1605-17-0

Usage

Structure

A brominated aromatic compound containing a benzene ring with a bromine atom at the 1-position and a cyclohexene group at the 4-position.

Reactivity

Highly reactive due to the presence of the bromine atom and the cyclohexene group.

Versatility

Can undergo various chemical transformations, such as nucleophilic substitution and addition reactions.

Applications

Commonly used in organic synthesis and chemical reactions to form a wide range of different products.

Intermediate

Used as an intermediate in the production of pharmaceuticals, agrochemicals, and other fine chemicals.

Importance

Plays a crucial role in the synthesis of various biologically active molecules and materials in the field of organic chemistry.

Upstream product

• 108-94-1 cyclohexanone 
• 106-40-1 4-bromo-aniline 
• 110-83-8 cyclohexene 
• 106-37-6 1.4-dibromobenzene 
• 18620-02-5 (4-bromophenyl)magnesium bromide 
• 19920-80-0 1-(4-bromophenyl)cyclohexan-1-ol 

Downstream Products

• 1837-03-2 1,4-di-cyclohex-1-enyl-benzene 
• 1605-15-8 1-p-bromophenyl-1,2-epoxycyclohexane 
• 20029-52-1 4-cyclohexylbenzoic acid 
• 19920-83-3 4-cyclohex-1-enyl-benzoic acid 
• 1321159-59-4 6-(4-nitrophenylamino)-1-(4-bromophenyl)cyclohexene 
• 61719-38-8 6-(4-bromophenyl)-6-oxohexanenitrile 
• 1269247-00-8 6-benzyloxy-1-(4-bromophenyl)cyclohexene 
• 25109-28-8 4-bromo(cyclohexyl)benzene 
• 6728-41-2 4-(p-Cyclohexen-⁽¹⁾-yl-phenyl)-3-hydroxy-buttersaeureethylester 
• 7045-20-7 4-(p-Cyclohexen-⁽¹⁾-yl-phenyl)-3-hydroxy-buttersaeurenitril 
• 6725-37-7 β-hydroxy-γ-(4-cyclohex-1-enylphenyl)butyric acid 
• 97127-77-0 2-p-bromophenyl-2-benzylaminocyclohexan-1-one hydrochloride 
• 96783-20-9 2-p-bromophenyl-2-aminocyclohexan-1-one hydrochloride 
• 96783-35-6 2-p-bromophenyl-2-benzamidocyclohexan-1-one 

Relevant academic research and scientific papers

One-Pot Dual Catalysis of a Photoactive Coordination Polymer and Palladium Acetate for the Highly Efficient Cross-Coupling Reaction via Interfacial Electron Transfer

We report herein an exploration of the straightforward one-pot dual-catalysis strategy, i.e., direct combination of a photoactive coordination polymer (CP) with another metal catalyst, for carrying out the desirable photoinduced organic transformation. Th

Sulfur mediated allylic C-H alkylation of tri- and disubstituted olefins

A novel transition-metal-free, sulfur mediated allylic C-H alkylation reaction through a one-pot procedure involving an ene-like step between simple olefins and activated sulfoxides to generate allylic sulfonium intermediates, and a subsequent [2,3]-sigmatropic rearrangement step under basic conditions to give allylic C-H alkylation products, has been developed. This method is applicable to tri- and disubstituted olefin substrates in both inter- and intramolecular fashions.

Enantioselective photoredox catalysis enabled by proton-coupled electron transfer: Development of an asymmetric aza-pinacol cyclization

The first highly enantioselective catalytic protocol for the reductive coupling of ketones and hydrazones is reported. These reactions proceed through neutral ketyl radical intermediates generated via a concerted proton-coupled electron transfer (PCET) event jointly mediated by a chiral phosphoric acid catalyst and the photoredox catalyst Ir(ppy)2(dtbpy)PF6. Remarkably, these neutral ketyl radicals appear to remain H-bonded to the chiral conjugate base of the Bronsted acid during the course of a subsequent C-C bond-forming step, furnishing syn 1,2-amino alcohol derivatives with excellent levels of diastereo- and enantioselectivity. This work provides the first demonstration of the feasibility and potential benefits of concerted PCET activation in asymmetric catalysis.

FeCl3/Nal-catalyzed allylic C-H oxidation of arylalkenes with a catalytic amount of disulfide under air

This paper describes a FeCl3/NaI-catalyzed formal allylic C-H oxidation of arylalkenes using a catalytic amount of disulfide with BnOH and 4-nitroaniline as nucleophiles and air as oxidant to form the corresponding allyl ethers and amines. A possible reaction mechanism has been proposed.

Chiral cyclohexyl compounds

The present invention describes liquid crystal compounds which are suitable for use in liquid crystal devices including those which exploit the electroclinic effect.