212263-60-0Relevant academic research and scientific papers
Synthesis and radical reactions of isomeric alkenyl oxaziridines
Black, David St.C.,Edwards, Gavin L.,Laaman, Scan M.
, p. 1981 - 1990 (2007/10/03)
Several alkenyl oxaziridines were prepared either by photoisomerisation of the precursor nitrones, or by peracid oxidation of the analogous pyrrolines. In each case the oxaziridines were produced as separable mixtures of diastereoisomers, and reasons for
Synthesis and reactivity of 1-pyrroline-5-carboxylate ester 1-oxides
Black, David Stc.,Edwards, Gavin L.,Evans, Richard H.,Keller, Paul A.,Laaman, Sean M.
, p. 1889 - 1897 (2007/10/03)
Some C5 mono- and diester-substituted 1-pyrroline-1-oxides have been prepared via reductive cyclisation of the corresponding γ-nitro carbonyl compounds. Ethyl 2-phenyl-1-pyrroline-1-oxide-5-carboxylate 5c was regioselectively alkylated at C5. Acylation of this molecule occurs exclusively on the nitrone oxygen and leads to C3 substituted pyrrolines as the result of a hetero-Cope rearrangement. (C) 2000 Elsevier Science Ltd.
