2888-11-1Relevant articles and documents
Renewable high-density spiro-fuels from lignocellulose-derived cyclic ketones
Xie, Junjian,Zhang, Xiangwen,Pan, Lun,Nie, Genkuo,Xiu-Tian-Feng,Liu, Qing,Wang, Peng,Li, Yafei,Zou, Ji-Jun
supporting information, p. 10303 - 10305 (2017/09/23)
Renewable high-density spiro-fuels are synthesized from lignocellulose-derived cyclic ketones for the first time, which show higher density, higher neat heat of combustion and lower freezing point compared with other biofuels synthesized from the same feedstock, and thus represent a new type of renewable high-density fuel attractive for practical applications.
Use of electrochemistry to provide efficient SmI2 catalytic system for coupling reactions.
Sun, Linhao,Sahloul, Kamar,Mellah, Mohamed
, p. 2568 - 2573 (2013/11/19)
Samarium metal has been used for the first time as electrode material to perform as an efficient and versatile SmI2 catalytic system assisted by electrochemistry. The established electrocatalytic procedure that excludes any metal additives was successfully applied in various transformations mediated by this useful reagent.
Study of I-strain relief in the intermediate when forming spiro ketones from unsymmetrical cycloalkylidenecycloalkanes, their dibromides, and their pinacols
Sands
, p. 468 - 471 (2007/10/02)
Three unsymmetrical intercyclic olefins, their dibromides, and their pinacols were prepared, each so the two carbons involved at the functional group were part of a different sized ring. The pinacols were reacted with 25% sulfuric acid and with boron trif