28004-69-5Relevant academic research and scientific papers
Direct oxidative amidation of aldehydes with amines catalyzed by heteropolyanion-based ionic liquids under solvent-free conditions via a dual-catalysis process
Fu, Renzhong,Yang, Yang,Zhang, Jin,Shao, Jintao,Xia, Xuming,Ma, Yunsheng,Yuan, Rongxin
, p. 1784 - 1793 (2016)
A simple and efficient procedure for the synthesis of amides directly from aldehydes and amines catalyzed by heteropolyanion-based ionic liquids under solvent-free conditions has been reported. The practical protocol was found to tolerate a wide range of substrates with different functional groups. Moderate to excellent yields, solvent-free media, and operational simplicity are the main highlights. The proposed dual-catalysis mechanistic pathway was briefly investigated. Furthermore, the heteropolyanion-based ionic liquids were easily reusable for this oxidative amidation.
Synthesis of Unsymmetrically Substituted 4H-1,2,4-Triazoles
Carlsen, Per H. J.,Joergensen, Kare B.
, p. 805 - 808 (2007/10/02)
A general method was developed for the synthesis of unsymmetrically 3,5-disubstituted 4H-1,2,4-triazoles (Ph, H or Ph, CH3) with allyl or benzyl groups in the 4-ring position.The reaction of the corresponding 3,5-disubstituted 1,3,4-oxadiazoles with allyl
