1934-75-4

Basic information

• Product Name: Sodium dicyanamide
• Synonyms: CyanaMide, N-cyano-,sodiuM salt (1:1);SodiuM dicyanaMide (DCD sodiuM);SodiuM DicyanaMide, 97+%;Sodium dicyamide;SODIUM DICYANAMIDE;SODIUM DICYANOAMIDE;NADCA;DICYANAMIDE,SODIUM SALT
• CAS NO: 1934-75-4
• Molecular Formula: C₂N₃Na
• Molecular Weight: 89.03
• EINECS: 217-703-5
• Product Categories: Pyridines;C-X Bond Formation (Non-Halogen);Others;Synthetic Reagents;Hydrocyanic acid derivatives;Various hydrocyanic acid derivatives
• Mol File: 1934-75-4.mol
• Article Data: 3

Chemical Properties

• Melting Point: 300 °C
• Boiling Point: 41.5 °C at 760 mmHg
• Flash Point: 8.5 °C
• Appearance: White to off-white powder
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility: Methanol (sparingly), Water
• Water Solubility: 260 g/L (30 ºC)
• Sensitive: Hygroscopic
• BRN: 3913818
• CAS DataBase Reference: Sodium dicyanamide(CAS DataBase Reference)
• NIST Chemistry Reference: Sodium dicyanamide(1934-75-4)
• EPA Substance Registry System: Sodium dicyanamide(1934-75-4)

Safety Data

• Hazard Codes: Xn,Xi
• Statements: 22-36/37/38
• Safety Statements: 26-36-37/39
• RIDADR: UN 3077
• WGK Germany: 1
• F: 3
• TSCA: Yes
• Hazardous Substances Data: 1934-75-4(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
Sodium dicyanamide is used as a reactant for the production of various pharmaceuticals, including chlorhexidine, biguanide, proguanil, and alexidine. It plays a crucial role in the synthesis of these drugs, contributing to their medicinal properties and effectiveness.
Used in Coordination Chemistry:
Sodium dicyanamide is used as a reactant for the preparation of various coordination polymers and complexes, such as:
1. Nickel diacetylpyridine dioximate pentanuclear, octanuclear, and decanuclear cluster complexes.
2. Decanuclear manganese(II/III) oxo azide diolate clusters, which serve as supertetrahedral building blocks to design extended magnetic networks.
3. Ruthenium bipyridine complexes entrapped in iron and manganese dicyanamide two-dimensional anionic sheet-like coordination polymeric networks, exhibiting dual emission photoluminescence.
4. Lead dicyanamide-bridged nitronyl nitroxide radical polymeric complex.
5. Antiferromagnetically coupled hexanuclear copper(II) Schiff base complexes with dicyanamido bridges.
6. CuII2L-based polymeric ladders using dicyanamide bridges.
7. Luminous hexacoordinated coordination polymers of cadmium(II), containing dicyanamide bridges.
These applications highlight the versatility of sodium dicyanamide in different industries, particularly in the development of novel materials with unique properties and potential applications in various fields.

InChI:InChI=1/C2N3.Na/c3-1-5-2-4;/q-1;+1/rC2N3Na/c3-1-5(6)2-4

Synthetic route

CYANAMID (420-04-2) + cyanogen chloride (506-77-4) → sodium N-cyanoisourea (76989-89-4) + sodium dicyanamide (1934-75-4) + sodium chloride (7647-14-5)

Conditions	Yield
With sodium hydroxide In water at 70 - 75℃; under 1050.11 Torr; pH=7.2 - 8.0; Purification / work up;	A n/a B 94% C n/a

CYANAMID (420-04-2) + cyanogen chloride (506-77-4) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With sodium hydroxide In water at 50 - 55℃; under 1050.11 Torr; pH=7.2 - 8.0;	87%
With sodium hydroxide In water at 70 - 75℃; under 1050.11 Torr; pH=7.2 - 8.0; Product distribution / selectivity;	83%
With sodium hydroxide In water at 70 - 75℃; under 1050.11 Torr; pH=7.2 - 8.0; Product distribution / selectivity;	82%
With sodium hydroxide In water at 50 - 55℃; under 1050.11 Torr; pH=7.2 - 8.0; Product distribution / selectivity;	79%
With sodium hydroxide In water at 70 - 75℃; for 1.58333h; pH=7.5 - 8.0;	76%

bromocyane (506-68-3) + CYANAMID (420-04-2) → sodium dicyanamide (1934-75-4)

Conditions	Yield
Stage #1: CYANAMID With sodium In ethanol at 20℃; for 1.5h; Stage #2: bromocyane In ethanol for 2.5h;	72%

bromocyane (506-68-3) + sodium cyanamide (19981-17-0, 20611-81-8, 123092-13-7, 17292-62-5) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With water

bromocyane (506-68-3) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With sodium amide in der Kugelmuehle;

sodium salt of O-ethyl-N-cyano-isourea → sodium dicyanamide (1934-75-4)

cyanogen chloride (506-77-4) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With sodium amide In not given byproducts: NH3, NaCl; at room temp., in ball mill;

sodium amide + cyanogen chloride (506-77-4) → sodium dicyanamide (1934-75-4)

Conditions	Yield
byproducts: NH3, NaCl; in ball mill; reactn. complete after 60 h at room temp.;
byproducts: NH3, NaCl; in ball mill; reactn. complete after 60 h at room temp.;

sodium amide + cyanogen chloride (506-77-4) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;

disodium cyanamide (20611-81-8) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With NCBr In neat (no solvent) grinding in ball mill;;
With NCBr In neat (no solvent) grinding in ball mill;;

bromocyane (506-68-3) + disodium cyanamide (20611-81-8) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In water addn. of aq. Na2NCN soln. to CNBr with cooling up to neutral soln.; evapn. on the water-bath;; recrystn. from ethanol;;

copper(II) dicyanamide (14890-16-5, 18447-47-7, 21962-69-6) + sodium phosphate → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

dicyanamide; calcium-bis-(dicyano-amide) (14723-18-3) + sodium phosphate → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

zinc dicyanamide + sodium phosphate → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

bromocyane (506-68-3) + sodium amide → sodium dicyanamide (1934-75-4)

Conditions	Yield
byproducts: NH3, NaBr; in ball mill; reactn. complete after 60 h at room temp.;
byproducts: NH3, NaBr; in ball mill; reactn. complete after 60 h at room temp.;

bromocyane (506-68-3) + CYANAMID (420-04-2) → {NHC(NHCN)(OC2H5)}(1-)*Na(1+)={NHC(NHCN)(OC2H5)}Na + sodium dicyanamide (1934-75-4) + sodium bromide (7647-15-6)

Conditions	Yield
With Na-alcoholate In ethanol
With Na-alcoholate In ethanol

sodium amide + bromocyane (506-68-3) → ammonia (7664-41-7) + sodium dicyanamide (1934-75-4) + sodium bromide (7647-15-6)

sodium amide + bromocyane (506-68-3) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;

cyanogen iodide (506-78-5) → sodium dicyanamide (1934-75-4)

Conditions	Yield
With sodium amide In neat (no solvent) byproducts: NH3, NaI; at room temp., in ball mill, extn. with water;

cyanogen iodide (506-78-5) + sodium amide → sodium dicyanamide (1934-75-4)

Conditions	Yield
byproducts: NH3, NaI; in ball mill; reactn. complete after 60 h at room temp.;
byproducts: NH3, NaI; in ball mill; reactn. complete after 60 h at room temp.;

sodium amide + cyanogen iodide (506-78-5) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;
In neat (no solvent) constantly grinding in ball mill at ambient temp., 60h; complete exclusion of air;;

sodium sulfide + silver dicyanamide (51342-29-1) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In water crystn. from hot MeOH;

copper(II) dicyanamide (14890-16-5, 18447-47-7, 21962-69-6) + sodium hydroxide (1310-73-2) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

dicyanamide; calcium-bis-(dicyano-amide) (14723-18-3) + sodium hydroxide (1310-73-2) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

zinc dicyanamide + sodium hydroxide (1310-73-2) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

copper(II) dicyanamide (14890-16-5, 18447-47-7, 21962-69-6) + sodium carbonate (497-19-8) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

dicyanamide; calcium-bis-(dicyano-amide) (14723-18-3) + sodium carbonate (497-19-8) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In water
In water

dicyanamide; calcium-bis-(dicyano-amide) (14723-18-3) + sodium sulfate (7757-82-6) → sodium dicyanamide (1934-75-4)

Conditions	Yield
In water
In water

sodium carbonate (497-19-8) + zinc dicyanamide → sodium dicyanamide (1934-75-4)

Conditions	Yield
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;
In not given synthesis from dicyanamide suspn. and Na salt soln.; filtration; evapn. under reduced pressure up to crystn.;;

sodium dicyanimide *H2O → sodium dicyanamide (1934-75-4)

Conditions	Yield
In neat (no solvent) byproducts: H2O; at 160°C;;
In neat (no solvent) byproducts: H2O; at 160°C;;

sodium dicyanamide (1934-75-4) + 4-chloro-aniline (106-47-8) → 1-(4-chlorophenyl)-3-cyanoguanidine (1482-62-8)

Conditions	Yield
oxonium; acetic acid In water at 40℃; Rate constant; Mechanism;	100%
With hydrogenchloride In water at 60℃; for 3h;	87%
Stage #1: sodium dicyanamide; 4-chloro-aniline With hydrogenchloride In water at 50 - 90℃; for 18h; Stage #2: With sodium hydrogencarbonate In water for 0.25h;	78.3%

sodium dicyanamide (1934-75-4) + 5-amino-2-methyl-1-(1-ethylpropyl)indole hydrochloride → N-cyano-N'-[2-methyl-1-(1-ethylpropyl)indol-5-yl]guanidine

Conditions	Yield
In N,N-dimethyl-formamide at 50℃; for 4h;	100%

Methyl 3-aminobenzoate (4518-10-9) + sodium dicyanamide (1934-75-4) → methyl 3-[amino(cyanoiminomethyl)]aminobenzoate (93070-47-4)

Conditions	Yield
With hydrogenchloride at 80 - 90℃; for 2h;	100%

sodium dicyanamide (1934-75-4) + 1-n-butyl-3-methylimidazolim bromide (85100-77-2) → 1-buthyl-3-methylimidazolium dicyanamide (448245-52-1)

Conditions	Yield
In acetone at 20℃; for 2h;	100%
Stage #1: sodium dicyanamide With silver nitrate Stage #2: 1-n-butyl-3-methylimidazolim bromide In water

ammonium chloride + sodium dicyanamide (1934-75-4) → ammonium dicyanamide

Conditions	Yield
With ion-exchange resin; silver nitrate In water ion exchange of aq. NH4(N(CN)2) with acidic form of ion-exchange resin umtil the pH is 4-5, washing the resin with water, chloride removal with AgNO3, pouring soln. of sodium dicyanamide onto the column; evapn. the eluate at room temp.;	100%
In water loading aq. soln. of NH4Cl on a column with ion exchange resin (Merck, Ionenaustauscher I, H(+)-Form, Art. 4765), washing with water, loading with a soln. of sodium salt; evapn. at room temp.;	99%
In water ion-exchange column was charged with NH4Cl and NaN(CN)2 soln. was passedthrough; soln. was evapd. at room temp.;

zinc(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) → zinc dicyanamide

Conditions	Yield
In water pptn. on addn. of Zn-salt to 2 equiv. cyanamide (stirring); collection (filtration), drying (vac., over P2O5, 2 h); single crystals from mother liquor;	100%

[Cu(bis(2-pyrimidylcarbonyl)amidate)(H2O)3]NO3*2H2O + water (7732-18-5) + sodium dicyanamide (1934-75-4) → [Cu(bis(2-pyrimidylcarbonyl)amidate)(dicyanamide)(H2O)]2 (1017235-46-9)

Conditions	Yield
In water equimolar aq. soln. of Cu-compound slowly diffused into aq. Na-compound for 1 month at room temp.; elem. anal.;	100%

aniline hydrochloride (142-04-1) + sodium dicyanamide (1934-75-4) → 1-phenyl-3-cyanoguanidine (41410-39-3)

Conditions	Yield
In butan-1-ol Reflux;	100%

1,2-diaminoethane dihydrochloride (333-18-6) + sodium dicyanamide (1934-75-4) → 1,2-bis(N3-cyano-N1-guanidino)ethane (7408-98-2)

Conditions	Yield
In butan-1-ol for 15h; Reflux;	99%
With butan-1-ol

copper(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) + 2-(1H-imidazolyl)pyridine (25700-14-5) → [Cu(II)(2-(2-pyridyl)imidazole)(H2O)(dicyanamide)]n(NO3)n

Conditions	Yield
In water elem. anal.;	99%

[2,2]bipyridinyl (366-18-7) + copper(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) → catena-poly[[(2,2'-bipyridine-κ2-N:N')(dicyanamido-κN)copper(II)]-μ-dicyanamido-κ2-N:N']

Conditions	Yield
In water elem. anal.;	99%

copper(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) + 2,2'-Bipyrimidine (34671-83-5) → [Cu(2,2'-bipyrimidine)(dicyanamide)2]n

Conditions	Yield
In water elem. anal.;	99%

di(pyridin-2-yl)amine (1202-34-2) + copper(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) → [Cu(II)(2,2'-dipyridylamine)(dicyanamide)2]n

Conditions	Yield
In water elem. anal.;	99%

diaqua{bis(2-pyridylcarbonyl)-amido}copper(II) nitrate dihydrate (127887-62-1) + sodium dicyanamide (1934-75-4) → [Cu(bis(2-pyridylcarbonyl)amidate)(H2O)(dicyanamide)]2 (428509-66-4)

Conditions	Yield
In water react. stoich. amts. (Cu(bpca)(H2O)2)NO3*2H2O and sodium dicyanamide; elem. anal.;	99%

copper(II) nitrate trihydrate + 2.9-dimethyl-1,10-phenanthroline (484-11-7) + sodium dicyanamide (1934-75-4) → [Cu2(2,9-dimethyl-1,10-phenanthroline)2(dicyanamide)4] (758716-17-5)

Conditions	Yield
In water addn. of aq. soln. of NaN(CN)2 to aq. soln. of Cu(NO3)2*3H2O and 2,9-dimethyl-1,10-phenanthroline; crystn., elem. anal.;	99%

4,4'-dimethyl-2,2'-bipyridines (1134-35-6) + copper(II) nitrate trihydrate + sodium dicyanamide (1934-75-4) → [Cu(4,4'-dimethyl-2,2'-bipyridine)(dicyanamide)2(H2O)] (758716-19-7)

Conditions	Yield
In water slow diffusion in an H-shaped tube containing aq. soln. Cu(4,4'-dimethyl-2,2'-bipyridine)(NO3)2 (mixt. of Cu(NO3)2*3H2O and 4,4'-dimethyl-2,2'-bipyridine in stoich. amts) in one arm and NaN(CN)2 in the other for 15 days; crystn., elem. anal.;	99%

pyridine-3-carbonitrile (100-54-9) + iron(II) perchlorate hexahydrate + sodium dicyanamide (1934-75-4) → [Fe(dicyanamide)2(3-cyanopyridine)2]n

Conditions	Yield
In methanol; water; acetonitrile powder X-ray diffraction;	99%
In methanol; water; acetonitrile soln. 3-CNpy and Na(N(CN)2) in MeCN-MeOH was heated for 5 min, aq. soln.Fe(ClO4)2*6H2O was added; soln. was filtered and left to stand at room temp. for 3 weeks; elem. anal.;	15%

3-methyl-1-(ethoxyethoxycarbonylmethyl)imidazolium bromide (1122146-50-2) + sodium dicyanamide (1934-75-4) → 3-methyl-1-(ethoxyethoxycarbonylmethyl)imidazolium dicyanoamide (1122146-55-7)

Conditions	Yield
In acetonitrile for 96h; Reflux;	99%

3-methyl-1-(ethoxyethoxyethoxycarbonylmethyl)imidazolium bromide (1122146-78-4) + sodium dicyanamide (1934-75-4) → 3-methyl-1-(ethoxyethoxyethoxycarbonylmethyl)imidazolium dicyanoamide (1122146-83-1)

Conditions	Yield
In acetonitrile for 96h; Reflux;	99%

2,3-dimethyl-1-(methoxyethoxyethoxycarbonylmethyl)imidazolium bromide (1122147-13-0) + sodium dicyanamide (1934-75-4) → 2,3-dimethyl-1-(methoxyethoxyethoxycarbonylmethyl)imidazolium dicyanoamide (1122147-18-5)

Conditions	Yield
In acetonitrile for 96h; Reflux;	99%

1-methyl-3-(11-ethoxycarbonyl-undecyl)imidazolium bromide (1000995-41-4) + sodium dicyanamide (1934-75-4) → [C10O2EtMIM][DCA] (1265530-16-2)

Conditions	Yield
In dichloromethane at 20℃; for 48h;	99%

sodium dicyanamide (1934-75-4) + 1-(2,4-dinitrophenyl)-pyridinium chloride (4185-69-7) → C11H8N3O4(1+)*C2N3(1-)

Conditions	Yield
In methanol at 20℃; for 18h; Inert atmosphere;	99%

sodium dicyanamide (1934-75-4) + silver nitrate → silver dicyanamide (51342-29-1)

Conditions	Yield
In water at 20℃;	98%
In water at 20℃; for 1h; Darkness;	97%
In water	95%

N-methoxylamine hydrochloride (593-56-6) + sodium dicyanamide (1934-75-4) → 1-cyano-2-methoxyguanidine (1108717-36-7)

Conditions	Yield
In ethanol at 20℃;	98%

1-methyl-3-(pentoxycarbonylmethyl)imidazolium bromide (808184-34-1) + sodium dicyanamide (1934-75-4) → 3-methyl-1-(pentoxycarbonylmethyl)imidazolium dicyanoamide

Conditions	Yield
In acetonitrile for 96h; Reflux;	98%

3-{2-[2-(2-butoxyethoxy)ethoxy]-2-oxoethyl}-1-methyl-1H-imidazol-3-ium bromide (1122146-92-2) + sodium dicyanamide (1934-75-4) → 3-methyl-1-(butoxyethoxyethoxycarbonylmethyl)imidazolium dicyanoamide (1122146-97-7)

Conditions	Yield
In acetonitrile for 96h; Reflux;	98%

1-(3-phenoxypropyl)-4-((2-(1-(3-phenoxypropyl)pyridin-1-ium-4‑carbonyl)hydrazono)methyl)pyridin-1-ium bromide + sodium dicyanamide (1934-75-4) → 1-(3-phenoxypropyl)-4-((2-(1-(3-phenoxypropyl)pyridin-1-ium-4‑carbonyl)hydrazono)methyl)pyridin-1-ium dicyanamide

Conditions	Yield
In acetonitrile for 0.166667h; Microwave irradiation;	98%

1-(4-phenoxybutyl)-3-((2-(1-(4-phenoxybutyl)pyridin-1-ium-4‑carbonyl)hydrazono)methyl)pyridin-1-ium bromide + sodium dicyanamide (1934-75-4) → 1-(4-phenoxybutyl)-3-((2-(1-(4-phenoxybutyl)pyridin-1-ium-4‑carbonyl)hydrazono)methyl)pyridin-1-ium dicyanamide

Conditions	Yield
In acetonitrile for 0.166667h; Microwave irradiation;	98%

1‐(2‐methoxyphenyl)‐3‐octyl‐imidazolium bromide + sodium dicyanamide (1934-75-4) → 1‐(2‐methoxyphenyl)‐3‐octyl‐imidazolium dicyanamide

Conditions	Yield
In water at 20℃; for 48h;	98%

3,9-bis(3-aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane dihydrochloride + sodium dicyanamide (1934-75-4) + butan-1-ol (71-36-3) → 3,9-bis(3-cyanoguanidinopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane

Conditions	Yield
	97.5%

Upstream product

• 506-68-3 bromocyane 
• 19981-17-0 sodium cyanamide 
• 420-04-2 CYANAMID 
• 506-77-4 cyanogen chloride 
• 14890-16-5 copper(II) dicyanamide 
• 1310-73-2 sodium hydroxide 
• 14723-18-3 dicyanamide; calcium-bis-(dicyano-amide) 
• 497-19-8 sodium carbonate 
• 7757-82-6 sodium sulfate 
• 1313-82-2 sodium sulfide 
• 51342-29-1 silver dicyanamide 
• 506-78-5 cyanogen iodide 
• 20611-81-8 disodium cyanamide 

Downstream Products

• 99069-43-9 N-benzyl-N'-cyano-N-methyl-guanidine 
• 96146-30-4 1,4-bis-[3-(N'-cyano-guanidino)-propoxy]-benzene 
• 15894-70-9 1,6-di-(N³-cyano-N¹-guanidino)hexane 
• 1609-07-0 1-cyano-3-methyl-guanidine 
• 2220-33-9 N¹-Aethyl-N¹-phenyl-cyanguanidin 
• 457-76-1 N''-cyano-N-(4-fluorophenyl)guanidine 
• 75564-72-6 N''-cyano-N-(2-methoxyphenyl)guanidine 
• 41410-43-9 N''-cyano-N-(2-chlorophenyl)guanidine 
• 1482-62-8 1-(4-chlorophenyl)-3-cyanoguanidine 
• 44830-55-9 3-cyano-1-isopropylguanidine 
• 56147-28-5 N-cyano-N'-(3,4-dichloro-phenyl)-guanidine 
• 41283-66-3 n-butyldicyandiamide 
• 557791-38-5 2,6-diamino-5,8-diaza-7,9-dicarba-purine 
• 898232-88-7 C₁₇H₁₈N₄ 

Relevant articles and documents

Synthesis, characterization and structure of metallocene dicyanamide complexes

The bis(cyclopentadienyl) complexes [Cp2Ti(dca)]2O and Cp2V(dca)2 (dca = dicyanamide) have been prepared by reaction of sodium dicyanamide with aqueous solution of titanocene dichloride and vanadocene dichloride

Luminol-Based Turn-On Fluorescent Sensor for Selective and Sensitive Detection of Sulfur Mustard at Ambient Temperature

We have explored a novel turn-on fluorescence detection of sulfur mustard (SM) at room temperature . The innovative protocol that uses the combination of luminol and an ionic liquid in water exhibits fluorescence detection of SM within seconds. In this simple, fast, and low-cost chemosensing method, luminol acts as the receptor as well as a signaling element, and the ionic liquid (1-ethyl-3-methylimidazolium dicyanamide) provides the requisite and polarizing medium to realize the detection at room temperature . Interestingly, with a higher concentration of a probe (0.56 mM), SM sensing can be visualized with the naked eye, leading to the formation of a fluorescent green color within a minute, thus expanding the application of the developed sensing technique for chromo-fluorogenic detection of SM. Excellent selectivity, sensitivity (LOD: 6 ppm), and chemosensing at ambient temperature make this methodology completely field-deployable.

Method of producing sodium dicyanamide

A process is described for preparing sodium dicyanamide, in which cyanamide is reacted simultaneously with sodium hydroxide solution and cyanogen chloride in aqueous solution at temperatures of 20 to 100° and a pH of 7.0 to 10.0. By means of the inventive process it is possible, starting from raw materials which are available in technical-grade quality, to prepare sodium dicyanamide in good yields of 75 to 95% and very high purities of up to 100% in a very environmentally friendly manner, for which reason this process is particularly highly suitable for the industrial scale.