27349-51-5

Basic information

• Product Name: Ethanone, 2-(3-methyl-5-isoxazolyl)-1-phenyl-
• CAS NO: 27349-51-5
• Molecular Formula: C12H11NO2
• Molecular Weight: 201.225
• Mol File: 27349-51-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(3-methyl-5-isoxazolyl)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(3-methyl-5-isoxazolyl)-1-phenyl-(27349-51-5)
• EPA Substance Registry System: Ethanone, 2-(3-methyl-5-isoxazolyl)-1-phenyl-(27349-51-5)

Safety Data

• Hazardous Substances Data: 27349-51-5(Hazardous Substances Data)

Upstream product

• 75632-83-6 3-methyl-5-[(trimethylsilyl)methyl]isoxazole 
• 123-54-6 acetylacetone 
• 300-87-8 3,5-dimethyl-1,2-oxazole 
• 93-58-3 benzoic acid methyl ester 
• 141104-33-8 (E)-3-[(E)-2-(3-Methyl-isoxazol-5-yl)-1-phenyl-vinylamino]-acrylonitrile 
• 100-47-0 benzonitrile 

Downstream Products

• 7500-03-0 2-Methyl-6-phenyl-1,4-dihydropyridin-4-on 
• 61449-25-0 2-Amino-6-hydroxy-6-phenyl-2-hexen-4-on 
• 102720-77-4 1,3-Diphenyl-2-(3-methyl-5-isoxazolyl)-propan-1,3-dion 
• 102720-74-1 3-Methyl-5-(2-phenyl-1,3-dioxolan-2-yl)-methylisoxazol 
• 497059-15-1 3-acetyl-5-(3-methyl-5-isoxazolyl)-4,6-diphenyl-2-pyridone 
• 881192-18-3 3-acetyl-6-isopropyl-5-(3-methyl-5-isoxazolyl)-4-phenyl-2-pyridone 
• 61448-99-5 (+/-)-5-(2-hydroxy-2-phenylethyl)-3-methylisoxazole 
• 102720-87-6 3,5-Diphenyl-4-(3-methyl-5-isoxazolyl)-isoxazol 
• 1469-95-0 1-phenylhexane-1,3,5-trione 
• 58369-46-3 (E)-6-phenyl-5-hexene-2,4-dione 

Relevant articles and documents

Asymmetric transfer hydrogenation of heterocycle-containing acetophenone derivatives using N-functionalised [(benzene)Ru(II)(TsDPEN)] complexes

The application of enantiomerically-pure ruthenium(II) catalysts containing N - functionalised TsDPEN ligand to the asymmetric transfer hydrogenation of 15 examples of α-heterocyclic acetophenone derivatives is reported. Products of up to 99% ee were formed.

Mo(CO)6-INDUCED N-O BOND CLEAVAGE OF ISOXAZOLES. A CONVENIENT ROUTE TO PYRIDIN-4(1H)-ONES

The Mo(CO)6-induced reaction of 3-methyl-5-(2-oxoalkyl)isoxazoles, which are derived through proton-abstraction of 3,5-dimethylisoxazole followed by treatment with esters, gave pyridin-4(1H)-ones in good to modest yields in a single step.

3,4-disubstituted-4,5-dihydro-1H-pyrazoles and a method of preparation

3,4-Diaryl-4,5-dihydro-1H-pyrazole compounds having a selected 5- or 6-membered aromatic heterocyclic moiety in the 4-position and an optionally substituted phenyl moiety in the 3-position, such as 4,5-dihydro-3-(4-fluorophenyl)-4-(5-trifluoromethyl-2-pyr