40028-30-6

Basic information

• Product Name: Benzene, 1-methoxy-4-[2-(phenylthio)ethenyl]-
• CAS NO: 40028-30-6
• Molecular Formula: C15H14OS
• Molecular Weight: 242.342
• Mol File: 40028-30-6.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[2-(phenylthio)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[2-(phenylthio)ethenyl]-(40028-30-6)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[2-(phenylthio)ethenyl]-(40028-30-6)

Safety Data

• Hazardous Substances Data: 40028-30-6(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 768-60-5 4-methoxyphenylacetylen 
• 3179-10-0 1-methoxy-4-(2-nitro-vinyl)-benzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1822-73-7 phenylthioethylene 
• 6303-59-9 (E)-4-(2-bromo-vinyl)-anisole 
• 943-89-5 (E)-3-(4-methoxyphenyl)acrylic acid 
• 214907-25-2 (4-methoxystyrene)boronic acid 
• 63413-91-2 3-(phenylthio)acrylic acid 
• 100-66-3 methoxybenzene 
• 7031-27-8 (phenylthio)acetic acid chloride 
• 21875-72-9 1-(4-methoxy-phenyl)-2-phenylsulfanyl-ethanone 
• 6388-72-3 2-(4-methoxyphenyl)oxirane 
• 6388-69-8 2-(4-methoxyphenyl)thiirane 

Downstream Products

• 5703-26-4 4-Methoxyphenylacetaldehyde 
• 882-33-7 diphenyldisulfane 
• 87891-80-3 (E)-4-[2-(phenylsulfonyl)vinyl]anisole 
• 1068616-29-4 (E)-1-methoxy-4-(penta-1,4-diene-1-yl)benzene 
• 86211-02-1 1-(2,2-Bis-phenylsulfanyl-ethyl)-4-methoxy-benzene 

Relevant articles and documents

Electrophilic Vinylation of Thiols under Mild and Transition Metal-Free Conditions

The iodine(III) reagents vinylbenziodoxolones (VBX) were employed to vinylate a series of aliphatic and aromatic thiols, providing E-alkenyl sulfides with complete chemo- and regioselectivity, as well as excellent stereoselectivity. The methodology displays high functional group tolerance and proceeds under mild and transition metal-free conditions without the need for excess substrate or reagents. Mercaptothiazoles could be vinylated under modified conditions, resulting in opposite stereoselectivity compared to previous reactions with vinyliodonium salts. Novel VBX reagents with substituted benziodoxolone cores were prepared, and improved reactivity was discovered with a dimethyl-substituted core.

Decarboxylative Heck-Type Reactions of Thioacrylic Acid with Aryl Bromides

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Highly stereoselective anti-Markovnikov hydrothiolation of alkynes and electron-deficient alkenes by a supported Cu-NHC complex

A practical, efficient, and low-cost heterogeneous catalyst consisting of a Cu-NHC (N-heterocyclic carbene) complex grafted to SBA-15 silica for the catalytic hydrothiolation of alkynes and electron-deficient alkenes under mild reaction conditions has been developed. The heterogeneous catalyst displays higher activity and stereoselectivity to Z-anti-Markovnikov isomers compared with the homogeneous analog under otherwise identical reaction conditions. The catalytic system is applicable to a broad range of alkynes and thiols and is recyclable without significant loss in catalytic performance. High activity and perfect selectivity to alkyl sulfides formed by the addition of electron-deficient alkenes to various thiols catalyzed by the supported Cu-NHC complex were also realized. This journal is the Partner Organisations 2014.