18245-74-4

Upstream product

• 108-98-5 thiophenol 
• 103-80-0 phenylacetyl chloride 
• 10557-67-2 N-nitroso-p-methyl-acetanilide 
• 104411-45-2 phenyl phenyldithioacetate 
• 120346-64-7 (E)-3-phenyl-2-phenylsulphonyl-2-phenylthiooxirane 
• 103-82-2 phenylacetic acid 
• 882-33-7 diphenyldisulfane 
• 5285-87-0 phenyl thiocyanate 
• 7205-94-9 chloromethyl phenyl sulfoxide 
• 100-39-0 benzyl bromide 
• 3561-67-9 bis(phenylthio)methane 
• 100-44-7 benzyl chloride 
• 98-09-9 benzenesulfonyl chloride 
• 14040-11-0 tungsten hexacarbonyl 

Downstream Products

• 139-66-2 diphenyl sulfide 
• 108-98-5 thiophenol 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 108-88-3 toluene 
• 92-52-4 biphenyl 
• 71-43-2 benzene 
• 104411-45-2 phenyl phenyldithioacetate 
• 61173-91-9 1-phenyl-2-(phenylthio)-1-butene 
• 16619-61-7 1-phenyl-2-phenylthioethene 

Relevant academic research and scientific papers

Synthesis of Thiol Esters Using PhSZnBr as Sulfenylating Agent: A DFT-Guided Optimization of Reaction Conditions

The use of PhSZnBr as sulfenylating agent in a solvent-free protocol to prepare thiol esters in excellent yields from acyl chlorides is reported. The products were efficiently obtained by grinding the neat reagents for 5 min in a mortar. DFT calculations

Method for preparing thioester compounds through carbonylation

The invention discloses a method for preparing thioester compounds through carbonylation, wherein the method comprises the following steps: adding palladium acetate, 4,5-bis(diphenylphosphine)-9,9-dimethyl xanthene, tungsten carbonyl, triethylamine, water, a benzyl chloride compound and sulfonyl chloride into an organic solvent, collecting, reacting at the temperature of 100 DEG C for 24 hours, and after the reaction is completed, performing post-treatment to obtain the thioester compounds. The preparation method is simple to operate, the initial raw materials of the reaction are cheap and easy to obtain, sulfonyl chloride is used as a sulfur source, and a thiol compound with unpleasant smell can be prevented from being used. The substrate is high in designability, the tolerance range of functional groups of the substrate is wide, and the reaction efficiency is high. Tungsten carbonyl can be used as a carbonyl source and a reducing agent, and an additional reducing agent is not needed. Various thioester compounds can be synthesized according to actual requirements, so that the practicability of the method is widened while the operation is convenient.

Synthesis of selenol esters via the reaction of acyl chlorides with diselenides in the presence of Zn dust catalyzed by CoCl2·6H2O

A practical and efficient approach for the synthesis of selenol and thiol esters is described via the reaction of acyl chlorides with diselenides or disulfides in the presence of Zn dust catalyzed by inexpensive CoCl2·6H2O This proto

Palladium-Catalyzed Thiocarbonylation of Benzyl Chlorides with Sulfonyl Chlorides for the Synthesis of Arylacetyl Thioesters

A convenient procedure for the synthesis of thioesters has been developed via a palladium-catalyzed thiocarbonylation of benzyl chlorides with sulfonyl chlorides. Various arylacetyl thioesters were produced in good yields by using sulfonyl chlorides as an odorless sulfur source. Furthermore, W(CO)6 exhibited dual roles as both a solid CO surrogate and reductant here. (Figure presented.).

An efficient synthesis of thioesters via TFA-catalyzed reaction of carboxylic acid and thiols: Remarkably facile C-S bond formation

A general, facile, and efficient new synthetic path to thioesters was established by employing defined TFA-catalyzed reaction of carboxylic acid and thiol under mild conditions. The structure of the newly synthesized compounds was determined by infrared spectroscopy, nuclear magnetic resonance, and a single crystal X-ray crystallographic analysis. Supplemental materials are available for this paper. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. Copyright

On water preparation of phenylselenoesters

PhSeZn-halides react under "on water" mild conditions with acid chlorides to provide a high yield route to a variety of aromatic and aliphatic phenylselenoesters.

Rapid and regiospecific phenylthiolation of some organic acids catalyzed by AlCl3 in the presence of excess anhydrous ZnCl2

Phenylthiolation of some carboxylic acids catalyzed by AlCl3 in the presence of excess dehydrating agent (ZnCl2) has been achieved. Moreover, regiospecificity was tested of some dioic acids and found to be specific at the aliphatic p

Silica-promoted facile synthesis of thioesters and thioethers: A highly efficient, reusable and environmentally safe solid support

An efficient, mild and rapid procedure for the acylation and alkylation of aromatic and aliphatic thiols mediated on a silica gel surface at room temperature is described. The protocol allows the protection of thiols under neutral heterogeneous conditions without requiring any bases or Lewis acids, and the silica gel used as the promoter can be recycled for several runs without any loss of activity.

Synthesis of chalcogenol esters from chalcogenoacetylenes

Thiol and selenol esters were conveniently prepared in good yields by reacting chalcogenoacetylenes with trifluoroacetic acid in dichloromethane in the presence of silica.

Kinetics and mechanism of the aminolysis of aryl phenyldithioacetates in acetonitrile

The aminolysis reactions of Z-aryl phenyldithioacetates (C6H5CH2C(=S)SC6H4Z) with benzylamines (XC6H4CH2NH2) are investigated in acetonitrile at -25.0 °C. T