207446-10-4

Basic information

• Product Name: (Z)-dimethyl(1-phenylprop-1-enyloxy)silane
• Synonyms: (Z)-dimethyl(1-phenylprop-1-enyloxy)silane
• CAS NO: 207446-10-4
• Molecular Weight: 192.333
• Mol File: 207446-10-4.mol

Chemical Properties

• CAS DataBase Reference: (Z)-dimethyl(1-phenylprop-1-enyloxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-dimethyl(1-phenylprop-1-enyloxy)silane(207446-10-4)
• EPA Substance Registry System: (Z)-dimethyl(1-phenylprop-1-enyloxy)silane(207446-10-4)

Safety Data

• Hazardous Substances Data: 207446-10-4(Hazardous Substances Data)

Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 108-18-9 diisopropylamine 
• 93-55-0 1-phenyl-propan-1-one 

Downstream Products

• 141277-75-0 (2S,3R)-2-Hydroxy-3-methyl-1,4-diphenyl-butane-1,4-dione 
• 141277-74-9 (2S,3S)-2-Hydroxy-3-methyl-1,4-diphenyl-butane-1,4-dione 
• 229317-96-8 erythro-3-hydroxy-2-methyl-1,3-diphenyl-1-propanone 
• 187848-93-7 (2S,3S)-1,3-diphenyl-3-hydroxy-2-methyl-1-propanone 
• 95741-11-0 (2R,3S)-2,3-Dimethyl-1,5-diphenyl-pentane-1,5-dione 
• 95741-11-0 (2R,3R)-2,3-Dimethyl-1,5-diphenyl-pentane-1,5-dione 
• 129139-66-8 3-(1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone 
• 111873-76-8 (2RS,3RS)-1,3-diphenyl-2-methyl-1,5-hexanedione 
• 111873-76-8 (2SR,3RS)-1,3-diphenyl-2-methyl-1,5-hexanedione 
• 16735-22-1 3-hydroxy-2-methylpropiophenone 
• 73739-29-4 (+/-)-(2S,3R)-3-hydroxy-2-methyl-1,5-diphenyl-1-pentanone 
• 73739-38-5 (+/-)-(2S,3S)-3-hydroxy-2-methyl-1,5-diphenyl-1-pentanone 
• 187848-83-5 (2R,3R)-3-hydroxy-2-methyl-1,5-diphenylpent-4-en-1-one 
• 187848-84-6 (2S,3R)-3-hydroxy-2-methyl-1,5-diphenylpent-4-en-1-one 

Relevant articles and documents

Lewis base-promoted aldol reaction of dimethylsilyl enolates in aqueous dimethylformamide: Use of calcium chloride as a Lewis base catalyst

In the presence of CaCl2, dimethylsilyl (DMS) enolates smoothly reacted with aldehydes under mild conditions to give aldol adducts in good to high yields. The catalytic activities of various metal and tetrabutylammonium salts have revealed that CaCl2 works as a Lewis base catalyst to activate DMS enolates. The CaCl2-promoted reaction proceeded even in the presence of water or in pure water. This catalytic system was applicable to the aldol reaction with aqueous aldehydes such as formalin. Copyright

Uncatalyzed aldol reaction using a dimethylsilyl enolate and α- dimethylsilyl ester in N,N-dimethylformamide

Dimethylsilyl enolates and α-dimethylsilyl esters reacted with aldehydes in N,N-dimethyl-formamide without an activator to give aldol adducts in moderate to good yields. Under the same conditions, the corresponding trimethylsilyl derivatives exhibited lower reactivities toward the aldol reaction.