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4-nitrophenyl 2-nitrophenyl sulfide is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

21387-93-9

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21387-93-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 21387-93-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,1,3,8 and 7 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 21387-93:
(7*2)+(6*1)+(5*3)+(4*8)+(3*7)+(2*9)+(1*3)=109
109 % 10 = 9
So 21387-93-9 is a valid CAS Registry Number.

21387-93-9Relevant articles and documents

Pd (II) immobilized on clinoptilolite as a highly active heterogeneous catalyst for ullmann coupling-type s-arylation of thiols with aryl halides

Alizadeh, Abdollah,Khalilzadeh, Mohammad A.,Alipour, Eskandar,Zareyee, Daryoush

, p. 657 - 666 (2020/08/24)

Background: There are a number of protocols for Ullmann coupling–type S-arylation reactions, many of them suffer from the use of homogenous and often corrosive catalyst, cumbersome workup procedures, and long reaction times. Besides, many of these reagents are expensive and non-recoverable, leading to the generation of a large amount of toxic waste particularly when large-scale applications are considered. Objective: The aim of this study was to prepare a new Pd catalyst bonded on the surface of zeolite as a heterogeneous catalyst. Methods: A heterogeneous palladium catalyst has been prepared by immobilizing Pd ions on Clinoptilolite. This novel developed heterogeneous catalyst was thoroughly examined for Ullmann coupling–type S-arylation reaction using different bases, solvents and 0.003 mg of the catalyst. The structural and morphological characterizations of the catalyst were carried out using XRD, TGA, BET and TEM techniques. Results: Highly efficient heterogeneous palladium catalyst has been developed by immobilizing Pd ions on Clinoptilolite, as one of the most abundant naturally occurring zeolites for Ullmann S-arylation. By using this method, we provide an efficient way to a wide variety of substituted thiolic compounds. Moreover, the catalyst is easily recovered using simple filtration and reused for 5 consecutive runs. Conclusion: In this effort, we developed a new Pd catalyst bonded on the surface of zeolite as a substrate to prepare the heterogeneous catalyst. We demonstrate that this novel catalyst offers reliable and convincing data that may offer a valuable application in further developing the science and technology of Ullmann reaction protocols and allied industries. Additionally, the catalyst was reusable and kept its high activities over a number of cycles.

KF/clinoptilolite: An efficient promoter for the synthesis of thioethers

Salmanpour, Sadegh,Khalilzadeh, Mohammad A.,Hosseini, Abolfazl

, p. 339 - 344 (2013/07/28)

Potassium fluoride impregnated on natural zeolite as a new solid base system effectively catalyzes the coupling of thiophenols with electron-deficient fluoro-, chloro- and bromo-arenes in DMSO. This versatile and efficient solid base has been demonstrated to afford the corresponding desired products in good to excellent yields. This procedure provides a convenient, efficient and practical method for the preparation of diaryl thioethers.

Ascorbate mediated copper catalyzed reductive cross-coupling of disulfides with aryl iodides

Martinek, Marek,Korf, Michal,Srogl, Jiri

supporting information; experimental part, p. 4387 - 4389 (2010/08/06)

The concept of using ascorbic acid as a mediator/ reducing agent in a Cu(i) catalyzed process is introduced and further demonstrated on a cross-coupling reaction of aryl iodides with disulfides.

Convenient one-pot procedure for converting aryl sulfides to nitroaryl sulfones

Nose, Masatoshi,Suzuki, Hitomi

, p. 1065 - 1071 (2007/10/03)

When treated with nitrogen dioxide and ozone in inert solvent at 0°C or below, aryl sulfides underwent smooth oxidative nitration to give nitroaryl sulfones in good yield. Using this methodology, a series of mono- and di-nitrated aryl sulfones were prepared from methyl phenyl sulfide and diphenyl sulfide and their physical data are presented.

Synthesis of diphenyl sulfides. V. Mobility of the nitro group in derivatives of phenyl 4-nitrophenyl sulfide

Sevbo, D. P.,Stepanova, T. F.,Nekhoroshev, A. A.

, p. 1097 - 1101 (2007/10/02)

In derivatives of phenyl 4-nitrophenyl sulfide containing an alkoxycarbonyl group at the ortho position to the nitro group the latter is readily substituted by an arylthio group.

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