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Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane is a complex organic compound with the molecular formula C11H24Si2. It is a colorless liquid at room temperature and is characterized by its unique structure, which includes a trimethylsilyl group attached to a 2-butenyl chain that is in the (2E) configuration. Trimethyl[(2E)-4-(trimethylsilyl)-2-butenyl]silane is primarily used in organic synthesis, particularly in the formation of silyl ethers and as a protecting group for alcohols. It is also employed as a reagent in various chemical reactions due to its stability and the ability to form stable silyl ethers. The compound is synthesized through the reaction of trimethylsilyl chloride with allyltrimethylsilane, and it is known for its resistance to hydrolysis, which makes it a valuable intermediate in the synthesis of more complex organic molecules.

3528-12-9

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3528-12-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3528-12-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,5,2 and 8 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3528-12:
(6*3)+(5*5)+(4*2)+(3*8)+(2*1)+(1*2)=79
79 % 10 = 9
So 3528-12-9 is a valid CAS Registry Number.

3528-12-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethyl(4-trimethylsilylbut-2-enyl)silane

1.2 Other means of identification

Product number -
Other names 2-butene-1,4-diylbis<trimethylsilane>

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3528-12-9 SDS

3528-12-9Relevant academic research and scientific papers

Preparation of allylsilanes via cross-metathesis

Crowe, William E.,Goldberg, Daniel R.,Zhang, Zhijia J.

, p. 2117 - 2120 (2007/10/03)

Allylsilanes are prepared by simple metathetical cross-coupling of terminal olefins with allyltrimethylsilane. Allyltrimethylsilane coupling with π-substituted terminal olefins (styrenes, 1-phenyl-1,3-butadiene, and acrylonitrile) proceeds in excellent yi

OLEFIN METATETHESIS OF ALKENYLTRIMETHYLSILANES

Berglund, Mats,Andersson, Carlaxel,Larsson, Ragnar

, p. C15 - C17 (2007/10/02)

WCl6 has been used as a catalyst for the metathesis of various alkenylsilanes and the degree of conversion found to be dependent on the distance between the olefinic bond and the silyl group.The first observation of metathetical conversion of allyltrimethylsilane in the absence of a co-catalyst is reported.

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