1989-25-9

Basic information

• Product Name: p-chloro-alpha,alpha-dimethylbenzyl alcohol
• Synonyms: p-chloro-alpha,alpha-dimethylbenzyl alcohol;2-(p-Chlorophenyl)-2-propanol;α,α-Dimethyl-4-chlorobenzyl alcohol;Einecs 217-865-7;2-(4-chlorophenyl)propan-2-ol
• CAS NO: 1989-25-9
• Molecular Formula: C₉H₁₁ClO
• Molecular Weight: 170.63604
• EINECS: 217-865-7
• Mol File: 1989-25-9.mol
• Article Data: 29

Chemical Properties

• Melting Point: 31-32 °C
• Boiling Point: 250°Cat760mmHg
• Flash Point: 105°C
• Appearance: /
• Density: 1.144g/cm³
• Vapor Pressure: 0.0117mmHg at 25°C
• Refractive Index: 1.535
• Solubility: soluble in Methanol
• PKA: 14.29±0.29(Predicted)
• CAS DataBase Reference: p-chloro-alpha,alpha-dimethylbenzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: p-chloro-alpha,alpha-dimethylbenzyl alcohol(1989-25-9)
• EPA Substance Registry System: p-chloro-alpha,alpha-dimethylbenzyl alcohol(1989-25-9)

Safety Data

• Hazardous Substances Data: 1989-25-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H11ClO/c1-9(2,11)7-3-5-8(10)6-4-7/h3-6,11H,1-2H3

Upstream product

• 917-64-6 methyl magnesium iodide 
• 7335-27-5 ethyl 4-chlorobenzoate 
• 99-91-2 para-chloroacetophenone 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 67-64-1 acetone 
• 34386-95-3 tert-butyl p-chloro-α,α-dimethylbenzyl peroxide 
• 2747-38-8 methyltrichlorotitanium 
• 1712-70-5 1-chloro-4-(1-methylethenyl)-benzene 
• 917-54-4 methyllithium 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 2621-46-7 1-chloro-4-isopropylbenzene 
• 74-88-4 methyl iodide 
• 75-16-1 methylmagnesium bromide 
• 1126-46-1 Methyl 4-chlorobenzoate 

Downstream Products

• 31220-69-6 N-[1-(4-chlorophenyl)-1-methylethyl]-acrylamide 
• 34386-95-3 tert-butyl p-chloro-α,α-dimethylbenzyl peroxide 
• 64798-38-5 1-chloro-4-(1-isocyanato-1-methylethyl)benzene 
• 41912-29-2 1-(4-chlorophenyl)-1-methylethylium 
• 28094-77-1 5-chloro-3-(4-chlorophenyl)-1,1,3-trimethyl-2,3-dihydro-1H-indene 
• 98-82-8 Isopropylbenzene 
• 1712-70-5 1-chloro-4-(1-methylethenyl)-benzene 
• 1293965-61-3 2-[(2-(4-chlorophenyl)prop-2-yl)sulfanyl]-5-(4-methoxyphenyl)-4-methylthiazole-N-oxide 
• 99-91-2 para-chloroacetophenone 

Relevant articles and documents

Stepwise benzylic oxygenation via uranyl-photocatalysis

Stepwise oxygenation at the benzylic position (1°, 2°, 3°) of aromatic molecules was comprehensively established under ambient conditions via uranyl photocatalysis to produce carboxylic acids, ketones, and alcohols, respectively. The accuracy of the stepwise oxygenation was ensured by the tunability of catalytic activity in uranyl photocatalysis, which was adjusted by solvents and additives demonstrated through Stern–Volmer analysis. Hydrogen atom transfer between the benzylic position and the uranyl catalyst facilitated oxygenation, further confirmed by kinetic studies. Considerably improved efficiency of flow operation demonstrated the potential for industrial synthetic application.

Isopropanol as a hydrogen source for single atom cobalt-catalyzed Wacker-type oxidation

The first example of a heterogeneous cobalt catalytic system for Wacker-type oxidation catalyzed by a single atom dispersed Co-N/C catalyst using alcohol as the hydrogen source under an oxygen atmosphere is presented. By combining a well-designed, controlled experiment and various methods of characterization, we determined that single atom cobalt was the active center rather than nanoparticle or oxide counterparts.

NEW COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME

The present specification provides a compound represented by chemical formula 1, and an organic light-emitting device comprising the same. The compound of the present specification may be used as a material for an organic material layer in an organic light-emitting device to improve efficiency, low driving voltage, and lifetime characteristics of the organic light-emitting device. Additionally, the present specification provides an organic light-emitting device which comprises: a first electrode; a second electrode facing the first electrode; and one or more organic material layers disposed between the first electrode and the second electrode, wherein at least one of the organic material layers comprises the compound of the present specification.COPYRIGHT KIPO 2017