51664-89-2Relevant academic research and scientific papers
Post-functionalized iridium-Zr-MOF as a promising recyclable catalyst for the hydrogenation of aromatics
Rasero-Almansa, Antonia M.,Corma, Avelino,Iglesias, Marta,Sanchez, Felix
, p. 3522 - 3527 (2014/07/08)
The multifunctional heterogeneous catalyst iridium-Zr-based MOF is able to effectively catalyze the hydrogenation of aromatic compounds in high yields under mild conditions. The catalyst was found to be highly active and reusable, giving similar reactivity and selectivity after at least five catalytic uses. This journal is the Partner Organisations 2014.
Carbonylation of Organomercury Compounds: A General Synthesis of Carboxylic Acids and Esters
Baird, William C.,Hartgerink, Ronald L.,Surridge, John H.
, p. 4601 - 4605 (2007/10/02)
Organomercury compounds react with carbon monoxide in aqueous or alcoholic media to give good yields of carboxylic acids or esters.The carboxyl group is introduced selectively at the site of the carbon-mercury bond.Homogeneous group 9 and 10 metal complexes catalyze this carbonylation reaction, which yields mercury(0) as the inorganic byproduct.The mercuration-carbonylation sequence represents a general synthesis of carboxylic acids and esters.
HYPERVALENT IODINE IN ORGANIC SYNTHESIS. A NEW ROUTE TO α-FUNCTIONALIZED CARBOXYLATE ESTERS.
Moriarty, Robert M.,Hu, Henry
, p. 2747 - 2750 (2007/10/02)
Aryl and alkylcarboxylate esters are converted into the corresponding α-hydroxy acids or α-alkoxyesters upon treatment with C6H5I(OAc)2 and base in the appropriate solvent.
