3613-53-4

Basic information

• Product Name: 1-[(benzyloxy)methyl]-4-methoxybenzene
• CAS NO: 3613-53-4
• Molecular Formula: C₁₅H₁₆O₂
• Molecular Weight: 228.2863
• Mol File: 3613-53-4.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 329.3°C at 760 mmHg
• Flash Point: 126.2°C
• Density: 1.07g/cm³
• Vapor Pressure: 0.000343mmHg at 25°C
• Refractive Index: 1.557
• CAS DataBase Reference: 1-[(benzyloxy)methyl]-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(benzyloxy)methyl]-4-methoxybenzene(3613-53-4)
• EPA Substance Registry System: 1-[(benzyloxy)methyl]-4-methoxybenzene(3613-53-4)

Safety Data

• Hazardous Substances Data: 3613-53-4(Hazardous Substances Data)

Usage

Appearance

White to off-white solid

Usage

a. Synthesis of pharmaceuticals
b. Synthesis of organic compounds

Application

Reagent in organic synthesis

Hazards

a. Skin irritant
b. Eye irritant

Safety precautions

a. Handle with caution
b. Use proper protective equipment (gloves, goggles, etc.) to avoid adverse health effects

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 100-51-6 benzyl alcohol 
• 100-39-0 benzyl bromide 
• 123-11-5 4-methoxy-benzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 100-44-7 benzyl chloride 
• 67-56-1 methanol 
• 14642-79-6 benzyloxy-trimethylsilane 
• 623-12-1 4-chloromethoxybenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 3587-60-8 Benzyloxymethyl chloride 
• 19013-30-0 p-methoxyphenyl mesylate 
• 104-21-2 p-methoxybenzyl acetate 
• 2746-25-0 p-Methoxybenzyl bromide 

Downstream Products

• 104-93-8 p-methylanizole 
• 1657-55-2 1,2-bis(4-methoxyphenyl)ethane 
• 108-88-3 toluene 
• 83318-92-7 ethyl p-methoxybenzyl sulfide 
• 100-51-6 benzyl alcohol 
• 831-91-4 Benzyl phenyl sulfide 
• 5023-67-6 4-methoxybenzyl phenyl sulfide 
• 100-52-7 benzaldehyde 
• 351-70-2 benzyl trifluoroacetate 
• 6316-54-7 4-methoxy-benzoic acid benzyl ester 
• 123-11-5 4-methoxy-benzaldehyde 
• 105-13-5 4-Methoxybenzyl alcohol 
• 2749-70-4 bis(benzyloxy)methane 
• 31600-55-2 benzyl methoxymethyl ether 

Relevant articles and documents

INSECTICIDAL COMPOSITION

PROBLEM TO BE SOLVED: To provide a composition that can exhibit effective insecticidal action on insect pests. SOLUTION: An insecticidal composition comprises, e.g., a compound represented by general formula (1) in the figure. [R1 is a C1-10 alkyl group or the like, where the alkyl group and the like may be substituted with a halogen atom or the like; R2 is a hydrogen atom or the like, or R2 may bind a methoxy group binding a carbon atom adjacent to a carbon atom which R2 binds, to form a -O-CH2-O- group.] SELECTED DRAWING: None COPYRIGHT: (C)2021,JPO&INPIT

Auto-Tandem Catalysis with Frustrated Lewis Pairs for Reductive Etherification of Aldehydes and Ketones

Herein we report that a single frustrated Lewis pair (FLP) catalyst can promote the reductive etherification of aldehydes and ketones. The reaction does not require an exogenous acid catalyst, but the combined action of FLP on H2, R-OH or H2O generates the required Br?nsted acid in a reversible, “turn on” manner. The method is not only a complementary metal-free reductive etherification, but also a niche procedure for ethers that would be either synthetically inconvenient or even intractable to access by alternative synthetic protocols.