5185-97-7

Usage

Uses

Used in Food and Beverage Industry:
Acetopropylacetate is used as a flavoring agent for imparting a sweet and fruity flavor to a variety of food and beverage products, enhancing their taste profiles and consumer appeal.
Used in Perfume and Personal Care Products Industry:
Acetopropylacetate is utilized as a fragrance ingredient in perfumes and personal care products, contributing to their pleasant and attractive scents, which are essential for consumer acceptance and product differentiation.
Used in Pharmaceutical Industry:
Due to its chemical properties, Acetopropylacetate has potential applications in the pharmaceutical sector, where it may be employed in the development of new drugs or as a component in drug formulations, leveraging its versatile nature.
Used in Industrial Applications:
Acetopropylacetate's chemical characteristics also make it suitable for use in various industrial applications, where it can serve as a solvent or be involved in the synthesis of other compounds, showcasing its broad utility across different sectors.
It is crucial to handle Acetopropylacetate with care and adhere to safety guidelines to ensure the prevention of any adverse effects during its use in these various applications.

InChI:InChI=1/C7H12O3/c1-6(8)4-3-5-10-7(2)9/h3-5H2,1-2H3

Upstream product

• 75-07-0 acetaldehyde 
• 74-85-1 ethene 
• 64-19-7 acetic acid 
• 67-64-1 acetone 
• 20117-47-9 1-methylcyclobutanol 
• 638-38-0 manganese(II) acetate 
• 765-47-9 1,2-dimethylcyclopentene 
• 626-95-9 1,4-Pentanediol 
• 591-87-7 Allyl acetate 
• 107825-25-2 (E)-4,4’,5,5’-tetrahydro-2’H,3H-[2,3’-bifuranylidene]-2’-one 

Downstream Products

• 13045-13-1 3-chloro-3-acetylpropanol 
• 13051-49-5 5-Acetoxy-3-chloropentan-2-one 
• 1071-73-4 5-Hydroxy-2-pentanone 
• 13891-87-7 pent-4-en-2-one 
• 625-33-2 3-penten-2-one 
• 64-19-7 acetic acid 
• 20206-80-8 1-bromo-5-acetoxypentanone-2 
• 29021-95-2 1-acetoxy-3-(2-methyl-[1,3]dioxolan-2-yl)-propane 
• 29021-98-5 3-(2-methyl-[1,3]dioxolan-2-yl)-propan-1-ol 
• 41913-82-0 5-Tosyloxy-2,2-ethylenedioxypentane 
• 626-95-9 1,4-Pentanediol 
• 22508-64-1 4-methyl-4-penten-1-ol 
• 25163-50-2 4-methyl-4-pentenyl-1-tosylate 

Relevant academic research and scientific papers

Bromide ions and methyltrioxorhenium as cocatalysts for hydrogen peroxide oxidations and brominations

Oxidation of alcohols by hydrogen peroxide is negligible; even when catalyzed by methyltrioxorhenium (MTO), the process requires a long reaction time. The addition of a catalytic quantity of bromide ions, as HBr or NaBr, greatly enhances the rate. Some of the reactions were carried out on a larger scale in glacial acetic acid, and others at kinetic concentrations. The data establish that Br2 is the active oxidizing agent in the system, because the catalytic rates under suitable circumstances match those for the independently measured Br2 reaction with alcohol (benzyl alcohol, in particular). At much lower levels of MTO, however, Br2 formation plays a role in the kinetics. Certain other reluctant transformations are conveniently carried out with the MTO/H2O2/Br- combination: aldehydes to methyl esters; 1,3-dioxolanes to glycol monoesters; and ethers (with cleavage) to ketones (mostly), but in fair yield only. When Br- was used in stoichiometric quantity, certain bromination reactions occur. Thus, phenyl acetylenes (PhC2R, R = H, Me, Ph) are converted to dibromoalkenes that are entirely or largely formed as the trans isomer, and phenols are brominated. The latter reaction shows the preference para > ortho > meta. Kinetic studies of benzyl alcohol oxidation with MTO/H2O2Br- were carried out in aqueous solution. With sufficient (normal) levels of MTO, the rate constant for the formation of benzaldehyde agreed with the independently determined value for Br2 + PhCH2OH, k = 4.3 x 10-3 L mol-1 s-1 at 25.0 °C; for sec- phenethyl alcohol, k = (9.8 ± 0.4) x 10-3 L mol-1 s-1. Bromine is formed from the known oxidation of Br- with H2O2, catalyzed by MTO. This reaction results in BrO-/HBOr, which is then rapidly converted to Br2. However, with substantially lower concentrations of MTO, the buildup of benzaldehyde is ca. 4-fold slower, reflecting the diminished rate of Br- oxidation.

Gas-Phase Reactions of 1,2-Dimethylcyclopentene and of 2,6-Heptanedione with Ozone: Unprecedented Formation of an Ozonide by Ozone Treatment of a Diketone

Gas-phase ozonizations of 1,2-dimethylcyclopentene (1) and of 2,6-heptanedione (5) afforded in each case dimethylcyclopentene ozonide (2) in low yields. In the ozonization of 1, diketone 5 was formed as the single major product, along with nine "abnormal" ozonolysis products which were formed by oxidative cleavage of carbon-carbon single bonds.

Electrochemical oxidative ring opening of 1-methylcyclobutanol

The manganese(III) acetate-mediated electrooxidative ring opening of 1-methylcyclobutanol (1) in acetic acid affords pentane-2-one (2) as the major product. The reaction of 1-methylcyclobutanol with Mn(OAc)3-LiCl gives 5-chloropentane-2-one (4).

UV-LIGHT- AND RADIATION-INITIATED ADDITION OF ACETALDEHYDE TO ALLYL ALKANOATES

UV-light- and γ-60Co-initiated addition of acetaldehyde to allyl formate (I) and allyl acetate (II) yielded the 1:1 adducts - 4-oxopentyl formate (III) and 4-oxopentyl acetate (IV), respectively, together with the 1:2 telomers - 7-formyloxy-4-formyloxymethyl-2-heptanone (V) and 7-acetoxy-4-acetoxymethyl-2-heptanone (VI).The initial radiation yields are: G(III) = 200.8, G(IV) = 211.3, G(V) = 39.5, G(VI) = 37.9.Base-catalyzed transesterification of oxopentyl alkanoates III and IV afforded 5-hydroxy-2-pentanone (XIV), the same reaction of dialkylalkanoates VI and VII gave 5-hydroxy-4-hydroxymethyl-2-heptanone (XV).

RADICAL REACTIONS OF CARBONYL COMPOUNDS INITIATED BY METAL SALTS AND OXIDES. XIV. RADICAL OXIDATIVE TELOMERIZATION OF ETHYLENE WITH ACETONE

The radical telomerization of ethylene with acetone was investigated.The telomeric radicals CH3COCH2(CH2CH2)n-1C.H2CH2 (n=1-5) are oxidized by the metal ions with the formation of unsaturated and acetoxy-substituted ketones.The effect of the nature of metal ion and the solvent (acetic acid, ethyl acetate, ethanol, acetonitrile) on the direction of oxidation of the radicals was studied.It was shown that oxidative telomerization takes place most selectively in the presence of divalent copper ions; here the main products are γ-acetopropyl and γ-acetopropenyl acetates or ω-unsaturated ketones, depending on the reaction conditions.