19275-80-0

Basic information

• Product Name: 2-oxo-1-phenylpropyl acetate
• Synonyms: 2-Oxo-1-phenylpropyl acetate; 2-propanone, 1-(acetyloxy)-1-phenyl-
• CAS NO: 19275-80-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.2112
• Mol File: 19275-80-0.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 272.5°C at 760 mmHg
• Flash Point: 115.5°C
• Density: 1.11g/cm³
• Vapor Pressure: 0.00608mmHg at 25°C
• Refractive Index: 1.506
• CAS DataBase Reference: 2-oxo-1-phenylpropyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-oxo-1-phenylpropyl acetate(19275-80-0)
• EPA Substance Registry System: 2-oxo-1-phenylpropyl acetate(19275-80-0)

Safety Data

• Hazardous Substances Data: 19275-80-0(Hazardous Substances Data)

Upstream product

• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 64-19-7 acetic acid 
• 56955-33-0 1-methoxy-2-phenylcyclopropanol 
• 67-56-1 methanol 
• 109-63-7 trifluoroborane diethyl ether 
• 76-03-9 trichloroacetic acid 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 5910-25-8 3-phenylpentane-2,4-dione 
• 116119-86-9 (S)-(-)-1-phenylprop-2-yn-1-yl acetate 
• 1073233-53-0 C₁₉H₂₀O₂ 
• 1798-60-3 (R)-1-hydroxy-1-phenyl-2-propanone 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 100-52-7 benzaldehyde 

Downstream Products

• 1798-60-3 (R)-1-hydroxy-1-phenyl-2-propanone 
• 1262149-40-5 C₁₁H₁₃NO₃ 
• 1855-09-0 1-phenyl-1,2-propandiol 
• 4773-35-7 1-chloro-1-phenylpropan-2-one 
• 5703-17-3 1-phenyl-2-piperidin-1-yl-propan-1-one 
• 90-63-1 (RS)-1-hydroxy-1-phenylpropan-2-one 

Relevant articles and documents

Homogeneous and Nanoparticle Gold-Catalyzed Hydrothiocyanation of Haloalkynes

The first homogeneous and heterogeneous nanoparticle gold-catalyzed addition of sulfur nucleophiles to alkynes was developed. More specifically, gold-catalyzed hydrothiocyanation of haloalkynes gave good yields and good stereoselectivity of vinyl thiocyanates. Furthermore, a sulfur-based gold catalyst (PPh3AuSCN) has shown a unique reactivity in gold-catalyzed reactions such as the cyclization of N-propargylic amides.

Gold(I) Complexation of Phosphanoxy-Substituted Phosphaalkenes for Activation-Free LAuCl Catalysis

The phosphanoxy-substituted phosphaalkene bearing the P=C?O?P skeleton can be prepared from diphosphene Mes*P=PMes* (Mes=2,4,6-tBu3C6H2), and their use for catalysis is of interest. In this paper, complexation of the phosp

Silica-Supported Phosphine–Gold Complexes as an Efficient Catalytic System for a Dearomative Spirocyclization

The combination of metal catalyst and inorganic silica frameworks provides a greener approach to recyclable catalysis. In this study, three phosphine–gold chloride complexes have been successfully covalently grafted onto chiral silica nanohelices. The resulting 3D ensembles showed chiroptical properties that allowed the monitoring of the supported ligands. The heterogeneous gold chloride catalysts in cooperation with silver triflate exhibited high reactivity in various reactions, especially in the spirocyclization of aryl alkynoate esters, for which a catalytic loading of 0.05 mol % could be employed. The heterogeneous catalysts could be easily recovered and recycled seven or eight times without any loss of efficiency. By adding more silver triflate, 25 cycles with full conversion were achieved owing to a complex catalytic system based on silica and metallic species.

Coinage Metal (Bisfluorosulfonyl)imide Complexes: Preparation, Characterization, and Catalytic Applications

Triflate (–OTf) and triflimide (–NTf2) represent two most widely used weakly coordinating counteranions in transition metal catalysis, yet their high price hinders large-scale application. Herein, we report the preparation, characterization, and catalytic applications of silver(I), gold(I), and copper(II) (bisfluorosulfonyl)imide (–FSI) complexes, showing –FSI as a low cost alternative of –OTf and –NTf2. These complexes, including AgFSI·2MeCN (1), AgFSI·MeCN (2), AgFSI·H2O (3), (AgFSI)6·(H2O)4 (4), AgFSI (5), LAuFSI (6a–6e), and CuFSI2·4H2O (7), are prepared conveniently starting from KFSI, an inexpensive chemical, and shown interesting structural features and some unprecedented coordination modes. In comparison with the corresponding coinage metal triflimides, the FSI complexes have exhibited comparable or better catalytic performance in a series of the model chemical transformations.