470-35-9

Basic information

• Product Name: TETRAPHENYLETHYLENE OXIDE
• Synonyms: TETRAPHENYLETHYLENE OXIDE;Tetraphenyloxirane;α-Benzpinacoline
• CAS NO: 470-35-9
• Molecular Formula: C₂₆H₂₀O
• Molecular Weight: 348.44
• Mol File: 470-35-9.mol
• Article Data: 27

Chemical Properties

• Appearance: /
• CAS DataBase Reference: TETRAPHENYLETHYLENE OXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: TETRAPHENYLETHYLENE OXIDE(470-35-9)
• EPA Substance Registry System: TETRAPHENYLETHYLENE OXIDE(470-35-9)

Safety Data

• Hazardous Substances Data: 470-35-9(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 98-88-4 benzoyl chloride 
• 1217-45-4 9,10-Dicyanoanthracene 
• 93-59-4 Perbenzoic acid 
• 67-66-3 chloroform 
• 632-51-9 1,1,2,2-tetraphenylethylene 
• 2051-90-3 Dichlorodiphenylmethane 
• 108-88-3 toluene 
• 7601-90-3 perchloric acid 
• 464-72-2 tetraphenylethane-1,2-diol 
• 7732-18-5 water 
• 64-19-7 acetic acid 
• 10026-04-7 tetrachlorosilane 
• 1600-30-2 1,2-dichloro-1,1,2,2-tetraphenylethane 

Downstream Products

• 1016-09-7 benzhydryl methyl ether 
• 1217-45-4 9,10-dicyanoanthracene radical anion 
• 119-61-9 benzophenone 
• 778-22-3 2,2-diphenylpropane 
• 632-51-9 1,1,2,2-tetraphenylethylene 
• 612-00-0 1,1'-ethylidenebis-benzene 
• 599-67-7 1,1-diphenylethanol 
• 39520-11-1 2-(1-methylethenyl)-1,1-diphenylcyclopropane 
• 39520-10-0 1-ethenyl-1-methyl-2,2-diphenylcyclopropane 
• 32987-83-0 3,3,5,5-tetraphenyl-1,2,4-trioxolane 
• 91-01-0 1,1-Diphenylmethanol 
• 101-81-5 Diphenylmethane 
• 632-50-8 1,1,2,2-tetraphenylethane 
• 1733-63-7 1,2,2-triphenylethan-1-one 

Relevant articles and documents

EPR EVIDENCE FOR A SINGLE ELECTRON TRANSFER MECHANISM IN REACTIONS OF AROMATIC KETONES WITH LITHIUM AMIDES

Direct spectroscopic evidence (EPR) supporting a single electron transfer mechanism in the reaction of lithium amides with aromatic ketones is presented.

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Nickel-catalyzed deoxygenation of oxiranes: Conversion of epoxides to alkenes

Deoxygenation of epoxides takes place under the catalysis of nickel in the presence of diethylzinc as a deoxygenation agent to yield alkenes. Epoxides with a wide variety of substitution patterns are deoxygenated in this catalytic system to give terminal, 1,1-disubstituted, 1,2-disubstituted, trisubstituted, and tetrasubstituted alkenes in high yields. Reactions of 1,2-disubstituted epoxides we examined proceeded in an E-stereoselective manner. High compatibility with other functional groups through this transformation was also observed.

Pinacol Rearrangement and Direct Nucleophilic Substitution of Allylic Alcohols Promoted by Graphene Oxide and Graphene Oxide CO2H

Graphene oxide (GO) and carboxylic acid functionalized GO (GO–CO2H) have been found to efficiently promote the heterogeneous and environmentally friendly pinacol rearrangement of 1,2-diols and the direct nucleophilic substitution of allylic alcohols. In general, high yields and regioselectivities are obtained in both reactions using 20 wt % of catalyst loading and mild reaction conditions.

Metalloporphyrinic framework containing multiple pores for highly efficient and selective epoxidation

Metalloporphyrin MnIIICl-5,10,15,20-tetrakis(3,5- biscarboxylphenyl)porphyrin, having eight carboxylate groups in multiple coordination modes, connects with paddle-wheel Zn2(COO)4 units for the construction of an interesting porous porphyrinic framework that demonstrates high efficiency and stability upon epoxidation of olefins with excellent substrate size selectivity.