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Di(p-methoxyphenyl)tellurium dichloride is an organotellurium compound with the chemical formula C14H14Cl2O2Te. It is a colorless solid that is soluble in common organic solvents such as dichloromethane, chloroform, and acetone. di(p-methoxyphenyl)tellurium dichloride is synthesized by reacting p-methoxyphenylmagnesium bromide with dichlorodimethyltelluride. Di(p-methoxyphenyl)tellurium dichloride is of interest in the field of organometallic chemistry and has potential applications in the synthesis of other tellurium-containing compounds. It is also used as a reagent in various organic reactions, such as the formation of carbon-tellurium bonds and as a catalyst in certain organic transformations. Due to its reactivity and potential toxicity, it is important to handle di(p-methoxyphenyl)tellurium dichloride with care and in accordance with proper safety protocols.

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  • 4456-36-4 Structure
  • Basic information

    1. Product Name: di(p-methoxyphenyl)tellurium dichloride
    2. Synonyms: di(p-methoxyphenyl)tellurium dichloride
    3. CAS NO:4456-36-4
    4. Molecular Formula:
    5. Molecular Weight: 412.77
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 4456-36-4.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: di(p-methoxyphenyl)tellurium dichloride(CAS DataBase Reference)
    10. NIST Chemistry Reference: di(p-methoxyphenyl)tellurium dichloride(4456-36-4)
    11. EPA Substance Registry System: di(p-methoxyphenyl)tellurium dichloride(4456-36-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 4456-36-4(Hazardous Substances Data)

4456-36-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 4456-36-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,4,5 and 6 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 4456-36:
(6*4)+(5*4)+(4*5)+(3*6)+(2*3)+(1*6)=94
94 % 10 = 4
So 4456-36-4 is a valid CAS Registry Number.

4456-36-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name cis-1,3-dimethyl-4-phenyl-2-azetidinone

1.2 Other means of identification

Product number -
Other names N,3-Dimethyl-4-phenylazetidin-2-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4456-36-4 SDS

4456-36-4Relevant articles and documents

Synthesis, Characterization and Antimicrobial Studies of Some New Tellurium(IV) Complexes Derived from 2-[(2-Hydroxyphenyl)imino methyl]-1-naphthol Schiff Base

Dalal, Mahak,Garg, Sapana,Kumar, Manish,Verma, K. K.

, p. 183 - 190 (2022/01/08)

This article reports the synthesis, characterization and antimicrobial screening of a tridentate 2-[(2-hydroxyphenyl)imino methyl]-1naphthol ligand (H2AP) and its organotellurium(IV) complexes. Structural characterization of the synthesized ligand and com

Some organotellurium(iv) complexes of 1-methyl-3-(p-tolylimino)indolin-2-one schiff base

KUMAR, MANISH,VERMA,GARG, SAPANA

, p. 1236 - 1244 (2021/06/09)

Six new hexa-coordinated organotellurium(IV) complexes of type RTeCl3 NMeIPT and R2TeCl2 NMeIPT (R = 4-hydroxyphenyl, 4- methoxyphenyl or 3-methy-4-hydroxyphenyl; NMeIPT(L) = Schiff base (1-methyl-3-(p-tolylimino)indolin-2-one) derived from condensation o

COMPOSITION FOR RESIST UNDERLAYER FILM FORMATION, UNDERLAYER FILM FOR LITHOGRAPHY, AND PATTERN FORMATION METHOD

-

Paragraph 0312-0315, (2020/08/22)

The present invention provides a composition for resist underlayer film formation comprising a tellurium-containing compound or a tellurium-containing resin.

OPTICAL COMPONENT FORMING COMPOSITION AND CURED PRODUCT THEREOF

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Paragraph 0358-0361, (2020/08/30)

The present invention provides an optical component forming composition comprising a tellurium-containing compound or a tellurium-containing resin.

The Anticancer Activity of Organotelluranes: Potential Role in Integrin Inactivation

Silberman, Alon,Kalechman, Yona,Hirsch, Shira,Erlich, Ziv,Sredni, Benjamin,Albeck, Amnon

, p. 918 - 927 (2016/05/24)

Organic TeIV compounds (organotelluranes) differing in their labile ligands exhibited anti-integrin activities in vitro and anti-metastatic properties in vivo. They underwent ligand substitution with l-cysteine, as a thiol model compound. Unlike inorganic TeIV compounds, the organotelluranes did not form a stable complex with cysteine, but rather immediately oxidized it. The organotelluranes inhibited integrin functions, such as adhesion, migration, and metalloproteinase secretion mediation in B16F10 murine melanoma cells. In comparison, a reduced derivative with no labile ligand inhibited adhesion of B16F10 cells to a significantly lower extent, thus pointing to the importance of the labile ligands of the TeIV atom. One of the organotelluranes inhibited circulating cancer cells in vivo, possibly by integrin inhibition. Our results extend the current knowledge on the reactivity and mechanism of organotelluranes with different labile ligands and highlight their clinical potential.

Studies on the pyrazine complexes of some diaryltellurium dihalides

Narwal, Jitender Kumar,Chhabra, Shashi,Malik, Rajesh Kumar,Garg, Sapana,Verma

, p. 1339 - 1349 (2014/05/06)

Nine new Pyrazine Complexes of diaryltelluriumdihalides, R 2TeX2.Pyz (R =p-methoxyphenyl, p-hydroxyphenyl and 3-methyl- 4-hydroxy phenyl; X=Cl, Br, I; Pyz = pyrazine) have been prepared by reactions of diaryltelluriumdihalides with pyrazine in 1:1 molar ratio. These complexes have been characterized by elemental analysis, conductance and cryoscopic measurements, infrared and proton magnetic resonance spectral studies. Conductance studies in nitrobenzene, acetone and acetonitrile predict their non-electrolyte type behaviour in these solvents, which is well supported by cryoscopic data in nitrobenzene. IR and 1H NMR studies suggest the unidentate nature of pyrazine in these complexes, involving only one nitrogen atom in coordination. Thus, tellurium in R2TeX2.Pyz complexes attains a coordination number of five probably in a square pyramidal.

Studies on nickel(II) and palladium(II) complexes with some tetraazamacrocycles containing tellurium

Rathee, Nitu,Verma, Krishan Kumar

, p. 325 - 333 (2012/05/20)

The synthesis of 10-membered and 12-membered tellurium-containing tetraazamacrocyclic complexes of divalent nickel and palladium by template condensation of diaryltellurium dichlorides, (aryl = p-hydroxyphenyl, 4-hydroxy-3-methyl-phenyl, p-methoxyphenyl)

Synthesis and characterization of some group 12 metal complexes with tellurium containing 10-membered tetraazamacrocyclic ligands

Nitu,Verma

body text, p. 1158 - 1163 (2012/06/18)

A new series of 10-membered tellurium containing tetraazamacrocyclic complexes, [ML1Cl2], [ML2Cl2] and [ML3Cl2], where [M=Zn(II), Cd(II), Hg(II); L1, L2 and L3=10-membered tellurium containing tetraazamacrocyclic ligands] have been prepared via the templa

SYNTHESIS AND STRUCTURES OF AROMATIC AND HETEROCYCLIC TELLURIUM COMPOUNDS. XXXI. REACTIONS OF ARYLTELLURIUM OXOCHLORIDES

Rivkin, B. B.,Maksimenko, A. A.,Sadekov, I. D.

, p. 1049 - 1055 (2007/10/02)

The reactions of aryltellurium oxochlorides with the lowest aliphatic acid anhydrides lead to diaryltellurium dichlorides, Te, and CO2 through the intermediate formation of diaryltellurium chloride diacylates.Aryltellurium trichlorides and carboxylic acid anhydrides are formed in the reaction with acyl chlorides.The chlorine atom in the tellurium oxochlorides is replaced by a phenyl group on reaction with phenyllithium.The reaction with dimedone in the presence of triethylamine leads to diaryl ditellurides and a product of trimerization of a carbene, viz., a dimedone derivative that is formed in the thermal decomposition of the intermediate ylid.

Synthesis and Characterisation of Diorganotellurium(IV) Bis(haloacetates)

Srivastava, T. N.,Singh, Jai Deo

, p. 260 - 262 (2007/10/02)

A new diorganotellurium bis(haloacetates) of the type R2Te(OCOR')2 (R = C6H5, p-MeOC6H4, CH3; R' = CF3, CCl3, CHCl2 and CH2Cl) have been prepared and characterised.The IR spectral data of these haloacetates indicate that both the haloacetate groups are eq

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