1946-09-4

Basic information

• Product Name: diethyl ethylphosphoramidate
• CAS NO: 1946-09-4
• Molecular Formula: C₆H₁₆NO₃P
• Molecular Weight: 181.1699
• Mol File: 1946-09-4.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 204.2°C at 760 mmHg
• Flash Point: 77.3°C
• Density: 1.045g/cm³
• Vapor Pressure: 0.266mmHg at 25°C
• Refractive Index: 1.419
• CAS DataBase Reference: diethyl ethylphosphoramidate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl ethylphosphoramidate(1946-09-4)
• EPA Substance Registry System: diethyl ethylphosphoramidate(1946-09-4)

Safety Data

• Hazardous Substances Data: 1946-09-4(Hazardous Substances Data)

Upstream product

• 814-49-3 diethyl chlorophosphate 
• 75-04-7 ethylamine 
• 85231-90-9 C₁₁H₂₄NO₅P 
• 762-04-9 phosphonic acid diethyl ester 
• 61056-26-6 ethylphosphoramidic acid dichloride 
• 141-52-6 sodium ethanolate 
• 122-52-1 triethyl phosphite 
• 74-96-4 ethyl bromide 
• 40923-48-6 diethyl N-(trimethylsilyl)phosphoroamidate 
• 557-66-4 ethanamine hydrochloride 

Downstream Products

• 13360-63-9 N-ethylbutylamine 
• 624-78-2 N-Ethylmethylamine 
• 20193-20-8 ethylpropylamine 
• 2424-02-4 allylethylamine 
• 914941-63-2 diethoxy[N-(4-oxo-4-phenoxy-Δ²1,3,4-oxazaphospholin-2-yl)-N-ethyl]amidophosphate 
• 91691-46-2 Phosphorsaeure-diaethylester- 
• 53897-00-0 C₅H₅Fe(CO)(CNC₂H₅)P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=C₅H₅Fe(CO)(CNC₂H₅)P(C₆H₅)3PF₆ 

Relevant articles and documents

Selective N-Alkylation of Diethyl Phosphoramidate: Tetrabutylaminium Bromide as Catalyst for Nucleophilic Substitution in a Homogeneous Medium

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One-step transformation of ammonium dialkyl phosphoroselenoates into dialkyl phosphoramidates

Ammonium dialkyl phosphoroselenoates are directly converted into the dialkyl phosphoramidates by iodosobenzene and iodoxybenzene. The inversion of configuration at the phosphorus atom, using model diastereoisomeric ammonium cis- and trans-2-oxo-2-seleno-4-methyl-1,3,2-dioxaphosphinan system, was observed. The mechanistic scheme of this transformation is discussed.

Phosphoramidate-mediated conversion of metal carbonyls into metal isonitriles

The reaction of metal carbonyls with readily-available phosphoramidate anions provides a new route to metal isonitriles; in particular, enantiomerically pure isonitrile complexes are easily accessed by this method.

VARIANT OF THE ATHERTON-TODD REACTION

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