17898-21-4

Basic information

• Product Name: Allyltriethylsilane
• Synonyms: Allyltriethylsilane
• CAS NO: 17898-21-4
• Molecular Formula: C₉H₂₀Si
• Molecular Weight: 156.3406
• Mol File: 17898-21-4.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 168°C(lit.)
• Appearance: /
• Refractive Index: 1.4410-1.4450
• CAS DataBase Reference: Allyltriethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: Allyltriethylsilane(17898-21-4)
• EPA Substance Registry System: Allyltriethylsilane(17898-21-4)

Safety Data

• RIDADR: 1993
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 17898-21-4(Hazardous Substances Data)

Usage

General Description

Allyltriethylsilane is a chemical compound with the molecular formula C10H22Si. It is an organosilicon compound that consists of a silicon atom bonded to three ethyl groups and one allyl group. It is commonly used as an allylating agent in organic synthesis, particularly in the production of complex molecules such as pharmaceuticals and agrochemicals. Allyltriethylsilane is known for its ability to facilitate allylation reactions, where the allyl group is transferred onto a carbon-containing substrate in the presence of a suitable catalyst. Allyltriethylsilane is valued for its versatile reactivity and its role in the formation of carbon-carbon bonds.

Upstream product

• 994-30-9 triethylsilyl chloride 
• 1730-25-2 allylmagnesium bromide 
• 617-86-7 triethylsilane 
• 624-65-7 2-propynyl chloride 
• 762-72-1 allyl-trimethyl-silane 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 
• 591-87-7 Allyl acetate 
• 1746-13-0 allyl phenyl ether 
• 18146-00-4 allyloxytrimethylsilane 
• 187737-37-7 propene 
• 925-90-6 ethylmagnesium bromide 
• 101519-12-4 sodiumtris(benzene-1,2 diolato)silicate 
• 463-49-0 1,2-propanediene 

Downstream Products

• 124494-12-8 1-methoxy-4-(1-phenylbut-3-en-1-yl)benzene 
• 1112-48-7 triethyl-bromo-silane 
• 7688-51-9 N,N-bis(trimethylsilyl)allylamine 
• 106-95-6 allyl bromide 
• 18759-16-5 1,3-Diaethyl-1,3-diphenyl-1,3-bis-<3-triaethylsilyl-propyl>-disiloxan 
• 18759-17-6 1,3-Diaethyl-1,3-diphenyl-1,3-bis-<3-triaethylsilyl-propyl>-disilthian 
• 18759-19-8 1,3-Diaethyl-1,3-diphenyl-1,3-bis-<3-triaethylsilyl-propyl>-disilazan 
• 185809-92-1 [Pd(1,10-phenanthroline)(Si(C2H5)3)(η(2)-allyltriethylsilane)]B(C8H3F6)4 
• 185809-86-3 [Pd(1,10-phenanthroline)(Si(C6H5)3)(η(2)-allyltriethylsilane)]B(C8H3F6)4 
• 1219613-75-8 [2-(4-chlorophenyl)pent-4-enyl]triethylsilane 
• 1246169-41-4 trimethyl(2-((1-phenylbut-3-en-1-yl)oxy)ethoxy)silane 
• 1246169-42-5 trimethyl(2-((3-methyl-1-phenylbut-3-en-1-yl)oxy)ethoxy)silane 
• 1246169-43-6 C₁₈H₃₀O₂Si 
• 1246169-44-7 C₁₉H₃₂O₂Si 

Relevant articles and documents

REACTION OF TRIETHYLSILANE WITH PROPARGYL CHLORIDE IN THE PRESENCE OF THE H2PtCl6-I2 CATALYTIC SYSTEM

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Synthesis and reactions of donor cyclopropanes: efficient routes to cis- and trans-tetrahydrofurans

Abstract A detailed study on the synthesis and reactions of silylmethylcyclopropanes is reported. In their simplest form, these donor-only cyclopropanes undergo Lewis acid promoted reaction to give either cis- or trans-tetrahydrofurans, with the selectivity being reaction condition-dependant. The adducts themselves are demonstrated to be an important scaffold for structural diversification. The combination of a silyl-donor group in a donor-acceptor cyclopropane with novel acceptor groups is also discussed.

Mesoporous aluminosilicate-catalyzed allylation of carbonyl compounds and acetals

A mesoporous aluminosilicate (Al-MCM-41) was found to be an effective heterogeneous catalyst for the reaction of both carbonyl compounds and acetals with allylsilanes to afford the corresponding homoallyl silyl ethers and homoallyl alkyl ethers, respectively. Both the mesoporous structure and the presence of aluminum moiety were indispensable for the high catalytic activity of Al-MCM-41. Moreover, Al-MCM-41 could catalyze the reaction of acetals chemoselectively in the presence of the corresponding carbonyl compounds. The solid acid catalyst Al-MCM-41 could be recovered easily by filtration and could be reused three times without a significant loss of catalytic activity.

Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes

Pd-catalyzed synthesis of allylsilanes from chlorosilanes and allyl ethers is described. The reaction proceeds efficiently at room temperature by the use of phenyl or vinyl Grignard reagent in the presence of palladium catalysts. The present method can also be applied to synthesis of propargylsilanes by the use of propargyl ethers. Copyright