5395-00-6

Basic information

• Product Name: N-(2-methoxyphenyl)benzamide
• Synonyms: benzamide, N-(2-methoxyphenyl)-
• CAS NO: 5395-00-6
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.2585
• Mol File: 5395-00-6.mol
• Article Data: 71

Chemical Properties

• Boiling Point: 287.6°C at 760 mmHg
• Flash Point: 127.7°C
• Density: 1.181g/cm³
• Vapor Pressure: 0.00247mmHg at 25°C
• Refractive Index: 1.619
• CAS DataBase Reference: N-(2-methoxyphenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-methoxyphenyl)benzamide(5395-00-6)
• EPA Substance Registry System: N-(2-methoxyphenyl)benzamide(5395-00-6)

Safety Data

• Hazardous Substances Data: 5395-00-6(Hazardous Substances Data)

Upstream product

• 23997-78-6 (2-methoxyphenyl)phenylmethanone oxime 
• 108-88-3 toluene 
• 65-85-0 benzoic acid 
• 67-56-1 methanol 
• 83125-89-7 N-phenyl-N-(tosyloxy)benzamide 
• 67-62-9 O-Methylhydroxylamin 
• 98-88-4 benzoyl chloride 
• 31600-86-9 2-methoxyphenyllithium 
• 60-29-7 diethyl ether 
• 10026-13-8 phosphorus pentachloride 
• 55-21-0 benzamide 
• 246872-19-5 N-{bis[3,5-bis(trifluoromethyl)phenyl]methylidene}(2-methoxyaniline) 
• 59557-91-4 4-bromo-2-methoxyaniline 
• 529-28-2 4-iodoanisol 

Downstream Products

• 38421-66-8 N-(2-methoxyphenyl)benzothioamide 
• 107480-53-5 N-(2-methoxyphenyl)-N-methylbenzamide 
• 37856-18-1 3-(2-methoxyphenyl)-2-phenylquinazolin-4(3H)-one 
• 854829-04-2 N-benzoyl-N-(2-nitro-benzoyl)-o-anisidine 
• 103700-28-3 3-benzoylamino-4-methoxy-benzenesulfonyl chloride 
• 59386-96-8 N-(2-methoxyphenyl)benzimidoyl chloride 
• 38259-78-8 N-(2-methoxy-4-nitrophenyl)benzamide 
• 1026136-95-7 8-methoxy-2,4-diphenylquinazoline 
• 55-21-0 benzamide 
• 16152-08-2 4-(2-methoxyphenyl)-3,5-diphenyl-4H-1,2,4-triazole 
• 532-32-1 sodium benzoate 
• 90-04-0 2-methoxy-phenylamine 
• 30616-79-6 4-methoxy-2-phenyl-1,3-benzoxazole 
• 439930-64-0 [Me₂Al(o-MeO-Ph)NC(O)(Ph)AlMe₃] 

Relevant articles and documents

Hydrogen bonding and structure of 2-hydroxy-N-acylanilines in the solid state and in solution

In crystals of 2-hydroxy-N-benzoylaniline and 2-hydroxy-N-trifluoroacetylaniline, ribbons of molecules are held by intermolecular hydrogen bonds between the hydrpxy and carbonyl groups of adjacent molecules. The O ... H ... O bond lengths are 2.65 and 2.7

Iron-catalyzed oxidative amidation of acylhydrazines with amines

A new approach for amide bond formation via a mild and efficient Iron-catalyzed cross-coupling reaction of acylhydrazines and amines using TBHP as oxidant is described. This protocol is compatible with a wide range of amines and acylhydrazines. In addition, the synthetic application of the reaction is presented.

An Environmentally Benign, Catalyst-Free N?C Bond Cleavage/Formation of Primary, Secondary, and Tertiary Unactivated Amides

Herein, we report an operationally simple, cheap, and catalyst-free method for the transamidation of a diverse range of unactivated amides furnishing the desired products in excellent yields. This protocol is environmentally friendly and operates under extremely mild conditions without using any promoter or additives. Significantly, this strategy has been implied in the chemoselective synthesis of a pharmaceutical molecule, paracetamol, on a gram-scale with excellent yield. We anticipate that this universally applicable strategy will be of great interest in drug discovery, biochemistry, and organic synthesis.