18227-62-8

Basic information

• Product Name: 3-BENZOYLAMINOBUTANONE
• Synonyms: 3-BENZOYLAMINOBUTANONE;RARECHEM AQ A3 0030;N-(1-Methyl-2-oxo-propyl)-benzamide
• CAS NO: 18227-62-8
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.23
• Mol File: 18227-62-8.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-BENZOYLAMINOBUTANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BENZOYLAMINOBUTANONE(18227-62-8)
• EPA Substance Registry System: 3-BENZOYLAMINOBUTANONE(18227-62-8)

Safety Data

• Hazardous Substances Data: 18227-62-8(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 2814, 1955 DOI: 10.1021/ja01615a042

Upstream product

• 20662-83-3 4,5-dimethyl-oxazole 
• 98-88-4 benzoyl chloride 
• 2198-64-3 N-Benzoylalanine 
• 133957-65-0 N-(but-3-en-2-yl)-benzamide 
• 51127-13-0 2-phenyl-4-methyl-4H-oxazolin-5-one 
• 17153-00-3 5-acetyloxy-4-methyl-2-phenyloxazole 
• 917-54-4 methyllithium 
• 506-96-7 Acetyl bromide 
• 17153-02-5 rac-4-acetyl-4-methyl-2-phenyloxazol-5-one 
• 108-24-7 acetic anhydride 
• 50996-03-7 benzamidoacetone 
• 74-88-4 methyl iodide 

Downstream Products

• 26028-53-5 4,5-dimethyl-2-phenyl-oxazole 
• 37557-72-5 3-benzamido-3-methylbutan-2-one 
• 21419-24-9 3-Amino-2-butanone hydrochloride 
• 90127-53-0 2-phenyl-4,5-bis(bromomethyl)oxazole 
• 1826-24-0 4,5-dimethyl-2-phenyl-1,3-thiazole 

Relevant articles and documents

Aldehyde selective Wacker oxidations of phthalimide protected allylic amines: A new catalytic route to β3-amino acids

(Chemical Equation Presented) A new method for the synthesis of β3-amino acids is presented. Phthalimide protected allylic amines are oxidized under Wacker conditions selectively to aldehydes using PdCl2 and CuCl or Pd(MeCN)2/s

A versatile synthesis of 3-phenylsulfonylpyrroles from α-amino acids

Reaction between α-benzamidoalkyl ketones 4a-e and the vinyl phosphonium salt 1 produces 3-phenylthio-3-pyrrolines 5a-e which can be converted into N-benzyl-3-phenylsulfonyl pyrroles 7a-e by m-CPBA oxidation, diborane reduction and DDQ aromatisation.