2078-18-4

Usage

Uses

Used in Silicone Product Manufacturing:
PHENYLACETOXYTRIMETHYLSILANE is used as a crosslinking agent for improving the mechanical and thermal properties of silicone products such as sealants, adhesives, and elastomers. Its reactivity allows for the formation of robust bonds within the silicone matrix, leading to enhanced performance and durability of the final products.
Used in Organic Synthesis:
PHENYLACETOXYTRIMETHYLSILANE is used as a reagent in organic synthesis for the introduction of trimethylsilyl functional groups into organic molecules. This modification can alter the reactivity, stability, or solubility of the target molecules, making PAMTS a valuable tool in the synthesis of various organic compounds.
Safety Considerations:
Due to its highly reactive nature with water and high flammability, PHENYLACETOXYTRIMETHYLSILANE requires proper handling and storage to prevent dangerous reactions or fires. Precautions should be taken to minimize exposure and ensure safe usage in industrial applications.

InChI:InChI=1/C11H16O2Si/c1-14(2,3)13-11(12)9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3

Upstream product

• 103-82-2 phenylacetic acid 
• 75-77-4 chloro-trimethyl-silane 
• 72658-09-4 (E)-(1-methoxyprop-1-enyloxy)trimethylsilane 
• 25561-30-2 N,O-Bis(trimethylsilyl)trifluoroacetamide 
• 17879-45-7 bis-(trimethylsilyl)acetamide 
• 60-12-8 2-phenylethanol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 1555-80-2 phenylacetic anhydride 
• 140-29-4 phenylacetonitrile 
• 7500-45-0 N-benzylphenylacetamide 
• 60-12-8 2-phenylethanol 
• 103-82-2 phenylacetic acid 
• 122-78-1 phenylacetaldehyde 
• 125294-36-2 3-hydroxyphenylmaleic anhydride 
• 29313-32-4 2-phenylacetyl isothiocyanate 
• 621-06-7 2,N-diphenylacetamide 
• 64277-60-7 Phenylketen-bis--acetal 
• 31491-21-1 2-phenyl-1,1-bis(trimethylsilyloxy)ethene 

Relevant academic research and scientific papers

Synthesis of trimethylsilyl carboxylates by HMDS under solvent-free conditions

A broad set of structurally different carboxylic acids were transformed into their trimethylsilyl esters with HMDS in a practically completely solvent-free process, while a catalytic amount of iodine was required in some cases. The process has several advantages over the known methods: untreated reactants, air atmosphere, mild and neutral conditions, no evolution of hydrogen halide, no need of an additional base, low amount of waste, completely without chromatography, low consumption of energy, and operational simplicity.

Fe(TAML)Li/(diacetoxyiodo)benzene-mediated oxidation of alcohols: Evidence for mild and selective C-O and C-C oxidative cleavage in lignin model transformations

A novel combination of Fe(TAML)Li and (diacetoxyiodo)- benzene for the oxidation of primary and secondary alcohols at 25 °C in acetone is reported. In view of the interesting ability of this system to selectively cleave specific types of C-C bonds of elaborated alcohols, the application of this novel combination to the oxidative cleavage of lignin model molecules was investigated. Considering the numerous supported versions of the oxidant as well as the mild conditions employed, the developed methodology appears to be a promising lignin depolymerization strategy.

Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane

Liquid-liquid partition is used in sample preparation and in countercurrent and liquid-liquid chromatographic separations. Partition coefficients are widely used in toxicology, environmental, and analytical chemistry. The K hn determination procedure for the n-hexane/ nitromethane system was optimized and partition coefficients for 99 ketones, esters and trimethylsilyl derivatives of phenols, aliphatic and aromatic acids were determined. For 130 compounds, Khn values were predicted using mathematical relationships between Khn and other physicochemical and structural parameters. Versita Sp. z o.o.

One-pot synthesis of 3-hydroxymaleic anhydrides by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride

Functionalized 3-hydroxymaleic anhydrides were prepared by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride.