25315-79-1Relevant academic research and scientific papers
Benzothiazolines as radical transfer reagents: Hydroalkylation and hydroacylation of alkenes by radical generation under photoirradiation conditions
Uchikura, Tatsuhiro,Moriyama, Kaworuko,Toda, Mitsuhiro,Mouri, Toshiki,Ibá?ez, Ignacio,Akiyama, Takahiko
, p. 11171 - 11174 (2019/09/30)
Novel radical transfer reagents under photoirradiation conditions were developed by the use of benzothiazoline derivatives. These reagents enabled both hydroalkylation and hydroacylation of alkenes under neutral conditions at ambient temperature without a
Photocatalytic Radical Alkylation of Electrophilic Olefins by Benzylic and Alkylic Zinc-Sulfinates
Gualandi, Andrea,Mazzarella, Daniele,Ortega-Martínez, Aitor,Mengozzi, Luca,Calcinelli, Fabio,Matteucci, Elia,Monti, Filippo,Armaroli, Nicola,Sambri, Letizia,Cozzi, Pier Giorgio
, p. 5357 - 5362 (2017/08/17)
Alkyl radicals are obtained by photocatalytic oxidation of readily prepared or commercially available zinc sulfinates. The convenient benzylation and alkylation of a variety of electron-poor olefins triggered by the iridium(III) complex 6 Ir[dF(CF3)ppy]2(dtbbpy)PF6 as photocatalyst is described. Moreover, it is shown that zinc sulfinates can be used for facile nonradical sulfonylation reactions with highly electrophilic Michael acceptors.
Tetramethylethylene diamine/trimethylsilyl chloride mediated addition of benzyl copper reagents to α,β-unsaturated esters
Van Heerden, Pieter S.,Bezuidenhoudt, Barend C. B.,Ferreira, Daneel
, p. 12313 - 12322 (2007/10/03)
Several benzylic copper reagents, benzylcopper, 4-methoxybenzylcopper and 1-phenylethylcopper, facilitate the conjugate addition of the corresponding benzyl ligands to α,β-enoates in the presence of tetramethylethylene diamine and trimethylsilyl chloride in high yields.
Synthesis of 3-Aryl-1-tetralones
Selvaraj, S.,Rajendran, A. S.,Arumugam, N.
, p. 1047 - 1049 (2007/10/02)
A new method for the synthesis of 3-aryl-1-tetralones is presented.The tetralones synthesised have been characterised by elemental analysis and soectral data.
