2806-12-4Relevant academic research and scientific papers
Titanium-Catalyzed Hydroaminoalkylation of Ethylene
Rosien, Michael,T?ben, Iris,Schmidtmann, Marc,Beckhaus, Rüdiger,Doye, Sven
supporting information, p. 2138 - 2142 (2020/02/05)
The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti?C bond of a titanaaziridine is reported.
Microwave-promoted selective mono-n-alkylation of anilines with tertiary amines by heterogeneous catalysis
Lubinu, M. Caterina,De Luca, Lidia,Giacomelli, Giampaolo,Porcheddu, Andrea
supporting information; experimental part, p. 82 - 85 (2011/03/21)
A palladium-catalyzed N-alkylation of anilines with tertiary amines that occurs under heterogeneous transfer-hydrogenation conditions has been developed (see scheme). This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large-scale preparations.
Assembly of substituted 2-alkylquinolines by a sequential palladium-catalyzed Ci-N and Ci-C bond formation
Matsubara, Yoshio,Hirakawa, Saori,Yamaguchi, Yoshihiro,Yoshida, Zen-Ichi
experimental part, p. 7670 - 7673 (2011/10/05)
Diversity: A range of substituted 2-alkylquinolines can be prepared in a general and efficient synthetic approach that employs mild reaction conditions (see scheme). The synthesis is based on a sequential palladium-catalyzed Ci-N and Ci-C bond formation, followed by palladium-catalyzed aromatization, and results in the formation of the desired compounds in one step. Copyright
Herbicidal oxadiazolidines
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Page 18, (2010/11/30)
Compounds of Formula (1) and processes for their preparation, their N-oxides and agriculturally suitable salts, are disclosed which are useful for controlling undesired vegetation wherein Q, X1, X2, X3, R1, Rsu
A novel and efficient approach to mono-N-alkyl anilines via addition of Grignard reagents to aryl azides
Sampath Kumar,Subba Reddy,Anjaneyulu,Yadav
, p. 8305 - 8306 (2007/10/03)
Mono-N-alkyl anilines were obtained in high yields within a short reaction time when various aromatic azides were reacted with alkyl magnesium halides at room temperature.
