24316-60-7

Basic information

• Product Name: (Z)-(4-methoxyphenyl)(phenyl)methanone oxime
• CAS NO: 24316-60-7
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.2585
• Mol File: 24316-60-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 375.4°C at 760 mmHg
• Flash Point: 180.9°C
• Density: 1.08g/cm³
• Vapor Pressure: 2.65E-06mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: (Z)-(4-methoxyphenyl)(phenyl)methanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(4-methoxyphenyl)(phenyl)methanone oxime(24316-60-7)
• EPA Substance Registry System: (Z)-(4-methoxyphenyl)(phenyl)methanone oxime(24316-60-7)

Safety Data

• Hazardous Substances Data: 24316-60-7(Hazardous Substances Data)

Upstream product

• 932-90-1 Benzaldoxime 
• 100-52-7 benzaldehyde 
• 98-88-4 benzoyl chloride 
• 100-66-3 methoxybenzene 
• 75600-86-1 4-methoxybenzophenone phenylhydrazone 
• 5720-07-0 4-methoxyphenylboronic acid 
• 698-16-8 benzohydroximoyl chloride 
• 611-94-9 4-Methoxybenzophenone 

Downstream Products

• 611-94-9 4-Methoxybenzophenone 
• 57761-70-3 5-(4-methoxyphenyl)-1-phenyl-1H- tetrazole 
• 57761-73-6 1-(4'-methoxyphenyl)-5-phenyl-1H-tetrazole 
• 1359715-94-8 1-(4-methoxyphenyl)-3,4-diphenylisoquinoline 
• 17377-95-6 benzyl(4-methoxyphenyl)amine 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 7465-88-5 4-methoxy-N-phenylbenzamide 
• 2538-34-3 4-methoxybenzhydrylamine 

Relevant articles and documents

New imino-methoxy derivatives: design, synthesis, characterization, antimicrobial activity, DNA interaction and molecular docking studies

Four new diarylmethylamine imine compounds (5a-5d) were prepared in order to examine their DNA binding properties, antimicrobial activity and molecular docking. The compounds were characterized by the common spectroscopic and analytic methods. Furthermore

Transition-Metal-Free Coupling of 1,3-Dipoles and Boronic Acids as a Sustainable Approach to C?C Bond Formation

The need for alternative, complementary approaches to enable C?C bond formation within organic chemistry is an on-going challenge in the area. Of particular relevance are transformations that proceed in the absence of transition-metal reagents. In the current study, we report a comprehensive investigation of the coupling of nitrile imines and aryl boronic acids as an approach towards sustainable C?C bond formation. In situ generation of the highly reactive 1,3-dipole facilitates a Petasis–Mannich-type coupling via a nucleophilic boronate complex. The introduction of hydrazonyl chlorides as a complementary nitrile imine source to the 2,5-tetrazoles previously reported by our laboratory further broadens the scope of the approach. Additionally, we exemplify for the first time the extension of this protocol into another 1,3-dipole, through the synthesis of aryl ketone oximes from aryl boronic acids and nitrile N-oxides.

Vilsmeier-Haack reagent mediated synthetic transformations with an immobilized iridium complex photoredox catalyst

An immobilized iridium complex photocatalyst Ir(ppy)2(PDVB-py) was synthesized by immobilization of the iridium complex onto the nanoporous vinylpyridine-divinylbenzene copolymer (PDVB-py). Its application for the synthesis of amides, nitriles, and anhydrides was reported via reactions under the action of the visible-light-driven in situ generated Vilsmeier-Haack reagent from CBr4 in DMF. The results showed that this heterogeneous photocatalyst has extremely high activity and excellent stability to be recycled five times.