20912-56-5Relevant articles and documents
Synthesis of Secondary and Tertiary Carbinamines from N-(Trimethylsilyl)-imines and Organolithium Reagents
Hirao, Akira,Hattori, Iwakazu,Yamaguchi, Kazuo,Nakahama, Seiichi,Yamazaki, Noboru
, p. 461 - 462 (1982)
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Iodine-mediated 1,2-aryl migration of primary benzhydryl amines
Chang, Junbiao,Du, Yangxu,Hao, Wei,Hou, Jiao,Lu, Qing,Yu, Wenquan
supporting information, p. 16223 - 16226 (2021/09/22)
An iodine-mediated 1,2-aryl migration reaction of primary benzhydryl amines under transition metal-free conditions has been achieved. The crude imines generated by this rearrangement reaction can be directly transformed into various aromatic secondary ami
Convergent Synthesis of Diverse Nitrogen Heterocycles via Rh(III)-Catalyzed C-H Conjugate Addition/Cyclization Reactions
Weinstein, Adam B.,Ellman, Jonathan A.
supporting information, p. 3294 - 3297 (2016/07/13)
The development of Rh(III)-catalyzed C-H conjugate addition/cyclization reactions that provide access to synthetically useful fused bi- and tricyclic nitrogen heterocycles is reported. A broad scope of C-H functionalization substrates and electrophilic olefin coupling partners is effective, and depending on the nature of the directing group, cyclic imide, amide, or heteroaromatic products are obtained. An efficient synthesis of a pyrrolophenanthridine alkaloid natural product, oxoassoanine, highlights the utility of this method.