36449-75-9Relevant academic research and scientific papers
BISPHENOLATE TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF
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Page/Page column 38, (2019/02/15)
Bis phenolate transition metal complexes are disclosed for use in alkene polymerization, with optional chain transfer agent, to produce polyolefins.
Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex
Bedford, Robin B.,Brenner, Peter B.,Carter, Emma,Gallagher, Timothy,Murphy, Damien M.,Pye, Dominic R.
supporting information, p. 5940 - 5943 (2015/01/08)
Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).
NOVEL THIOPHENE DERIVATIVES AS IMMUNOSUPPRESSIVE AGENTS
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Page/Page column 61, (2010/02/15)
The invention relates to novel thiophene derivatives, their preparation and their use as pharmaceutically active compounds. Said compounds particularly act as immunosuppressive agents.
NOVEL THIOPHENE DERIVATIVES
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Page/Page column 65, (2010/02/15)
The invention relates to novel thiophene derivatives, their preparation and their use as pharmaceutically active compounds. Said compounds particularly act as immunosuppressive agents.
Imidazopyridinone derivatives and their use as phosphodiesterase inhibitors
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, (2008/06/13)
A compound (Ia): wherein the variables are defined in the specification, its prodrug or a pharmaceutically acceptable salt thereof useful in the treatment of angina, hypertension etc.
Tetracyclic triterpene derivatives with immunosuppressant activity
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, (2008/06/13)
The compounds of Formula I are useful as immunosuppressive agents.
Diastereoselective intramolecular meta photocycloaddition of side-chain- substituted 5-(2-methoxyphenyl)pent-1-enes
Timmermans, Johan L.,Wamelink, Marc P.,Lodder, Gerrit,Cornelisse, Jan
, p. 463 - 470 (2007/10/03)
Irradiation of a series of 5-(2-methoxyphenyl)pent-1-enes substituted with a hydroxy or trimethylsilyloxy group at the α-, β-, or γ-position of the side-chain yields in all cases meta photocycloadducts, in which the configuration at the substituted carbon atom is mainly endo. This indicates that the diastereoselectivity originates from minimization of steric interactions between the side-chain substituent and the ortho-methoxy group at the arene unit. Hydrogen bonding does not seem to be involved. The introduction of the side-chain substituents also influences the regioselectivity of the addition: The linear to angular adduct ratios are significantly increased compared to the case of the parent compound.
