354529-99-0

Basic information

• Product Name: 1-phenyl-2-butyl-2-propen-1-one
• Synonyms: 1-phenyl-2-butyl-2-propen-1-one
• CAS NO: 354529-99-0
• Molecular Weight: 188.269
• Mol File: 354529-99-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-phenyl-2-butyl-2-propen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-2-butyl-2-propen-1-one(354529-99-0)
• EPA Substance Registry System: 1-phenyl-2-butyl-2-propen-1-one(354529-99-0)

Safety Data

• Hazardous Substances Data: 354529-99-0(Hazardous Substances Data)

Upstream product

• 84370-13-8 (1-phenyl-2-(triphenyl-λ5-phosphanylidene)hexan-1-one) 
• 21406-61-1 pentyltriphenylphosphonium bromide 
• 98-88-4 benzoyl chloride 
• 124-38-9 carbon dioxide 
• 15121-79-6 2-(hydroxymethyl)-1-phenylprop-2-en-1-one 
• 91962-95-7 α-acetoxymethyl phenyl vinyl ketone 
• 2234-82-4 1-propylmagnesium chloride 
• 100-52-7 benzaldehyde 
• 693-02-7 hex-1-yne 
• 50-00-0 formaldehyd 
• 942-92-7 caprophenone 
• 100-97-0 hexamethylenetetramine 
• 41531-80-0 2-hydroxymethyl-1-phenyl-1-hexanone 
• 1129-65-3 (hex-1-yn-1-yl)benzene 

Downstream Products

• 1396011-20-3 (R)-2-((benzylthio)methyl)-1-phenylhexan-1-one 
• 76937-26-3 2-butyl-2,3-dihydro-1H-inden-1-one 

Relevant articles and documents

Synthesis method of terminal olefin type compound

The invention discloses a synthesis method of a terminal olefin type compound. The synthesis method comprises the following steps: taking a phosphorus ylide compound as a raw material and carbon dioxide as a C1 synthon in an organic solvent; reacting in the presence of a reducing agent to prepare the terminal olefin type compound, wherein the mole ratio of the phosphorus ylide compound to the reducing agent is 1 to (1 to 6) and the pressure of carbon dioxide is 1 to 3atm. The synthesis method disclosed by the invention has the advantages of convenience for operation, moderate conditions, widesubstrate applicable range and high efficiency; the defects in the prior art are filled; the synthesis method takes the carbon dioxide as synthon and carbon dioxide can be effectively absorbed so thata greenhouse effect is effectively prevented.

Thermal retro-aldol reaction using fluorous ether F-626 as a reaction medium

A high-boiling, fluorous-organic hybrid ether, F-626, was tested for use in thermal retro-aldol reactions and found to be an excellent reaction medium in view of the ease of separation from the product by fluorous/organic biphasic treatment. The recovered F-626 can be readily reused for subsequent runs.

Synthesis and stereochemical aspects of 2,6-disubstituted perhydroazulenes - Core units for a new class of liquid crystalline materials

A novel approach for the synthesis of cis/trans-fused perhydroazulenes 13-19 is reported. The stereochemistry of the derivatives of carbene addition products 9a-c/20-22, of the 2,6-disubstituted perhydroazulenes 12a-c/23-25, and that of compounds 26-27 has been studied by single-crystal X-ray crystallography. The hydrogenation of the tropylidene to the perhydroazulene skeleton under various conditions is described. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.