34288-40-9

Basic information

• Product Name: methyl (Z)-3-(2-methoxycarbonylphenyl)-2-propenoate
• Synonyms: methyl (Z)-3-(2-methoxycarbonylphenyl)-2-propenoate
• CAS NO: 34288-40-9
• Molecular Weight: 220.225
• Mol File: 34288-40-9.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: methyl (Z)-3-(2-methoxycarbonylphenyl)-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-3-(2-methoxycarbonylphenyl)-2-propenoate(34288-40-9)
• EPA Substance Registry System: methyl (Z)-3-(2-methoxycarbonylphenyl)-2-propenoate(34288-40-9)

Safety Data

• Hazardous Substances Data: 34288-40-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 18454-53-0 (E)-o-carboxycinnamic acid 
• 135-19-3 β-naphthol 
• 4122-56-9 methyl o-formylbenzoate 
• 96-32-2 bromoacetic acid methyl ester 
• 34288-40-9 2-(E)-[2-methoxycarbonylphenyl]acrylic acid methylester 
• 524-42-5 1,2-naphthoquinone 
• 292638-85-8 acrylic acid methyl ester 
• 134-20-3 2-carbomethoxyaniline 
• 13086-06-1 (E)-hex-2-en-4-ynedioic acid dimethyl ester 
• 1165952-91-9 cyclohexa-1,3-diene 
• 342-54-1 2-(methoxycarbonyl)benzenediazonium tetrafluoroborate 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 88-65-3 2-bromobenzoic-acid 

Downstream Products

• 18454-53-0 (E)-o-carboxycinnamic acid 
• 98116-20-2 (E)-3-(2-Methoxycarbonylphenyl)propenoic acid 
• 22955-77-7 methyl 1-indanone-2-carboxylate 
• 54311-87-4 2-phenyl-2,3,4,5-tetrahydro-1H-benzo[c]azepine 
• 54311-89-6 2-benzyl-2,3,4,5-tetrahydro-1H-benzo[c]azepine 
• 7216-22-0 2,3,4,5-tetrahydro-1H-benzo[c]azepine 
• 136863-23-5 3-[2-(hydroxymethyl)phenyl]propan-1-ol 
• 25040-17-9 methyl 3-[2-(methoxycarbonyl)phenyl]propionate 

Relevant articles and documents

PROCESSES FOR THE PREPARATION OF ORTHO-ALLYLATED HYDROXY ARYL COMPOUNDS

The present application describes process for preparing an ortho-allylated hydroxy aryl compounds such as compounds of Formula (I) by reacting an allylic alcohol with a hydroxy aryl compound in the presence of aluminum compound selected from alumina and aluminum alkoxides and in a non-protic solvent wherein at least one carbon atom ortho to the hydroxy group in the hydroxy aryl compound is unsubstituted. The present application also includes compounds of Formula (I).

Functionalized β-cyclodextrin as supramolecular ligand and their Pd(OAc)2 complex: Highly efficient and reusable catalyst for Mizoroki-Heck cross-coupling reactions in aqueous medium

A novel class of water soluble palladium complexes with recognition abilities based on functionalized β-cyclodextrin has been synthesized. The complex demonstrated high catalytic activity and a supramolecular platform for phosphine-free Mizoroki-Heck cross-coupling reactions in water. The efficient arylation of alkenes was carried out using different iodo- and bromo-arenes with good to excellent yields (up to 96%). The advantages, like recyclability of catalysts, operational simplicity and accessibility in aqueous medium, make this protocol eco-friendly.

First Microwave-Assisted Catalytic Wittig Reaction

We introduce a novel catalytic Wittig reaction based on an inexpensive and readily available phosphane oxide as a precatalyst. The performance of the reaction under microwave irradiation led to significantly improved yields and reaction rates relative to those obtained under conventional heating. Moreover, herein we enclose the first example of the asymmetric catalytic Wittig reaction based on a chiral phosphane as the catalyst.