4538-55-0Relevant articles and documents
REACTION OF RED PHOSPHORUS WITH BENZYL HALIDES IN A SUPERBASE SYSTEM
Gusarova, N. K.,Trofimov, B. A.,Malysheva, S. F.,Rakhmatulina, T. N.,Vyalykh, E. P.,Voronkov, M. G.
, p. 430 (1989)
-
Reactions of elemental phoshorus and phosphine with electrophiles in superbasic systems: XIX. Formation of the C-P bond with participation of elemental phosphorus under microwave assistance
Malysheva,Gusarova,Kuimov,Sukhov,Kudryavtsev,Sinyashin,Budnikova,Pai,Tolstikov,Trofimov
, p. 415 - 420 (2008/02/11)
Microwave irradiation facilitates phosphorylation of aryl methyl chlorides and styrene with red phosphorus in the presence of strong bases and increases the yield of the main products, tertiary phosphine oxides. Nauka/Interperiodica 2007.
The reaction of N-dichlorophosphoryl-P-trichlorophosphazene with alkyl grignard reagents
Asian,Ozturk,Arslan
, p. 413 - 416 (2007/10/03)
The reactions of N-dichlorophosphoryl-P-trichlorophosphazene Cl3P=N-P(O)Cl2 (1) with benzylmagnesium bromide, 2-phenylethylmagnesium bromide, trimethylsilylmethylmagnesium chloride, n-butylmagnesium bromide, cyclohexylmagnesium bromide, cyclopentylmagnesium bromide, tert-butylmagnesium bromide, iso-propylmagnesium bromide, and ethylmagnesium bromide were studied. Tri- and pentaalkyl phosphazenes were obtained in very poor yield from trimethylsilylmethylmagnesium chloride and cyclohexylmagnesium bromide, respectively. Trialkylphosphoryl compounds formed from benzyl-, 2-phenylethyl-, and n-butylmagnesium bromide. No phosphorus compound could be isolated from the reaction of 1 with t-butyl-, cyclopentyl-, iso-propyl-, and ethylmagnesium bromide.