Relevant articles and documents
Polymethacrylic zinc porphyrin: A new approach to chiral recognition
Angiolini, Luigi,Benelli, Tiziana,Giorgini, Loris
experimental part, p. 204 - 209 (2012/01/15)
A methacrylic homopolymer bearing in the side-chain achiral zinc tetraarylporphyrin moieties, has been studied as macromolecular chromophoric host to determine the absolute configuration of α,ω-diamines. The polymeric material resulted able to bind the ch
SYNTHESIS OF CHIRAL 1,2-DIAMINES
Bruni, Elena,Cardillo, Giuliana,Orena, Mario,Sandri, Sergio,Tomasini, Claudia
, p. 1679 - 1682 (2007/10/02)
(1'S,5R,S)-(1'-phenyleth-1'-yl)-5-iodomethyl-imidazolines 4a, b have been synthesised and easily resolved by silica gel chromatography.The correlation between the configuration and the 1H-NMR chemical shifts allows to assign the configuration at the C-5 of these intermediates.Each pure diastereomer has been converted to R(-)- and to S(+)-1,2-propyldiamine, respectively.