32723-67-4

Basic information

• Product Name: 3-Methyl-4-anisaldehyde
• Synonyms: ASISCHEM R37628;3-METHYLANISALDEHYDE;3-METHYL-P-ANISALDEHYDE;4-METHOXY-3-METHYLBENZALDEHYDE;4-METHOXY-M-TOLUALDEHYDE;TIMTEC-BB SBB008533;3-Methyl-para-anisaldehyde;Benzaldehyde, 4-methoxy-3-methyl-
• CAS NO: 32723-67-4
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.17
• EINECS: 251-177-8
• Product Categories: Fluorobenzene;Aromatic Aldehydes & Derivatives (substituted);Benzenes
• Mol File: 32723-67-4.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 80-85 °C1 mm Hg(lit.)
• Flash Point: 234 °F
• Appearance: Clear pale yellow to green liquid
• Density: 1.098 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.0142mmHg at 25°C
• Refractive Index: n20/D 1.569
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: Chloroform, Ethyl Acetate
• BRN: 2084045
• CAS DataBase Reference: 3-Methyl-4-anisaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-4-anisaldehyde(32723-67-4)
• EPA Substance Registry System: 3-Methyl-4-anisaldehyde(32723-67-4)

Safety Data

• Safety Statements: 23-24/25
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 32723-67-4(Hazardous Substances Data)

Usage

Chemical Properties

Clear pale yellow to green liquid

Uses

4-Methoxy-3-methylbenzaldehyde was used in the preparation of (4-methoxy-3-methylphenyl)-2-nitroalkene.

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 1078, 1984 DOI: 10.1021/jo00180a024

InChI:InChI=1/C9H10O2/c1-7-5-8(6-10)3-4-9(7)11-2/h3-6H,1-2H3

Upstream product

• 578-58-5 2-methylmethoxybenzene 
• 68-12-2 N,N-dimethyl-formamide 
• 15174-69-3 4-hydroxy-3-methyl-benzaldehyde 
• 74-88-4 methyl iodide 
• 4685-47-6 3,4-dimethylanisole 
• 114787-91-6 (4-methoxy-3-methylphenyl)methanol 
• 7647-01-0 hydrogenchloride 
• 7446-70-0 aluminium trichloride 
• 74-90-8 hydrogen cyanide 
• 21573-35-3 4-ethyl-2-methylphenyl methyl ether 
• 71-43-2 benzene 
• 6738-23-4 2,4-dimethylanisole 
• 14804-31-0 2-methyl-4-bromoanisole 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 53313-98-7 4-methoxy-3-methyl-mandelonitrile 
• 6880-04-2 4-methoxy-3-methylbenzoic acid 
• 199014-88-5 3¹-oxy-6-methoxy-1-methyl-3-propyl-benzene 
• 1029521-31-0 2-(2,3-difluorobenzylsulfanyl)-4-hydroxy-6-(4-methoxy-3-methyl-phenyl)-pyrimidine-5carbonitrile 
• 59931-48-5 4-methoxy-3-methylbenzoyl chloride 
• 1026943-29-2 1-(4-methanesulfonyl-phenyl)-5-(4-methoxy-3-methyl-phenyl)-1H-imidazole 
• 1026170-06-8 N-[5-ethyl-2-methoxy-4-(4-methoxy-3-methyl-benzoyl)-6-methyl-pyridin-3-yl]-2,2-dimethyl-propionamide 
• 248248-60-4 3-amino-5-ethyl-4-(4-methoxy-3-methyl-benzoyl)-6-methyl-1H-pyridin-2-one 
• 248248-47-7 3-amino-5-ethyl-4-(4-methoxy-3-methyl-benzyl)-6-methyl-1H-pyridin-2-one 
• 140841-05-0 ethyl 3-(4-hydroxy-3-methylphenyl)propanoate 
• 178676-98-7 ethyl 3-(4-methoxy-3-methylphenyl)propinoate 
• 209624-66-8 3-hydroxy-4-methoxy-5-methylbenzaldehyde 

Relevant articles and documents

Electricity Driven 1,3-Oxohydroxylation of Donor-Acceptor Cyclopropanes: a Mild and Straightforward Access to β-Hydroxy Ketones

An unprecedented external oxidant-free electrochemical protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropane is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp3?Csp3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of molecular oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed.

Volatiles from the xylarialean fungus Hypoxylon invadens

The volatiles emitted by agar plate cultures of the xylarialean fungus Hypoxylon invadens were investigated by use of a closed loop stripping apparatus in combination with GC-MS. Several aromatic compounds were found that could only be identified by comparison to all possible constitutional isomers with different ring substitution patterns. For the set of identified compounds a plausible biosynthetic scheme was suggested that gives further support for the assigned structures.

PEROXISOME PROLIFERATOR ACTIVATED RECEPTOR MODULATORS

The present invention is directed to a compound of formula (I), or a pharmaceutically acceptable salt, solvate hydrate or stereoisomer thereof, which is useful in treating or preventing disorders mediated by a peroxisome proliferator activated receptor (PPAR) such as syndrome X, type II diabetes, hyperglycemia, hyperlipidemia, obesity, coagaulopathy, hypertension, arteriosclerosis, and other disorders related to syndrome X and cardiovascular diseases.