5032-11-1

Basic information

• Product Name: bis(4-ethoxyphenyl)methanone
• CAS NO: 5032-11-1
• Molecular Formula: C₁₇H₁₈O₃
• Molecular Weight: 270.323
• Mol File: 5032-11-1.mol

Chemical Properties

• Boiling Point: 415.6°C at 760 mmHg
• Flash Point: 196.8°C
• Density: 1.087g/cm³
• Vapor Pressure: 4.09E-07mmHg at 25°C
• Refractive Index: 1.545
• CAS DataBase Reference: bis(4-ethoxyphenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-ethoxyphenyl)methanone(5032-11-1)
• EPA Substance Registry System: bis(4-ethoxyphenyl)methanone(5032-11-1)

Safety Data

• Hazardous Substances Data: 5032-11-1(Hazardous Substances Data)

Upstream product

• 351003-30-0 4-ethoxy-4'-bromo-benzophenone 
• 2212-41-1 bis-(4-ethoxy-phenyl)methane 
• 611-99-4 4,4'-Dihydroxybenzophenone 
• 75-03-6 ethyl iodide 
• 16331-46-7 4-ethoxybenzoylchloride 
• 103-73-1 Phenetole 
• 39179-74-3 C₃₁H₂₈Br₂O₂ 
• 20797-54-0 2,2-bis(4-ethoxyphenyl)acetic acid 
• 74-96-4 ethyl bromide 
• 5031-92-5 1,1-Bis(4-ethoxyphenyl)ethylene 
• 64-19-7 acetic acid 
• 7322-75-0 4,4'-diethoxythiobenzophenone 
• 108-88-3 toluene 
• 554-70-1 triethylphosphine 

Downstream Products

• 5031-92-5 1,1-Bis(4-ethoxyphenyl)ethylene 
• 77799-34-9 3,3-bis-(4-ethoxy-phenyl)-2-phenyl-acrylonitrile 
• 93727-67-4 4,4'-diethoxy-benzhydrol 
• 610-54-8 2,4-dinitro-1-ethoxybenzene 
• 2132-67-4 1,1-bis-(4-ethoxy-phenyl)-2-chloro-ethene 
• 2132-65-2 1,1-bis-(4-ethoxy-phenyl)-2-bromo-ethene 
• 54655-90-2 1,1,4,4-tetrakis-(4-ethoxy-phenyl)-buta-1,3-diene 
• 2132-71-0 2,2-Dichloro-1,1-bis(4-ethoxyphenyl)ethylene 
• 102171-98-2 3,3-bis-(4-ethoxy-phenyl)-acrylic acid 
• 735271-53-1 1,1-bis-(4-ethoxy-phenyl)-2-phenyl-ethene 
• 60883-74-1 1-bromo-2,2-bis(p-ethoxyphenyl)-1-phenylethene 
• 5031-96-9 2.2-Bis-(4'-ethoxyphenyl)acetaldehyd 
• 36374-73-9 C₂₀H₂₆O₄ 
• 56920-81-1 4,4'-(prop-1-ene-1,1-diyl)bis(ethoxybenzene) 

Relevant articles and documents

Regioselective Diboron-Mediated Semireduction of Terminal Allenes

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An efficient and alternative oxidative cross-coupling strategy starting from arylboronic acids and isocyanides for the selective synthesis of amides and diaryl ketones with palladium/copper catalysis is developed. Various substituted benzamides and benzop

Synthesis of Symmetrical Diaryl Ketones by Cobalt-Catalyzed Reaction of Arylzinc Reagents with Ethyl Chloroformate

Symmetrical diaryl ketones were prepared by a cross-coupling reaction between aryl bromides and ethyl chloroformate. This new method, which uses a catalyst composed of CoBr2and a bipyridine ligand along with readily available starting materials, allows for the synthesis of a variety of symmetrical diaryl ketones in moderate to excellent yields (37–99 %) under mild conditions. This reaction, in which ethyl chloroformate acts as a surrogate of carbon monoxide in the presence of cobalt and zinc, represents an interesting alternative to previously known approaches for the synthesis of diarylmethanones.

Pd/Cu-cocatalyzed aerobic oxidative carbonylative homocoupling of arylboronic acids and CO: A highly selective approach to diaryl ketones

A highly selective Pd/Cu-cocatalyzed aerobic oxidative carbonylative homocoupling of arylboronic acids has been developed. This method employs a simple catalytic system, readily available boronic acids as the substrates, molecular oxygen as the oxidant, and 1 atm of CO/O2, which makes this method practical for further applications.

Oxalyl chloride as carbonyl synthon in Pd-catalyzed carbonylations of triarylbismuth and triarylindium organometallic nucleophiles

Oxalyl chloride has been demonstrated to function as C1 carbonyl synthon in the carbonylations of triarylbismuth and triarylindium nucleophiles under palladium-catalyzed conditions. All the three aryl groups from both bismuth and indium reagents participated in carbonylative couplings to afford the corresponding functionalized ketones in high yields. This study also disclosed a novel utilization of oxalyl chloride as facile alternative source of CO for carbonylations under palladium catalysis.

Synthesis of new tetraoxacyclophanes containing benzophenone units

4,4′-Dihydroxybenzophenone was used as a precursor for synthesis of macrocyclic compounds. Low-temperature crystal structures were determined for 4,4′-diethoxybenzophenone (10), C17H18O3, orthorhombic, Pbcn, a = 7.2891(12), b = 6.2827(10), c = 31.1000(5) A, Z = 4 (one molecule with twofold symmetry), and 1,5,19,23-tetraoxa-12,30-dioxo[5.1.5.1]paracyclophane (6), C34H32O6, triclinic, P(-1), a = 9.1559(12), b = 11.634(2), c = 14.124(2) A, α = 93.745(12), β = 102.966(10), γ = 108.591(12)°, Z = 2, (two independent molecules each with inversion symmetry). The interplanar angles between aromatic rings is 53° for compound 10 and 53°, 49° for the two molecules of 6. IR , Raman and UV spectra were recorded for both compounds. Key words: tetraoxaparacyclophanes, benzophenone, preparation, crystal structure, IR and Raman spectra.

Sterically Hindered Free Radicals, XIX. - Stable 4,4',4''-Trisubstituted Triphenylmethyl Radicals

The title radicals (4-R-C6H4)3C. (1), R = F, Cl, Ph, OMe, NO2, tBu, OEt, SMe, CN, CF3, have been prepared, the latter four for the first time, and the ESR spectra have been recorded. aoH, amH, and as