20059-60-3Relevant articles and documents
Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement
Badamshin, Alexander G.,Spirikhin, Leonid V.,Salikov, Rinat F.,Dokichev, Vladimir A.,Tomilov, Yury V.
, p. 438 - 439 (2015)
N-Allyl-N-methylanilines react with methyl diazoacetate or diazoacetone in the presence of Y, Sc or Sm triflates to give the corresponding methyl N-(2-allylaryl)-N-methylglycinates or 2-allyl-N-methyl-N-(2-oxopropyl)aniline. The formation of these compoun
Plasmonic nanopillar arrays encoded with multiplex molecular information for anti-counterfeiting applications
Liu,Lee,Zhang,Cui,Ling
, p. 4312 - 4319 (2016/06/01)
A major challenge in information security and the development of an anti-counterfeiting platform is to encode multiple identification features on a single platform where these features can be decoded with no interference. Here, we demonstrate a progressiv
Transition-metal-free decarboxylation of dimethyl malonate: An efficient construction of α-amino acid esters using TBAI/TBHP
Zhang, Jie,Shao, Ying,Wang, Yaxiong,Li, Huihuang,Xu, Dongmei,Wan, Xiaobing
, p. 3982 - 3987 (2015/03/30)
A transition-metal-free decarboxylation coupling process for the preparation of α-amino acid esters, which succeeded in merging hydrolysis/decarboxylation/nucleophilic substitution, is well described. This strategy uses commercially available inexpensive starting materials, catalysts and oxidants and has a wide substrate scope and operational simplicity. This journal is
A new strategy for the construction of α-amino acid esters via decarboxylation
Zhang, Jie,Jiang, Jiewen,Li, Yuling,Zhao, Yun,Wan, Xiaobing
, p. 3222 - 3225 (2013/07/26)
A new α-amino acid esters formation reaction has been developed via decarboxylation. The methodology is distinguished by its practical novelty in terms of the readily accessible starting materials, environmentally benign reaction conditions and waste streams, and wide substrate scope.
Amide derivatives and methods of their use
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Page/Page column 29, (2008/06/13)
Amide derivatives of the general formulae Ia and Ib: are disclosed. Pharmaceutical compositions containing these compounds, and methods for their use, inter alia, for treating and/or preventing gastrointestinal disorders, pain, and pruritus are also disclosed.
Stevens rearrangement of anilinium salts by the action sodium carbonate hexahydrate
Shakhbazyan,Babakhanyan,Grigoryan,Kocharyan
, p. 1608 - 1610 (2007/10/03)
Anilinium salts containing an allyl-like group together with various functionally substituted receiving groups undergo Stevens rearrangement by the action of sodium carbonate hexahydrate in the absence of a solvent. As a result, both N-methylaniline deriv
Reaction of methyl diazoacetate with aldehydes, amines, thiols, alcohols and acids over transition metal-exchanged clays
Phukan, Prodeep,Mohan, Jakkam Madan,Sudalai, Arumugam
, p. 3685 - 3689 (2007/10/03)
Metal-exchanged clays (M = Rh and Cu) catalyze effectively the reaction of methyl diazoacetate with various aldehydes, affording the corresponding β-keto esters in high yields. They have also been effective in the decomposition of methyl diazoacetate to form metallocarbenes which, in turn, successfully insert into X-H (X = N, O, S, CO2) bonds of a variety of amines, aldehydes, thiols and acids, thereby producing the corresponding esters. The Royal Society of Chemistry 1999.
