35782-14-0Relevant articles and documents
Catalytic hydrodefluorination of fluoromethanes at room temperature by silylium-ion-like surface species
Ahrens, Mike,Scholz, Gudrun,Braun, Thomas,Kemnitz, Erhard
, p. 5328 - 5332 (2013)
'Al'l about F: Aluminum chlorofluoride (ACF) catalyzes the hydrodefluorination, as well as Friedel-Crafts reactions of fluorinated methanes in the presence of Et3SiH. A surface-bound silylium-ion-like species is considered to be a crucial intermediate in achieving the C-F bond cleavage. Copyright
Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides
Siwek, Agnieszka K.,Ahrens, Mike,Feist, Michael,Braun, Thomas,Kemnitz, Erhard
, p. 839 - 845 (2017/03/13)
We report on the activation of chlorinated methanes by the heterogeneous catalysts aluminum chlorofluoride (ACF) and high-surface aluminum fluoride (HS-AlF3) under moderate conditions. For comparison, chlorinated toluenes and 1,2-dichloroethane
The conformational distribution in diphenylmethane determined by nuclear magnetic resonance spectroscopy of a sample dissolved in a nematic liquid crystalline solvent
Celebre,De Luca,Emsley,Foord,Longeri,Lucchesini,Pileio
, p. 6417 - 6426 (2007/10/03)
The application of the probabilistic approach, coupled with the AP model for the conformational dependence of the interaction with liquid crystal molecules, gives a distribution PLC(τ1, τ2) which is similar to that found b
