3309-97-5

Basic information

• Product Name: 2-Cyclohexene-1-methanol
• Synonyms: 2-Cyclohexene-1-methanol
• CAS NO: 3309-97-5
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.17
• Mol File: 3309-97-5.mol
• Article Data: 35

Chemical Properties

• Boiling Point: 95 °C(Press: 8 Torr)
• Appearance: /
• Density: 0.9697 g/cm3(Temp: 25 °C)
• PKA: 14.87±0.10(Predicted)
• CAS DataBase Reference: 2-Cyclohexene-1-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-methanol(3309-97-5)
• EPA Substance Registry System: 2-Cyclohexene-1-methanol(3309-97-5)

Safety Data

• Hazardous Substances Data: 3309-97-5(Hazardous Substances Data)

Usage

General Description

2-Cyclohexene-1-methanol is a chemical compound with the molecular formula C7H12O. It belongs to the class of organic compounds known as cyclohexanols, which are compounds containing an alcohol group attached to a cyclohexane ring. This colorless liquid is characterized by its unique odor and it is primarily used in the manufacturing of fragrances due to its pleasant smell. Owing to its alcohol group, this compound exhibits typical alcohol properties, including the ability to form esters and ethers. 2-Cyclohexene-1-methanol is typically synthesized through the catalytic hydrogenation of Phenol or by treating cyclohexanone at a high temperature with methanol in the presence of a strong acid catalyst.

Upstream product

• 93-89-0 benzoic acid ethyl ester 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 186581-53-3 diazomethane 
• 822-67-3 Cyclohex-2-enol 
• 62115-15-5 cyclohex-2-ene-1-carboxylic acid 
• 7641-25-0 Formaldehyd-bis- 
• 286-08-8 bicyclo[4.1.0]heptane 
• 286-08-8 2,7,7-trimethyltricyclo[4.1.1.0^2,4]octane 
• 42540-33-0 cyclohex-2-enecarbaldehyde 
• 629-30-1 1,7-heptandiol 
• 109-87-5 Dimethoxymethane 
• 1521-51-3 rac-3-bromocyclohexene 
• 50-00-0 formaldehyd 
• 110-83-8 cyclohexene 

Downstream Products

• 158952-03-5 2-(Cyclohex-2-enylmethoxy)-tetrahydro-pyran 
• 156731-33-8 (2-cyclohexenyl)methyl methanesulfonate 
• 83732-05-2 cyclohex-1-en-3-ylmethyl vinyl ether 
• 42540-33-0 cyclohex-2-enecarbaldehyde 
• 37677-17-1 1-bromomethylcyclohexene 
• 591-48-0 3-methyl-1-cyclohexene 
• 16452-34-9 2-(cyclohex-2-enyl)ethanol 
• 19509-51-4 3-(β-chloroethyl)cyclohexene 
• 82166-21-0 methyl cyclohexane 
• 1072-95-3 cyclohexylmethyl chloride 
• 822-67-3 Cyclohex-2-enol 
• 62115-15-5 cyclohex-2-ene-1-carboxylic acid 
• 18964-38-0 (RS)-3-(methoxymethyl)cyclohex-1-ene 
• 1274896-73-9 4-(cyclohex-2-enylmethoxy)-5,5-dimethylfuran-2-(5H)-one 

Relevant articles and documents

Kinetic Resolution of Allyltriflamides through a Pd-Catalyzed C-H Functionalization with Allenes: Asymmetric Assembly of Tetrahydropyridines

Enantioenriched, six-membered azacycles are essential structural motifs in many products of pharmaceutical or agrochemical interest. Here we report a simple and practical method for enantioselective assembly of tetrahydropyridines, which is paired to a ki

Production of oxygen-containing alicyclic compounds (by machine translation)

[Problem] to provide, in a one-step reaction synthesizes an alicyclic compound containing oxygen, high yield production of oxygen-containing compound is a cycloaliphatic. [Solution] one or more hydroxy or carbonyl group 2, or a hydroxyl group having the carbon number of 5 or more aliphatic carbonyl group 2 in accordance with one or more oxygen-containing compound, a basic catalyst is brought into contact with an oxygen-containing alicyclic compound by cyclodehydration reaction, oxygen-containing alicyclic compound. [Drawing] no (by machine translation)

Selective hydrogenation of unsaturated carbonyls by Ni-Fe-based alloy catalysts

Ni-Fe alloy catalysts prepared by a simple hydrothermal method and subsequent H2 treatment exhibited the greatest activity and selectivity for the hydrogenation of biomass-derived furfural to furfuryl alcohol among the examined second metals, such as Al, Ga, In, Co, and Ti. This work reveals that the alloying of Ni and Fe is a key factor in achieving highly selective hydrogenation of the CO moiety in unsaturated carbonyl substrates. We found that decreasing the temperature of H2 treatment (i.e. decreasing the crystallite size), e.g. Ni-Fe(2)HT-573 K (TOF = 952 h-1), increased the activity compared to that over Ni-Fe(2)HT-673 (TOF = 375 h-1) for furfural hydrogenation. This result suggests that a low-coordinated Ni-Fe alloy was imperative for the catalytic cycle. Moreover, the effect of the metal/support interface was critical; despite the high catalytic performance of Ni-Fe/TiO2, Ni-Fe/Al2O3, and Ni-Fe/CeO2, Ni-Fe supported on SiO2, taeniolite, and hydrotalcite catalysts were ineffective. Vibrational studies using FT-IR measurement confirmed that furfural was physically adsorbed on the surface of the Ni-Fe alloy catalyst via an η1(O) configuration. The synthetic scope of the Ni-Fe catalytic system was very broad; various types of unsaturated carbonyls, such as unsaturated aromatics, unconjugated aliphatics, and a large substituent, were selectively converted into the corresponding unsaturated alcohols.