2425-54-9 Usage
Description
1-Chlorotetradecane, also known as 1-chloro-n-tetradecane, is a water-white distilled liquid with a mild odor. It is a chemical compound that contains 15.2% chloride and is subject to mild hydrolysis when left standing. This organic compound is widely recognized for its role as a synthetic intermediate in various chemical processes.
Uses
1-Chlorotetradecane is used as a chemical intermediate for various applications across different industries. Its versatility as a synthetic intermediate makes it a valuable component in the production of various compounds and materials.
Used in Surfactant Production:
In the chemical industry, 1-Chlorotetradecane is used as a synthetic intermediate to prepare Dimethyldimyristyl ammonium chloride (D472560), a surfactant. Surfactants are essential in various applications, including the formulation of detergents, emulsifiers, and dispersants.
Used in Nonionic Microemulsion Preparation:
1-Chlorotetradecane is also utilized in the preparation of nonionic microemulsions, specifically in combination with pentaoxyethylene glycol dodecyl ether and water. These microemulsions have potential applications in the pharmaceutical, cosmetic, and food industries, where they can enhance the solubility and stability of active ingredients.
Used in Analytical Chemistry:
As an internal standard, 1-Chlorotetradecane is employed in the determination of 3-chloropropane-1,2-diol in hydrolyzed vegetable protein using capillary gas chromatography with electrolytic conductivity detection. This application highlights its importance in ensuring accurate and reliable analytical results in the field of chemistry.
Synthesis Reference(s)
Tetrahedron Letters, 25, p. 2295, 1984 DOI: 10.1016/S0040-4039(01)80237-9
Check Digit Verification of cas no
The CAS Registry Mumber 2425-54-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,2 and 5 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 2425-54:
(6*2)+(5*4)+(4*2)+(3*5)+(2*5)+(1*4)=69
69 % 10 = 9
So 2425-54-9 is a valid CAS Registry Number.
InChI:InChI=1/C14H29Cl/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3
2425-54-9Relevant articles and documents
Iron-catalyzed AlkylAlkyl negishi coupling of organoaluminum reagents
Agata, Ryosuke,Kawamura, Shintaro,Isozaki, Katsuhiro,Nakamura, Masaharu
supporting information, p. 238 - 241 (2019/03/13)
The first iron-catalyzed cross-coupling reaction of alkyl halides with alkylaluminum reagents (alkylalkyl Negishi coupling) is developed using an iron/bisphosphine catalyst system. The reaction shows high functional group tolerance: various primary alkyl halides possessing a non-protected indole, carboxyl, or hydroxy group are coupled with primary alkylaluminum reagents in good yields. Potassium fluoride plays a key role to promote the reaction by generating an aluminate species, which facilitates the transmetalation between the organoaluminum and the iron catalyst.
Process for preparing alkyl chlorides
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Page/Page column 5-6, (2008/06/13)
The invention relates to a process for preparing alkyl chlorides by reacting alcohols with gaseous hydrogen chloride in the presence of a catalyst, wherein the catalyst comprises at least one compound of the structure: wherein R1 is a linear alkyl group having from 1 to 20 carbon atoms, R2, R3, and R4 is selected from a hydrogen, an alkyl, an alkenyl, an aralkyl or an alkylaryl group from 1 to 20 carbon atoms, wherein the substituents of R2, R3, and R4 are all identical, are all different or two of the substituents of R2, R3, and R4 type are identical.
REACTION OF ALKOXYHYDROPEROXIDES WITH METAL SALTS. ALKYL HALIDE PREPARATION
Cardinale, G.,Grimmelikhuysen, J. C.,Laan, J. A. M.,Lier, F. P. van,Steen, D. van der,Ward, J. P.
, p. 5971 - 5978 (2007/10/02)
A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by ozonisation in methanol, with ferric chloride: RCH=CH2 --> RCH(OOH)OCH3 --> R. --> RCl.Yields of 1-chlorotetradecane were about 60percent; those of other halides from 38 to 57percent.