370555-60-5

Upstream product

• 54555-84-9 benzyl iodoethyl ether 
• 68972-96-3 (Z)-1,4-dibenzyloxy-2-butene 
• 100-39-0 benzyl bromide 
• 1462-37-9 bromoethyl-2-benzyl ether 
• 374077-59-5 4-benzyloxy-2,2-dimethyl-butyric acid ethyl ester 
• 823180-17-2 methyl 4-(benzyloxy)-2,2-dimethylbutanoate 
• 622-08-2 2-Benzyloxyethanol 
• 370555-59-2 4-(benzyloxy)-2,2-dimethylbutan-1-ol 

Downstream Products

• 823180-03-6 (((5,5-diiodo-3,3-dimethylpent-4-enyl)oxy)methyl)benzene 
• 374077-57-3 2-(1,1-Dimethyl-3-(2-nitrophenylselenyl)propyl)-1,4-naphthalenedione 
• 374077-58-4 1-(3,3-dimethyl-pent-4-ynylselanyl)-2-nitro-benzene 
• 67099-42-7 3,3-Dimethyl-5-benzyloxy-1-pentin 

Relevant academic research and scientific papers

Highly efficient two-step synthesis of C-sp3-centered geminal diiodides

(Chemical Equation Presented) Trisubstituted gem-diiodoalkenes of functionalized chains are efficiently reduced to the corresponding terminal geminal diiodides in high yields upon treatment with the diazene precursor, diethyl 4-(hydrazinosulfonyl)-benzyl phosphonate.

Novel use of a selenoalkyne within untraditionally mild D?tz benzannulation processes; total synthesis of a Calceolaria andina L. natural hydroxylated naphthoquinone

A total synthesis of the Calceolaria andina L. extract 2-(1,1-dimethyl-2-propenyl)-3-hydroxy-1,4-naphthalenedione is described incorporating the first reported D?tz benzannulation of a selenoalkyne. Importantly, it has been shown that it is possible to effect this annulation at ambient temperature under dry state conditions with a significant improvement in cyclisation yield.