35435-68-8

Basic information

• Product Name: 1,4-Butanediol, monoacetate
• CAS NO: 35435-68-8
• Molecular Formula: C6H12O3
• Molecular Weight: 132.159
• Mol File: 35435-68-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 1,4-Butanediol, monoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Butanediol, monoacetate(35435-68-8)
• EPA Substance Registry System: 1,4-Butanediol, monoacetate(35435-68-8)

Safety Data

• Hazardous Substances Data: 35435-68-8(Hazardous Substances Data)

Usage

Chemical structure

Ester formed by the combination of 1,4-Butanediol and acetic acid

Physical state

Clear, colorless liquid

Odor

Slight odor

Solubility

Soluble in water

Primary uses

a. Solvent
b. Intermediate in the production of various industrial chemicals

Additional applications

a. Plasticizer
b. Manufacturing of resins, coatings, and adhesives

Pharmaceutical industry use

Precursor for the synthesis of certain medications

Upstream product

• 110-63-4 Butane-1,4-diol 
• 141-78-6 ethyl acetate 
• 108-05-4 vinyl acetate 
• 591-87-7 Allyl acetate 
• 201230-82-2 carbon monoxide 
• 64-19-7 acetic acid 
• 175849-49-7 acetic acid 4-(tert-butyldimethylsilanyloxy)butyl ester 
• 108-24-7 acetic anhydride 
• 626-68-6 2-methyl-[1,3]dioxane 
• 50-00-0 formaldehyd 

Downstream Products

• 6962-92-1 4-Chlorobutyl acetate 
• 4753-59-7 4-Bromobutyl acetate 
• 693272-66-1 acetic acid 4-(biphenyl-4-yl-diphenyl-methoxy)-butyl ester 
• 693272-65-0 acetic acid 4-(biphenyl-4-yl-phenyl-methoxy)-butyl ester 
• 373-09-1 4-fluorobutyl acetate 
• 1082056-34-5 Bis(4-methoxyphenyl)methyl 4-acetoxybutyl ether 
• 1070868-10-8 C₁₄H₂₂O₄ 
• 807639-73-2 1-butanol,4-[2-(4-chloro-2-nitrophenyl)ethoxy]-, acetate(ester) 
• 114423-64-2 trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 

Relevant articles and documents

METHOD FOR PRODUCING 1,3-BUTADIENE FROM 1,4-BUTANEDIOL

A method for producing 1,3-butadiene from a 1,4-butanediol feedstock: One step for esterification of 1,4-butanediol,One step for pyrolysis of 1,4-butanediol diester, producing butadiene.

Tandem hydroformylation/hydrogenation of alkenes to normal alcohols using Rh/Ru dual catalyst or Ru single component catalyst

The catalyst system for tandem hydroformylation/hydrogenation of terminal alkenes to the corresponding homologated normal alcohol was developed. The reaction mechanism for the Rh/Ru dual catalyst was investigated by real-time IR monitoring experiments and 31P NMR spectroscopy, which proved the mutual orthogonality of Rh-catalyzed hydroformylation and Ru-catalyzed hydrogenation. Detailed investigation about Ru-catalyzed hydrogenation of undecanal under H2/CO pressure clarified different kinetics from the hydrogenation under H2 and gave a clue to design more active hydrogenation catalysts under H2/CO atmosphere. The solely Ru-catalyzed normal selective hydroformylation/hydrogenation is also reported.

Effects of acidity and immiscibility of lactam-based Bronsted-acidic ionic liquids on their catalytic performance for esterification

Several lactam-based Bronsted-acidic ionic liquids with different acidities were synthesized and applied to the esterification of carboxylic acids with alcohols. High conversion and perfect selectivity were obtained under mild conditions. Among the ionic liquids investigated, those having a methyl sulfonate anion (which has weaker acidity than those with a tetrafluoroborate anion) afforded the highest activity for esterification. The results indicated that the acidity and immiscibility of Bronsted-acidic ionic liquids has a synergistic effect on their esterification performance. Furthermore, after removal of water under vacuum, such ionic liquids could be reused several times without substantial loss of activity.