404-38-6

Basic information

• Product Name: Benzene, 1,1'-thiobis[4-fluoro-
• CAS NO: 404-38-6
• Molecular Formula: C12H8F2S
• Molecular Weight: 222.258
• Mol File: 404-38-6.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-thiobis[4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-thiobis[4-fluoro-(404-38-6)
• EPA Substance Registry System: Benzene, 1,1'-thiobis[4-fluoro-(404-38-6)

Safety Data

• Hazardous Substances Data: 404-38-6(Hazardous Substances Data)

Upstream product

• 371-42-6 4-Fluorothiophenol 
• 395-25-5 bis(4-fluorophenyl)sulfoxide 
• 7361-89-9 di-n-propyl diselenide 
• 89959-08-0 MoO(2,6-bis(2,2-diphenyl-2-mercaptoethyl)pyridine^(2-))(DMF) 
• 352-34-1 4-fluoro-1-iodobenzene 
• 732306-64-8 bis(4-fluorophenyl)iodonium triflate 
• 459-45-0 4-fluorobenzenediazonium tetrafluoroborate 
• 405-31-2 bis(4-fluorophenyl)disulfide 
• 352-13-6 4-flourophenylmagnesium bromide 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 98-08-8 α,α,α-trifluorotoluene 
• 462-06-6 fluorobenzene 
• 349-88-2 4-Fluorobenzenesulfonyl chloride 
• 352-33-0 1-Chloro-4-fluorobenzene 

Downstream Products

• 71888-05-6 bis(4-fluorophenyl)(imino)-λ⁶-sulfanone 
• 395-25-5 bis(4-fluorophenyl)sulfoxide 
• 383-29-9 bis(p-fluorophenyl)sulfone 
• 1194484-47-3 4,4'-difluorodiphenyl(difluoro)sulfurane 
• 398-23-2 4,4'-difluorobiphenyl 
• 475598-83-5 tris(4-fluorophenyl)sulfonium trifluoromethanesulfonate 
• 330-83-6 N-(4-fluorophenyl)aniline 
• 500-41-4 3-fluoro-N-phenyl-aniline 
• 136684-94-1 cyclohexyl-(4-fluorophenyl)-amine 

Relevant articles and documents

Thiol as an Electron Donor in Molybdenum Oxo-Transferase Analogue Reaction Systems: Observations by 19F NMR Spectroscopy and Biological Implications

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Heterogeneously Ni-Pd nanoparticle-catalyzed base-free formal C-S bond metathesis of thiols

This study rationally designed a heterogeneously catalyzed system (i.e., using Ni-Pd alloy nanoparticles supported on hydroxyapatite (Ni-Pd/HAP) under an H2atmosphere) achieving an efficient base-free formal C-S bond metathesis of various thiolsviasuppression of the Ni catalysis deactivation.

Dechalcogenization of Aryl Dichalcogenides to Synthesize Aryl Chalcogenides via Copper Catalysis

An application for dechalcogenization of aryl dichalcogenides via copper catalysis to synthesize aryl chalcogenides is disclosed. This approach is highlighted by the practical conditions, broad substrate scope, and good functional group tolerance with several sensitive groups such as aldehyde, ketone, ester, amide, cyanide, alkene, nitro, and methylsulfonyl. Furthermore, the robustness of this methodology is depicted by the late-stage modification of estrone and synthesis of vortioxetine. Remarkably, synthesis of more challenging organic materials with large ring tension under milder conditions and synthesis of some halogen contained diaryl sulfides which could not be synthesized using metal-catalyzed coupling reactions of aryl halogen are successfully accomplished with this protocol.